|
|
|
|
|
|
Research on Efficiency Improvement of Inverted PTB7∶PC70BM Solar Cells Using ZnO Nanofibers Prepared by Electrospinning as Electron Transport Layer |
SUN Qin-jun*, SHI Xiao-lei, GAO Li-yan, ZHOU Shao-long, WU Jun, HAO Yu-ying* |
Key Lab of Advanced Transducers and Intelligent Control System of Ministry of Education and Taiyuan Province, College of Physics and Optoelectronic Engineering, Taiyuan University of Technology, Taiyuan 030024, China |
|
|
Abstract In this paper, the effects of different diameters of ZnO nanofibers prepared by electrospinning on the conversion efficiency of organic solar cells were studied. First of all, ZnO nanofibers with diameters ranging from 43 to 110 nm were prepared by electrospinning technique. Then, ZnO nanofibers with different diameters were added to inverted organic solar cells (ITO/ZnO∶ZnO nanofiber/PTB7∶PC70BM/MoO3/Al) as electron transport layer. Compared to the planar ZnO electron transport layer, ZnO nanofibers have the advantages of large specific surface area, increasing the ability of electron transfer and extraction and improving the photoelectric conversion efficiency of the device. It was found that the smaller the diameter of ZnO nanofibers is, the greater the efficiency of the cells will be. When the diameter of ZnO nanofibers was (46±5) nm and the receiving time was 30 s, conversion efficiency of the cell increased by 8%.
|
Received: 2016-12-10
Accepted: 2017-05-08
|
|
Corresponding Authors:
SUN Qin-jun, HAO Yu-ying
E-mail: sunqinjun@tyut.edu.cn;hyy_123991@sina.com
|
|
[1] Bundgaard E, Hagemann O, Manceau M, et al. Macromolecules, 2010, 43(19): 8115.
[2] Lee S, Yeo J S, Ji Y, et al. Nanotechnology, 2012, 23(34): 1995.
[3] ZHAO Huan-bin, SUN Qin-jun, ZHOU Miao, et al(赵焕斌,孙钦军,周 淼,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2016, 36(2): 331.
[4] Naichia Yeh, PulinYeh, et al. Renew. Sust. Energ. Rev., 2013, 21(5): 421.
[5] Gholamkhass B, Kiasari N M, Servati P, et al. Org. Electron., 2012, 13(6): 945.
[6] Lin Z H, Jing C Y, Zhu C X, et al. Acs. Appl. Mate. Interface, 2013, 25(5): 1310.
[7] Chang J, Lin Z, Jiang C, et al. Acs. Appl. Mater. Interfaces, 2014, 6(21): 18861.
[8] Macleod B A, Villers B J T D, Schulz P, et al. Energy. Environ. Sci., 2014, 8(2): 592.
[9] Saleh W R, Saeed N M, Twej W A, et al. Adv. Mater. Phys. Chem., 2012, 2(1): 11.
[10] Zandi S, Kameli P, Salamati H, et al. Phys B: Cond. Matter, 2011, 406: 3215.
[11] Thambidurai M, Kim J Y, Ko Y, et al. Nanoscale, 2014, 6(15): 8585.
[12] Zuo L, Zhang S, Dai S, et al. Rsc. Advances, 2015, 5(61): 49369.
[13] Kim J W, Suh Y H, Lee C L, et al. Nanoscale, 2015, 7(10): 4367.
[14] Fu H, Choi M, Lua W, et al. Solid State Electronics, 2012, 69(69): 50.
[15] Sablon K A, Little J W, Mitin V, et al. Nano. Lett., 2011, 11(6): 2311.
[16] Choi H W, Lee K S, Alford T L, et al. Appl. Phys. Lett., 2012, 5(10): 153301.
[17] Liu C P, Chen Z H, Wang H E, et al. Appl. Phys. Lett., 2012, 100(24): 243102.
[18] Tanveer M, Habib A, Khan M B, et al. Mater. Sci. Eng B, 2012, 177(13): 1144.
[19] Park J A, Moon J, Lee S J, et al. Curr. Appl. Phys., 2009, 9(3): S210.
[20] Horzum N, Ta瘙塂ioglu D, Okur S. Talanta, 2011, 85(2): 1105.
[21] Kumar P R, Khan N, Vivekanandhan S, J. Nanosci. Nanotech., 2012, 12(1): 1.
