1. Department of Physics and Labratory of Materials Physics of He'nan Province, Zhengzhou University, Zhengzhou 450052,China 2. Laboratory of Special Functional Materials, He'nan University, Kaifeng 475001,China
Abstract:Raman spectra of boron carbonitride(BCN) nanotubes made by thermal decomposition under different temperatures and with different catalysts were analysized. The intensity ratio of D to G band, ID/IG, increases and then decreases with the increase of the temperature. It was indicated that there exists an optimal temperature under which B and N incorporation is maximum. The catalysts influence also the Raman spectra of the BCN nanotubes. ID/IG is higher with cobalt/ferrocene and nickel/ferrocene than with cobalt, nickel and cobalt/nickel as catalysts. This means that better BCN nanotubes with B and N contents can be produced with the former. The results were confirmed by TEM observation.
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