Abstract:The feasibility of using laser-induced breakdown spectroscopy (LIBS) combined with chemometrics methods for fast identification of matcha and green tea powder was investigated in this paper. The main differences between matcha and green tea powder are varieties of tea plants, cultivation management, growth time and processing technology. LIBS spectra between 230 to 880 nm of matcha produced by different manufacturers and green tea powder made with different fixation methods were selected and min-max normalization was the measure for preprocessing. Characteristic wavelengths were selected according to the X-variables loadings on the basis of principal component analysis (PCA), and then linear discriminant analysis (LDA) models were built based on characteristic wavelengths. The results showed that the LDA model based on characteristic wavelengths could identify matcha and green tea powder rapidly. Four characteristic wavelengths belong to C(Ⅰ) 247.94 nm,Mg(Ⅱ) 279.60 nm,Ca(Ⅱ) 393.45 nm and Fe(Ⅱ) 766.68 nm. The accuracy of the calibration and the prediction set all reached 100%. Laser-induced breakdown spectroscopy could accurately identify matcha produced by different manufacturers and green tea powder made with different fixation methods.
Key words:Laser-induced breakdown spectroscopy; Matcha; Green tea powder; Linear discriminant analysis (LDA)
於筱岚,彭继宇,刘 飞,何 勇. 激光诱导击穿光谱技术用于抹茶和绿茶粉的快速鉴别[J]. 光谱学与光谱分析, 2017, 37(06): 1908-1911.
YU Xiao-lan, PENG Ji-yu, LIU Fei, HE Yong. Fast Identification of Matcha and Green Tea Powder with Laser-Induced Breakdown Spectroscopy. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1908-1911.
[1] Anhui Agricultural College(安徽农学院). Tea Manufacture(制茶学). Beijing: China Agriculture Press(北京: 中国农业出版社), 2008. 202.
[2] ZHANG Tang-heng(张堂恒). Tea Science Dictionary of China(中国茶学辞典). Shanghai: Shanghai Scientific & Technical Publishers(上海: 上海科学技术出版社), 1995. 32.
[3] Pereira F M V, Milori D M P, Venancio A L, et al. Talanta, 2010, 83(2): 351.
[4] Zhang D C, Ma X, Wen W Q, et al. Journal of Physics: Conference Series, 2009, (185): 012058.
[5] Beldjilali S, Yip W L, Hermann J, et al. Anal. Bioanal. Chem., 2011, 400(7): 2173.
[6] Nunes L C, Silva G A, Trevizan L C, et al. Spectrochim. Acta Part B, 2009, 64(6): 565.
[7] Schenk E R, Almirall J R. Appl. Opt., 2010, 49(13): C153.
[8] Bilge G, Velioglu H M, Sezer B, et al. Meat Sci., 2016, 119: 118.
[9] Zhang Tianlong, Wu Shan, Dong Juan, et al. J. Anal. At. Spectrom., 2015, 30(2): 368.
[10] Morsy N, Sun D W. Meat Sci., 2013, 93(2): 292.
[11] Braga J W B, Trevizan L C, Nunes L C, et al. Spectrochim. Acta Part B, 2010, 65(1): 66.
[12] Ferreira E C, Menezes E A, Matos W O, et al. Food Control, 2010, 21(10): 1327.
[13] Khumaeni A, Lie Z S, Niki H, et al. Anal. Bioanal. Chem., 2011, 400(10): 3279.
[14] Boyain-Goitia A R, Beddows D C S, Griffiths B C, et al. Appl. Opt., 2003, 42(30): 6119.