[22] Shuakat M N, Lin T, J. Nanosci. Nanotech., 2014, 14(2): 1389.
[23] Moliton A, Nunzi J M. Polym. Int., 2006, 55: 583.
[24] Hu X, Wang M, Huang F, et al. Synth. Met., 2013, 164: 5.
[25] Jayawardena K D G I, Rhodes R, Gandhi K K, et al. J. Mater. Chem. A, 2013, 34: 9922. |
[1] |
ZHANG Xin-bo1, CONG Long-zhuang1, YANG Lan-lan1, DU Zhong-lin1, WANG Yao1, WANG Yan-xin1, HUANG Lin-jun1, GAO Fan1, Laurence A. Belfiore2, TANG Jian-guo1*. Optimal Fluorescence Property of CdSe Quantum Dots and Electrospinning Polyvinylpyrrolidone Hybrid Microfibers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 990-996. |
[2] |
SONG Wei, LI Ting-ting, WANG Xu, ZHAO Bing* . Preparation Polyacrylonitrile/Ag Nanoparticle Composite Nanofibers Via an Elelctrospinning Technique and Their Surface Enhanced Raman Scattering Study[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1899-1903. |
[3] |
JIA Hui-min1, TANG Ji-long1*, FANG Xuan1*, WANG Shuang-peng2, ZHAO Hai-feng2, FANG Dan1, WANG Xiao-hua1, FANG Fang1, LI Jin-hua1, CHU Xue-ying1, WEI Zhi-peng1, MA Xiao-hui1, XU Li1 . Preparation of MgxZn1-xO Nanofibers Using PVP Nanofibers as Templates by Atom Layer Deposition and Their Optical Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(12): 3197-3200. |
[4] |
CHEN Jia-long, GAO Guang-yu, CHU Sai-sai, WANG Shu-feng*, GONG Qi-huang* . All Wavelength Picosecond Fluorescent Anisotropy of Aligned MEH-PPV/PVP Electrospun Fibers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(10): 2593-2596. |
[5] |
QU Ping, WANG Xuan, CUI Xiao-xia, ZHANG Li-ping*. Biomimetic Mineralization of Rod-Like Cellulose Nano-Whiskers and Spectrum Analysis [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(05): 1418-1422. |
[6] |
WANG Xiu-hong1, HUANG Tao1*, HUANG Fei2,3*, ZHANG Sheng-nan1, WANG Yi2, GAO Chao1 . Light Absorption Characteristic of Natural Pyrite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(09): 2508-2511. |
[7] |
SONG Dan-dan, ZHAO Su-ling*, XU Zheng, ZHANG Fu-jun, LU Li-fang, ZHANG Yan-fei, KONG Chao, YAN Guang . Effect of Mixed Interface on the Performance of Solution-Processed Phosphorescent OLEDs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(06): 1454-1457. |
[8] |
ZHANG Li-ping1, TANG Huan-wei1, QU Ping1, LI Shuai1, QIN Zhu2, SUN Su-qin2 . Spectral Property of One-Dimensional Rodlike Nano Cellulose [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(04): 1097-1100. |
[9] |
TANG Li-rong, HUANG Biao*, DAI Da-song, OU Wen, LIN Yan-ping, CHEN Xue-rong . Preparation and Spectrum Properties of Cellulose Nanoparticles [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(07): 1876-1879. |
[10] |
LIU Yan-hong1, 2, LI Bin1*, CONG Yan1, 2 . Synthesis and Optical Property Studies of Long-Lasting Phosphor ZrO2∶Ti Electrospinning Fibers [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(04): 887-891. |
[11] |
WANG Dong-mei1, 2, WANG Liang1, DONG Huai3, LIU Wei4, JIANG Jian-zhuang2 . Preparation and Optical Properties of Fluorescent Nanofiber Containing Europium Complex [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(10): 2777-2781. |
[12] |
SU Meng-chan1,YI Li-xin1,WANG Yang2,3,SHI Yu-meng1,LIANG Chun-jun1*. Investigation on Performance Enhancement of Bulk Heterojunction Organic Solar Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(04): 740-744. |
[13] |
YANG Shao-peng1,YANG Ya-ru1,ZHAO Su-ling2,XU Zheng2,ZHANG Fu-jun2,ZHANG Xue-feng1,LU Su-kui1,QIN Xiang-dong1*. Effects of PBD on the Luminescence Properties of PVK∶Ir(ppy)3[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(02): 241-245. |
|
|
|
|