EDXRF Analysis of Soil Heavy Metals on Lead-Zinc Orefield
CHU Bin-bin1,2, LUO Li-qiang1*
1. National Research Center for Geoanalysis, Beijing 100037, China 2. School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
Abstract:Due to the impact of lead-zinc mining and smelting, the soil of lead-zinc orefield and nearby areas has been widely polluted. Moreover, the concentration of lead and zinc was high, and their concentration range was wide. Furthermore, the impact of overlapping interference between low concentration As and high Pb was serious, and the lack of soil standards of lead and zinc was also a problem. According to these problems, the present work studied an effective solution to setting up the EDXRF analysis of Pb, As, Cd, Cu and Zn of soil on lead-zinc orefield. The measurable concentration of Pb was 4.4-23 600 μg·g-1, and that of Zn was 7.0-39 400 μg·g-1. The detection limit was 1.1 μg·g-1 for Pb and 0.9 μg·g-1 for Zn. The average relative error was 7.6% for Pb and 6.2% for Zn.
Key words:Lead-zinc mine;Soil heavy metals;Energy-dispersive X-ray fluorescence (EDXRF)
[1] Cappuyns V, Swennen R, Vandamme A. Journal of Geochemical Exploration, 2006, 88(1-3): 6. [2] Verner J F, Ramsey M H, Helios-Rybicka E, et al. Applied Geochemistry, 1996, 11(1-2): 11. [3] Jung M C, Thornton I. Applied Geochemistry, 1996, 11(1-2): 53. [4] Moles N R, Smyth D, Mather C E, et al. Northern Ireland. Applied Earth Science, 2004, 113: 21. [5] Wilson B, Lang B, Pyatt F B. Ecotoxicology and Environmental Safety, 2005, 60(3): 269. [6] Kachur A N, Arzhanova V S, Yelpatyevsky P V, et al. The Science of the Total Environment, 2003, 303(1-2): 171. [7] Sobanska S, Ledésert B, Deneele D, et al. Earth and Planetary Sciences, 2000, 331(4): 271. [8] Shikazono N, Zakir H M, Sudo Y. Journal of Geochemical Exploration, 2008, 98(3): 80. [9] Aslan A, Budak G, Karabulut A. Journal of Quantitative Spectroscopy and Radiative Transfer, 2004, 88(4): 423. [10] Ostachowicz J, Ostachowicz B, Hoyńska B, et al. X-Ray Spectrometry, 1995, 24(2): 81. [11] Kutle A, Nad K, Obhoda J, et al. X-Ray Spectrometry, 2004, 33(1): 39. [12] Bennet C, Jonsson P, Lindgren S. X-Ray Spectrometry, 2005, 34(1): 1. [13] Boman J, Gatari M J, Wagner A, et al. X-Ray Spectrometry, 2005, 34(5): 460. [14] Marguí E, Padilla R, Hidalgo M, et al. X-Ray Spectrometry, 2006, 35(3): 169. [15] Nguyen Thi Hong, Huynh Vinh Ha. X-Ray Spectrometry, 1996, 25(1): 3. [16] ZHAN Xiu-chun, LUO Li-qiang(詹秀春,罗立强). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 804.