Monitoring Water in Lubricating Oil with Min-Infrared LED
YU Liang-wu1, TIAN Hong-xiang1*, MING Ting-feng1, YANG Kun2
1. College of Naval Architecture and Power, Naval University of Engineering, Wuhan 430033, China 2. School of Energy and Power Engineering, Wuhan University of Technology, Wuhan 430063, China
Abstract:A method that could be used to quantify the water concentration in ship machinery lubricating oil based on Mid-infrared LED is discussed. A Mid-infrared LED with peak emission wavelength of 2 840 nm and FWHM of 400 nm is used as the light source, the emitting light is partly absorbed by the oil sample, the remaining is received by the infrared detector. The percentage of water is determined according to the absorbance. In the experiment, a optical configuration including the transmission, absorbing and receiving of infrared light is designed, calcium fluoride wafer is used as the window, a hard metal coil with circular section is selected as the washer to get the fixed thickness of oil film accurately, a photoelectric diode with detection wavelength of 2 500~4 800 nm and response time of 10~20 ns is used as the detector of light intensity. Matching with this, a system of signal preamplifier, microcontroller-based data acquisition, storage and communication is developed. Absorbance data of six oil samples with different water mass concentration: 0, 0.062 5%, 0.125%, 0.25%, 0.375% and 0.5% is acquired through experiment. Fitting the data by the method of least squares, a linear equation in terms of absorbance and water concentration is obtained, and the determination coefficient is 0.996. Finally, in order to test the accuracy of this measurement method, using oil sample with water concentration of 0.317 5% to validate the equation, measuring the absorbance by the experimental device, the water content is calculated through the linear equation, the results show that the relative error is 2.7% between the percentage calculated and the real sample, indicating that this method can accurately measure the water concentration in the oil.
Key words:Ship machinery;Lubricating oil;Water concentration;measurements;Mid-infrared LED
余良武1,田洪祥1*,明廷锋1,杨 琨2 . 基于中红外LED的润滑油水分含量测量研究 [J]. 光谱学与光谱分析, 2015, 35(06): 1488-1492.
YU Liang-wu1, TIAN Hong-xiang1*, MING Ting-feng1, YANG Kun2 . Monitoring Water in Lubricating Oil with Min-Infrared LED . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(06): 1488-1492.
[1] TIAN Hong-xiang, LIU Yu, WANG Xin(田洪祥, 刘 瑜, 王 鑫). China Ship Repair(中国修船), 2009, 22(2): 35. [2] SUN Qi-hu, TIAN Hong-xiang, GUO Wen-yong(孙齐虎,田洪祥,郭文勇). Lubrication Engineering(润滑与密封),2006: 52. [3] ASTM D95 Test Method for Water in Petroleum Products and Bituminous Materials by Distillation. [4] GB/T 260—1977 Determination of Water Content in Petroleum Products—Distillation Method(石油产品水分测定法——蒸馏法). [5] ASTM D1744. Test Method for Water in Liquid Petroleum Products by Karl Fischer Reagent. [6] GB 6284—86. General Method for the Measurement of Water in Chemical Products—Gravimetric Method(化工产品中水分含量测定的通用方法—重量法). [7] E2412—10 Standard Practice for Condition Monitoring of In-Service Lubricants by Trend Analysis Using Fourier Transform Infrared (FT-IR) Spectrometry. [8] LI Min-zan(李民赞). Spectroscopy and Its Applications(光谱分析技术及其应用). Beijing: Science Press(北京:科学出版社),2006. 23. [9] Mohammadi L B,Kullmannn F, Holzki M, et al. Optical Sensing and Detection. 2010: 77260M-1-12. [10] Matveev B A, Gavrilov G A, Evstropov V V, et al. Sensors and Actuators B,1997,38-39: 339.