|
|
|
|
|
|
Study on Leakage Detection Technology of Corrosive Acid Solution Based on Fiber Raman Temperature Measurement |
FENG Wei-yi1, 2, LIU Li-hua1*, ZHANG Xu-ping2, ZHAO Xia1, HUANG Xiao-wei1, YU Chun-han3 |
1. Fasten Group, Wuxi 214433, China
2. Post-Doctoral Research Station of Materials and Engineering, Nanjing University, Nanjing 210008, China
3. Jiangyin Excen Broaden Polymer Co., Ltd., Wuxi 214446, China |
|
|
Abstract Distributed Temperature Sensing System (DTS) is based on the effect of Raman spectrum on temperature sensitivity. It can realize long-distance distributed temperature monitoring, especially suitable for fire alarm, high-temperature liquid leakage, low-temperature gas leakage and other application scenarios. However, for normal temperature media, such as highly corrosive solutions transported in chemical pipelines, when corrosion occurs in the pipeline infiltration, there is basically no temperature change between the leakage location and the surrounding environment. At this time, DTS temperature measurement technology is difficult to identify the occurrence of leakage events. In order to solve the problem of leakage detection of strong acid solution pipelines or tanks under normal temperature, in this paper, a technology based on optical fiber sensing to detect the leakage of acid solution medium was proposed. A novel self-sensing structure of acid solution was designed. Compared with leaking cable, it does not need to consume electricity and is not easy to cause a false alarm. Precise positioning and simple laying. Multi-point leakage detection can be realized across the pipeline. Fiber optic cable outer sheath material is alkali resistant and acid-resistant material, composed of nylon, magnesium hydroxide, aluminum hydroxide and a small number of colors masterbatch. It can be dissolved quickly by hydrochloric acid with the certain mass fraction. Exothermic chemical neutralization reaction occurs. Then the Raman spectrum of backscattering in the sensor fiber is changed, and the temperature of the sensor fiber can be increased by more than 5℃. The sensing fiber optic cable is connected to the DTS system, and the system adopts the dual demodulation method based on anti-stokes light and stokes light to calculate the temperature value of each position in the sensing fiber. Therefore, when the special optical cable and pipeline are laid in the same ditch, if acid solution leakage occurs in a certain position, resulting in the temperature rise of the point. After the dispersion compensation and the temperature calibration, the acid leakage event can be determined, according to the ratio change between the anti-stokes light and the stokes light. This technology not only solves the problem of engineering application of leakage detection and alarm in the transportation and storage of acid solution but also avoids the interference of false alarm of weak acid or alkali solution, saving energy and protecting the environment. It can accurately detect the leakage of the highly corrosive acid solution and improve the digital intelligent safety monitoring level of hazardous chemicals.
|
Received: 2019-11-19
Accepted: 2020-03-02
|
|
Corresponding Authors:
LIU Li-hua
E-mail: fengwy@fastengk.com
|
|
[1] ZHAO Quan(赵 全). Beijing University of Chemical Technology(北京化工大学), 2017.
[2] LIAN Long-jie(连龙杰). Beijing University of Chemical Technology(北京化工大学), 2014.
[3] WANG Yong-sheng, WEN Hua-long, WU Hai-tao(王永胜, 文华陇, 吴海涛). Sulphuric Acid Industry(硫酸工业), 2013, (3): 34.
[4] Huang Y, Wang Q, Shi L, et al. Applied Optics, 2016, 55(2): 242.
[5] Wong L, Deo R, Rathnayaka S, et al. Electron. J. Struct. Eng., 2018, 18: 47.
[6] Ren L, Jiang T, Jia Z, et al. Measurement, 2018, 122: 57.
[7] Jia Z, Ho S C, Li Y, et al. Journal of Loss Prevention in the Process Industries, 2019, 62: 103926.
[8] WANG Chen, LIU Qing-wen, CHEN Dian, et al(王 辰, 刘庆文, 陈 典, 等). Acta Optica Sinica(光学学报), 2019, 39(10): 1006005.
