Abstract:The Keggin ⅡB element-monosubstitiuted heteropoly compounds with the stoichiometry of K7 (M=Zn, Cd) were prepared by one-pot method and characterizated via elemental analyses, FTIR, UV and XRD. The photocatalytic activity of K7 was tested vis degradation of the model molecule, methyl red (MR). After 60 min irradiation in the presence of K7 (20 mg·L-1), the degradation rate of an aqueous MR (25 μmol·L-1, pH 2) got to 95%.
[1] Kozhevnikov I V. Chem. Rev., 1998, 98: 171. [2] Mizuno N, Misono M. Chem. Rev., 1998, 98: 199. [3] Rhule J T, Hill C L, Judd D A. Chem. Rev., 1998, 98: 327. [4] Coronado E, Gómez-Garcia C J. Chem. Rev., 1998, 98: 273. [5] Gao L H, Hu X J, Zhang D S, et al. J. Nanosci. and Nanotech., 2008, 8(3): 1355. [6] Xiang H, Gao L H, Wang K Z, et al. Chin. Phys. Lett., 2003, 20(10): 1759. [7] Wang K Z, Gao L H. Synth. React. Inorg. Met-Org. Chem., 2003, 33(3): 471. [8] Kormali P, Troupis A, Triantis T, et al. Catalysis Today 2007, 124(3-4): 149. [9] Guo Y H, Hu C W. J. Molecular Catalysis A: Chemical, 2007, 262(1-2): 136. [10] Rocchiccioli-Deltcheff C, Fournier M, Franck R. Inorg. Chem., 1983, 22: 207. [11] YU Jian-feng, QIN Du-jie, WU Tong-hao, et al(于剑峰, 秦笃捷, 吴通好, 等). Acta. Phys. Chim. Sin.(物理化学学报), 1998, 14(5): 435. [12] LIU Yong, ZHOU Bai-bin, WANG Yun-peng, et al(刘 永, 周百斌, 王蕴鹏, 等). Journal of Molecular Science(分子科学学报), 2006, 22(2): 71. [13] WANG En-bo, HU Chang-wen, XU Lin(王恩波, 胡常文, 许 林). An Introduction of Polyacid Chemistry(多酸化学导论). Beijing: Chemical Industry Press(北京:化学工业出版社),1998. [14] Acerete R, Hammer C F, Baker L C W, et al. J. Am. Chem. Soc., 1982, 104: 5384. [15] ZHU Zhi-ping, LIU Jing-fu, ZHAO Ben-liang(朱志平, 刘景福, 赵本良). Journal of Inorganic Chemistry(无机化学学报), 1991, 7(4): 409. [16] HUANG Wei-hong, CHEN Yi-qun, RUAN Jie-bin, et al(黄卫红, 陈义群, 阮介兵, 等). Chinese Journal of Environmental Engineering(环境工程学报), 2008, 2(12): 1655. [17] PENG Yin, CHEN Jia-wei, Lü Tong-jie, et al(彭 银, 陈家伟, 吕同杰, 等). Science & Technology Information(科技资讯), 2008, (22): 10. [18] YU Xin-wu, TAO Hui-juan, FANG Tao(余新武, 陶慧娟, 方 涛). Journal of Functional Materials(功能材料), 2005, 36(7): 1053.