Abstract:A new method for the determination of trace Sb in plastic pipes for drinking water was found. Cu is used as a matrix modifier in the transverse-orientation Zeeman background dedution GFAAS to determine trace Sb in plastic pipes for drinking water rapidly. The ashing temperature and atomization temperature were obtained by optimization process. The influences of medium acidity were studied. The best measurement conditions were selected. The sensitivity and precision of the method were improved. Sb was detected directly with a linear range of 0.27-20.0 μg·L-1. The equation of working curve is Y= 0.006 8 X-0.000 2, r=0.999 6. The characteristic mass of the method is 6.7 pg. The detection limit is 5.4 pg. The recovery is 92.2%-102.5%. The RSDs were obtained from the data of 6 determinations at the concentration level of 5.0,10.0 and 20.0 μg·L-1 is 6.47%,4.97% and 2.45% respectively. The method is simple,rapid,accurate and of highly sensitive and precise. Satisfactory results are obtained.
Key words:GFAAS;Plastic pipes for drinking water;Trace Sb
鲁 丹,钱燕儿. 石墨炉原子吸收光谱法快速测定塑料饮水管浸出液中的痕量锑 [J]. 光谱学与光谱分析, 2004, 24(02): 242-244.
LU Dan,QIAN Yan-er . Rapid Determination of Trace Sb in Plastic Pipes for Dringing Water by GFAAS . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(02): 242-244.
[1] WANG Shi-jun editor in cheif(王世俊主编). Industry Sanitation and Occupational Disease Subject(工业卫生与职业病学). Beijing: Chemistry Industry Publishing Company(北京:化工出版社),1990. 279. [2] ZHANG Hong-tao et al(张宏陶等). The Book of Water Quality Analysis(水质分析大全). Chongqing: Chongqing Branch of Science Technology Publishing Company(重庆:科学技术出版社重庆分社), 1989. 238. [3] WANG Guang-fen(王光芬). Journal of Preventive Medicine Information(预防医学情报杂志),1996,12(4):227. [4] The Department of Legal and Supervision of Ministry of Health P. R. China(中华人民共和国卫生部法制与监督司). The Sanitation Criterion of Life Drinking Water(生活饮用水卫生规范),2001. 317.