Abstract:Polygonum cuspidatum Sieb. et Zucc. is an important Chinese traditional medicine, and has wide distribution in China. Based on their infrared fingerprint spectra, Polygonum cuspidatum root samples from 7 geographical origins could be divided into 6 classes with principal component analysis. The classification was well correlated to their geographical origins and weather. In the same class, the chemical components of P. cuspidatum are similar to each other, which can be considered as the criterion for evaluating the quality of P. cuspidatum. The results showed that their characteristic infrared spectra were similar in the range of 4000-1700cm-1, but varied significantly for different groups and kinds of P. cuspidatum samples in the range of 1700-900cm-1. The method is rapid and simple, and could be applied to evaluate the quality of this traditional Chinese medicine. It is one of the methods in the quality control of traditional Chinese medicines.
Key words:Different distribution;FTIR spectroscopy;Root of Polygonum cuspidatum;Principal component analysis
[1] Editorial Office of National Chinese Herbal Medicine Collection(全国中草药汇编编写组编). Collection of National Chinese Herbal Medicine(全国中草药汇编). Beijing: People’s Hygine Press(北京:人民卫生出版社), 1975. 508. [2] Pharmacopoeia Committee of Ministry of Health, the People's Republic of China(国家药典委员会主编). Pharmacopoeia of the Peoples’s Republic of China(中华人民共和国药典). Beijing: Chemical Industry Press(北京: 化学工业出版社), 2000. 167. [3] XUE Lan(薛 岚). China Journal of Chinese Material Medica(中国中药杂志), 2000, 25(11): 651. [4] HUANG Yuan-fen, HUANG Pei-pei, LUO Xiao-shan(黄远芬, 黄蓓蓓, 罗霄山). Guangdong Pharmaceutical Journal(广东药学), 2000, 6(1): 13. [5] JIANG Yan, WANG Hong-xia, BAO Zuo-yi(蒋 岩, 王红霞, 鲍作义). Virologica Sinica(中国病毒学). 1998, 19(4):306. [6] WANG Zhi-jie(王志洁). Journal of Anhui Tradition Chinese Medical College(安徽中医学院学报), 1999, 18(3): 41. [7] Jayasuriya H, Koonchanok N M, Geahien R L, et al. J. Nat. Prod., 1992, 55(5): 6968. [8] Jiang Y, Sano K, Molimatu S, et al. Japanese Archiyes of Sexually Transmitted Diseases, 1994, 5(1): 138. [9] CHEN Lei, YANG Fu-quan, ZHANG Tian-you, et al(陈 雷, 杨福全, 张天佑, 等). Journal of Instrumental Analysis(分析测试学报), 2000,19(4): 60. [10] SHU Shi-yu, LU Zhong-yi, WANG Xing-yong(舒仕瑜, 卢仲毅, 王兴勇). Journal of Pediatric Pharmacy(儿科药学杂志), 2002, 8(1): 9. [11] CAO Yong, YU Hua-zhong, LI Guo-zhang, et al(曹 庸, 于华忠, 李国章, 等). Chinese Pharmaceutical Journal(中国药学杂志), 2004, 39(5): 337. [12] ZHOU Jian-jun, ZHANG Hong-jie, YANG Pei-jun(周建军, 张宏杰, 杨培君). Chinese Medical Herb(中药材), 2005, 28(1): 31. [13] WANG Yu-xi(王玉玺). Shizhen Medicine and Material Medical Research(时珍国医国药), 2004, 15(2): 82. [14] LU Yu, HUANG Zhi-shu, MA Lin, et al(陆 豫, 黄志纾, 马 林, 等). Chinese Journal of Applied Chemistry(应用化学), 2004, 21(5): 433. [15] CAO Yong, YU Hua-zhong, ZHANG Min, et al(曹 庸, 于华忠, 张 敏, 等). Chemistry and Industry of Forest Product(林产化学与工业), 2004, 24(2): 61. [16] ZHU Li-xian, JIN Zheng-yu, TAO Guan-jun, et al(朱立贤, 金征宇, 陶冠军, 等). Chinese Traditional Patent Medicine(中成药), 2005, 27(8): 944. [17] Cooper J B. Chemometrics and Intelligent Laboratory Systems, 1999, 46(2): 231. [18] XU Yong-qun, SUN Su-qin, FENG Xue-feng, et al(徐永群, 孙素琴, 冯学峰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(3): 502. [19] Woo Y A, Kim H J, Chung H. The Analyst., 1999, 124: 1223. [20] Woo Y A, Kim H J, Cho J H, et al. Journal of Pharmaceutical and Biomedical Analysis, 1999, 21(2): 407. [21] ZHANG Jin-tun(张金屯). Mathematical Ecology Method of Vegetation(植被数量生态学方法). Beijing: China Science and Technology Press(北京: 中国科学技术出版社), 1995. 111. [22] CHENG Cun-gui, GUO Shui-liang, CHEN Jian-hua(程存归, 郭水良, 陈建华). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(6): 954. [23] JIN Xiang-jun, LI Xiao-ping, LIU Zhi-qiang, et al(金向军, 李晓萍, 刘志强, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(4): 614.