| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of Trace Impurities in High Purity Titanium Dioxide by High Resolution Inductively Coupled Plasma Mass Spectrometry |
| HE Xiao-mei1,XIE Hua-lin1,NIE Xi-du1,TANG You-gen2 |
1. Department of Chemistry, Hunan Institute of Technology, Hengyang 421008, China
2. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China |
|
|
|
|
Abstract An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for the rapid simultaneous determination of twenty six elements (Be, Na, Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Mo, Cd, Sn, Sb, Ba, Ce, Nd, Sm, Pt, Pb and Bi) in high purity titanium dioxide was described. Samples were decomposed by (NH4)2SO4 and H2SO4. Most of the spectral interferences could be avoided by measuring in the high-resolution mode. The matrix effects due to the presence of excess sulfuric acid and Ti were evaluated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits are 0.004-0.63 μg·g-1,the recovery ratio is 87.6%-106.4%, and the RSD is less than 3.5%. The method is accurate, quick and convenient. It has been applied to the determination of trace impurities in high purity titanium dioxide with satisfactory results.
|
|
Received: 2006-05-06
Accepted: 2006-08-02
|
|
|
|
Corresponding Authors:
HE Xiao-mei
E-mail: hualinxie@vip.163.com
|
|
| Cite this article: |
|
HE Xiao-mei,XIE Hua-lin,NIE Xi-du, et al. Determination of Trace Impurities in High Purity Titanium Dioxide by High Resolution Inductively Coupled Plasma Mass Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(06): 1192-1196.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2007/V27/I06/1192 |
[1] Jackson K W, West T S, Balchin L. Anal. Chem., 1973, 45(2): 249.
[2] Wildhagen D, Krivan V. Fresenius’ J. Anal. Chem., 1997, 359(3): 230.
[3] Peng T Y, Du P W, Hu B, et al. Anal. Chim. Acta, 2000, 421(1): 75.
[4] Korn M G A, Ferreira A C, Costa A C S, et al. Microchem. Journal, 2002, 71(1): 41.
[5] ZHAO Jin-wei, FENG Ya-hui, CHENG Wei, et al(赵金伟, 封亚辉, 程 薇, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(5): 972.
[6] Nakane K, Uwamino Y, Morikawa H, et al. Anal. Chim. Acta, 1998, 369(1-2): 79.
[7] Riondato J, Vanhaecke F, Moens L, et al. J. Anal. Atom. Spectrom., 1997, 12(9): 933.
[8] WANG Xiao-yi, Zhu W, Witkamp, et al(王小逸, Zhu W, Witkamp, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(6): 1167.
[9] Vaughan M A, Horlick G, Tan S H. J. Anal. Atom. Spectrom., 1987, 2(8): 765.
[10] Vanhaecke F, Vanhoe H, Dams R et al. Talanta, 1992, 39(7): 737.
[11] Rodushkin I, dman F, Branth S. Fresenius’ J. Anal. Chem., 1998, 364(4): 338.
[12] Turk G C, YU L L, Salit M L, et al. Fresenius’ J. Anal. Chem., 2001, 370(2-3): 259.
[13] Lü Lin-lin, XU Ye, YI Ping, et al(吕琳琳, 徐 烨, 伊 萍, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(3): 548.
[14] TIE Mei, ZANG Shu-liang, ZHANG Wei, et al(铁 梅, 臧树良, 张 崴, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(3): 551. |
| [1] |
GUO Jin-ke, LU Ji-long, SI Jun-shi, ZHAO Wei, LIU Yang, WANG Tian-xin, LAI Ya-wen*. Study on Heavy Metal in Soil by Portable X-Ray Fluorescence
Spectrometry Based on Matrix Effect Correction and
Correspondence Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2309-2314. |
| [2] |
LIU Hong-wei1,3, FU Liang2*. Analysis of Metal Impurity Elements in Li4Ti5O12 Through Microwave Plasma Atomic Emission Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3021-3025. |
| [3] |
LI Tan-ping, LI Ai-yang. Analysis of Ultra-Trace Metal Impurity Elements in Proprylene Glycol Monomethyl Ether Using Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 618-623. |
| [4] |
ZHANG Liang-liang, WANG Chang-hua, HU Fang-fei, MO Shu-min, LI Ji-dong*. Determination of Trace Impurity Elements in Zircaloy by Ion Exchange-Inductively Coupled Plasma Mass Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2622-2628. |
| [5] |
GONG Ting-ting, TIAN Ye, CHEN Qian, XUE Bo-yang, HUANG Fu-zhen, WANG Lin-tao, LI Ying*. Matrix Effect and Quantitative Analysis of Iron Filings with Different Particle Size Based on LIBS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1207-1213. |
| [6] |
ZHENG Pei-chao1, HE Miao1, WANG Jin-mei1*, WANG Ning-shen1, LI Wei-qi1, LUO Yuan-jiang1, DONG Da-ming2, ZHENG Kun-peng1, YAN Bo-wen1. Ca and Mg Analysis in Solution by Solution Cathode Glow Discharge Combined with Standard Addition Method and Background Removal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 271-276. |
| [7] |
WANG Zi-ren, WANG Chang-hua, HU Fang-fei, LI Ji-dong*. Quantification of Trace Impurities in Graphite by Glow Discharge Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(04): 1256-1261. |
| [8] |
FU Liang1,3, ZHAO Feng-xuan2, WANG Hai-yan3, WANG Huan-zhe2, CHEN Tao2, XU Jian-hua1, LI Bing1, XIE Hua-lin1*. Impurity Elements Analysis of Catalyst Precursor Ruthenium Nitrosyl Nitrate Using Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3572-3577. |
| [9] |
FU Liang1, 2, SHI Shu-yun2*, TANG You-gen2, WANG Hai-yan2. Analysis of Ultra-Trace Impurities in High Purity Molybdenum Powder through Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2588-2594. |
| [10] |
FENG Xiao-gui1, KONG Xue-yan2, HE Qian-ge1, WANG Jian-chen1, CHEN Jing1. A Modified Standard Addition Method and Its Application in ICP Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3579-3584. |
| [11] |
FANG Li1,3, ZHAO Nan-jing1,3*, MA Ming-jun1,2,3, MENG De-shuo1,3, GU Yan-hong1,2,3, JIA Yao1,2,3, LIU Wen-qing1,3, LIU Jian-guo1,3. Quantitative Analysis of Pb，Cd，Cr and Cu in Soil Using Standard Addition Method Combined with Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(10): 3274-3280. |
| [12] |
XIU Jun-shan1, LIU Yun-yan1, DONG Li-li2，QIN Hua1. The Detection of Trace Wear Elements in Engine Oil Using Indirect Ablation-Laser Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2885-2890. |
| [13] |
WANG Jin-lei1, 2, QIAN Jun-min2, LI Bo1, LUO Lin1*, SUN Bao-lian1, XU Wei-jun2, CUI Ning2. Chloroformylation-Separation of Matrix and Determination of Trace Impurities in High Purity Chromium by ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2896-2899. |
| [14] |
YANG Wen-wu, SHI Guang-yu, SHANG Qi, ZHANG Wen, HU Zhao-chu*. Applications of Femtosecond (fs) Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry in Earth Sciences[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2192-2198. |
| [15] |
NIE Xi-du1, FU Liang2* . Simultaneous Determination of Impurity Elements in N-Methyl-2- Pyrrolidone (NMP) with Direct Injection Inductively Coupled Plasma Optical Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(03): 910-913. |
|
|
|
|