[9] LI Min, LIAO Yan-biao(黎 敏, 廖延彪). Fiber Optic Sensors Technology(光纤传感器及应用技术). Wuhan: Wuhan University Press(武汉:武汉大学出版社), 2012. |
[1] |
YUAN Ting-ting, HUANG Peng, LI Han-yang, SHANG Yan-ting, YANG Xing-hua, ZHANG Yang, LI Han-yang, ZHAO En-ming*. Design and Research for a Kind of Optical Fiber Sensor Based on Extroradinary Optical Tramsimission Phenomenon[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 681-684. |
[2] |
ZHANG Yan-jun, GAO Hao-lei, FU Xing-hu*, TIAN Yong-sheng, WANG Hui-min, ZHANG Yi-nan. Threshold of Brillouin Scattering in a Few-Mode Fiber[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 285-289. |
[3] |
CHEN Chen, LI Xian-li, DING Hui*. A Novel Wavelength Demodulation Technique for Interferometric Fiber Optic Sensor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2948-2953. |
[4] |
SUN Ming-ming, WANG Jian-feng, JIN Yong-xing*, DONG Xin-yong. All-Fiber Mach-Zehnder Interferometer Based on Lateral-Offset and Peanut Shape Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(05): 1560-1564. |
[5] |
ZHANG Fu-cai1, SUN Xiao-gang1*, XING Jian2. Study on the Multi-Spectral True Temperature Pyrometer for Explosion Transient of Thermo-Baric Explosives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(05): 1598-1603. |
[6] |
ZHANG Yan-jun1, 2, LIU Wen-zhe1, FU Xing-hu1, 2*, BI Wei-hong1, 2 . An Extraction and Recognition Method of the Distributed Optical Fiber Vibration Signal Based on EMD-AWPP and HOSA-SVM Algorithm [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 577-582. |
[7] |
ZHANG Yan-jun1, 2, LIU Wen-zhe1, FU Xing-hu1, 2*, BI Wei-hong1, 2 . A Brillouin Scattering Spectrum Feature Extraction Based on Flies Optimization Algorithm with Adaptive Mutation and Generalized Regression Neural Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2916-2923. |
[8] |
ZHANG Yan-jun1, 2, LIU Wen-zhe1, FU Xing-hu1, 2*, BI Wei-hong1, 2 . The High Precision Analysis Research of Multichannel BOTDR Scattering Spectral Information Based on the TTDF and CNS Algorithm [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1802-1807. |
[9] |
FENG Xin-jie1, MAO Pei-ling1, CHEN Xiao-long1, LUO Yun-han1, 2*, PENG Shui-hua1, CHEN Chao-ying1, WANG Fang1, TANG Jie-yuan1, 2, YU Jian-hui1, 2, ZHANG Jun1, 2, LU Hui-hui1, 2, CHEN Zhe1, 2 . Design and Optimization of Surface Plasmon Resonance Sensor Based on Side Polished Single-Mode Fiber [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(05): 1419-1423. |
[10] |
YAO Jun1, SHEN Jing2*, LI Li1*, LI Xin-xia1, CHEN Jian1 . Development and Application of Six-Channel Fiber Optic Sensing Drug Dissolution Monitor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(09): 2587-2590. |
[11] |
ZHAO Na1, FU Hai-wei1, 2*, SHAO Min1, 2, LI Hui-dong1, LIU Ying-gang1, QIAO Xue-guang2 . Research on High Sensitivity Temperature Sensor Based on Mach-Zehnder Interferometer with Waist-Enlarged Fiber Bitapers [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1722-1726. |
[12] |
YUAN Cheng-xu, WANG Zi-nan*, JIA Xin-hong, LI Jin, YAN Xiao-dong, CUI An-bin . 94 km Brillouin Distributed Optical Fiber Sensors Based on Ultra-Long Fiber Ring Laser Pumping [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(05): 1191-1195. |
[13] |
DING Hai-yan1, LI Gai-ru1,YU Ying-ge2, ZHOU Dong-dong2, GUO Wei1, ZHI Ling1, LI Xin-xia1* . Process Monitoring of Dissolution of Valsartan and Hydrochlorothiazide Tablets by Fiber-Chemical Sensor Assisted by Mathematical Separation Model of Linear Equations[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(04): 1056-1059. |
[14] |
LUO Yun-han1, CHEN Xiao-long1, XU Meng-yun1, GE Jia1, ZHANG Yi-long2, HE Yong-hong2, TANG Jie-yuan1, YU Jian-hui1, ZHANG Jun1, CHEN Zhe1, CHEN Xing-dan1 . Spectra Modulated Surface Plasmon Resonance Sensor Based on Side Polished Multi-Mode Optical Fiber[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(03): 577-581. |
[15] |
WANG Tao, HE Da-wei*, WANG Yong-sheng, QUAN Yu, WANG Peng-fei, YIN Ze-lin . Spectral Repeatability of Regenerated Fiber Gratings Prepared by High Temperature Annealing[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(05): 1411-1414. |
|
|
|
|