Structure Effect on K Shell Fluorescence Parameters at Bis-4-Bromobenzyl-1,2,4-Triazol-3-Ones
V. Aylkc1*, Y. ünver2, N. Kup Aylkc3, E. T r o lu4, K. Sancak2, Z. Laap2
1. Department of Metallurgical and Materials Engineering, Faculty of Technology, skenderun Technical University, 31040, Hatay, Turkey 2. Department of Chemistry, Faculty of Science, Karadeniz Technical University, 61080, Trabzon, Turkey 3. Department of Energy Systems Engineering, Faculty of Technology, skenderun Technical University University, 31040, Hatay, Turkey 4. Department of Physics, Faculty of Sciences, Karadeniz Technical University, 61080, Trabzon, Turkey
Structure Effect on K Shell Fluorescence Parameters at Bis-4-Bromobenzyl-1,2,4-Triazol-3-Ones
V. Aylkc1*, Y. ünver2, N. Kup Aylkc3, E. T r o lu4, K. Sancak2, Z. Laap2
1. Department of Metallurgical and Materials Engineering, Faculty of Technology, skenderun Technical University, 31040, Hatay, Turkey 2. Department of Chemistry, Faculty of Science, Karadeniz Technical University, 61080, Trabzon, Turkey 3. Department of Energy Systems Engineering, Faculty of Technology, skenderun Technical University University, 31040, Hatay, Turkey 4. Department of Physics, Faculty of Sciences, Karadeniz Technical University, 61080, Trabzon, Turkey
摘要： In this study; the effect of the electron density over the Br atoms raising with increasing number of CH2 group using the results of the K X-ray cross-sections and average fluorescence yields of bromine in quaternary-imidazole ring. In the experimental set-up, 50 mCi 241Am source and a collimated Ultra-LEGe detector were used. The electron density on the Br atoms raises according to the number of the CH2 groups on the contrary of the inductive effect. The decreasing of the X-ray fluorescence parameters is interested with the increasing the electron density of Br atoms.
Abstract：In this study; the effect of the electron density over the Br atoms raising with increasing number of CH2 group using the results of the K X-ray cross-sections and average fluorescence yields of bromine in quaternary-imidazole ring. In the experimental set-up, 50 mCi 241Am source and a collimated Ultra-LEGe detector were used. The electron density on the Br atoms raises according to the number of the CH2 groups on the contrary of the inductive effect. The decreasing of the X-ray fluorescence parameters is interested with the increasing the electron density of Br atoms.
V. Aylkc1*, Y. ünver2, N. Kup Aylkc3, E. T r o lu4, K. Sancak2, Z. Laap2 . Structure Effect on K Shell Fluorescence Parameters at Bis-4-Bromobenzyl-1,2,4-Triazol-3-Ones[J]. 光谱学与光谱分析, 2016, 36(12): 4120-4124.
V. Aylkc1*, Y. ünver2, N. Kup Aylkc3, E. T r o lu4, K. Sancak2, Z. Laap2 . Structure Effect on K Shell Fluorescence Parameters at Bis-4-Bromobenzyl-1,2,4-Triazol-3-Ones. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(12): 4120-4124.
[1] Isloor A M, Kalluraya B, Rao M, et al. Chem. Soc., 2000，4：265. [2] Amir M, Kumar H, Javed S A. Eur. J. Med. Chem.，2008，43(10)：2056. [3] Sztanke K, Tuzimski T, Rzymowska J, et al. Eur. J. Med. Chem.，2008，43(2)：404. [4] Kus C, Klcgil G A, zbey S, et al. Bioorg. Med. Chem.，2008，16(8)：4294. [5] Padmavathi V, Thriveni P, Sudhakar G，et al. Eur. J. Med. Chem.，2008，43(5)：917. [6] Kalluraya B, Isloor A M, Shenoy S. Indian J. Heterocycl. Chem.，2001，11：159. [7] Kalluraya B, Isloor A M, Priya F V, et al. Indian J. Heterocycl. Chem.，2004，13(3)：245. [8] Koparir M, Orek C, Parlak A E, et al. European Journal of Medicinal Chemistry，2013，63：340. [9] Brunner G, Nagel M, Hartmann E. E. Arnt, J. Phys. B: At. Mol. Phys.，1982，15：4517. [10] Folkmann F. Nucl. Instr. and Meth. B，1996，109/110：39. [11] Raj S, Padhi H C, Polasik M. Nucl. Instr. and Meth. B, 1998, 145: 485. [12] Mukoyama T, Taniguchi K, Adachi H. X-Ray Spectrom., 2000，29：426. [13] Raj S, Padhi H C, Polasik M. Nucl. Instr. and Meth. B, 2000, 160: 443. [14] Mukoyama T, Taniguchi K, Adachi H. Phys. Rev. A, 2001, 63: 042514. [15] Kawai J, Ohta M, Konishi T. Analytical Sciences, 2005, 21: 865. [16] Mukoyama T, Kaji H, Taniguchi K, et al. X-Ray Spectrom.，1997，26：269. [17] Kulshreshtha S K, Wagh D N, Bajpei H N. X-Ray Spectrom., 2005, 34: 200. [18] Porikli S, Han I, Yaln P, et al. Spectroscopy Letters，2011，44：38. [19] Sogut O, Seven S, Baydas E, et al. Spectrochim. Acta, Part B，2001，56：1367. [20] Iwatsuki M, Fukasawa T. X-Ray Spectrom.，1987，16：73. [21] Kucukonder A. Eur. Phys. J. D，2001，17：293. [22] Kucukonder A, Sogut O, Buyukkasap E, et al. X-Ray Spectrom.，2003，32：60. [23] Aylikci V, Unver Y, Dugdu E, et al. Chem. Phys. Lett.，2013，556：365. [24] Berger M J, Hubbell J H. XCOM: Photon Cross-Sections on a Personnel Computer (version 1.2), NBSIR85-3597, National Bureau of Standarts, Gaithersburg, MD, USA, for version 3.1, 1999, see http://physics.nist.gov/. [25] Apaydin G, Aylikci V, Biyiklioglu Z, et al. Chinese J. Chem. Phys.，2008，21：591. [26] Scofield H. Lawrence Livermore Laboratory (UCRL), 1973. 51326. [27] Aylikci V, Cengiz E, Apaydin G, et al. Chem. Phys. Lett.，2008，461：332. [28] Krause M O. J. Phys. Chem. Ref., 1979, Data 8, 307.
