光谱学与光谱分析
|
紫外光谱重叠的多组分混合物体系的同时定量测定
刘慧,胡仰栋,卢彦越
中国海洋大学化学化工学院,山东 青岛 266003
Study of Simultaneous Quantitative Analysis of Overlapping UV Spectra
LIU Hui,HU Yang-dong,LU Yan-yue
College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266003,China
摘要 : 提出一种可将紫外吸收光谱严重重叠的混合物体系准确定量分析的方法。该方法利用系统聚类结合加和性检验而得的优化波长集合有效地降低了混合物光谱的相关性。通过选取优化波长集合内的波长点的信息,把吸光系数和待测浓度同时作为自变量,建立非线性优化模型,对于组分间浓度差较小的混合物体系经一次优化分析计算可得待测浓度;混合物中组分浓度差较大的体系经四次左右优化迭代,逐步降低误差的分析结果,相对误差可控制在3.63%之内。分析结果表明该法稳定、准确、简便快速,可对多组分混合物体系进行定量测定。
关键词 :紫外光谱;系统聚类;多组分定量分析;迭代;非线性规化
Abstract :The simultaneous multi-component quantitative determination was proposed without any chemical separation procedure. The method uses optimum wavelength gather obtained after hierarchical clustering and additive validation to reduce correlation of the component spectra. Information of 30 wavelength points after hierarchical clustering analysis was taken and,with the information of optimum wavelength gather,the absorptivity coefficient and component concentration of solutions were treated as independent variables,and a constrained optimization model was set up. The concentration awaiting test can be obtained after one optimization calculation for the mixed solution in which the concentration of every component is close to each other. But for some solutions in which component concentration is not close to each other,iterative optimization is necessary. The final results obtained are satisfying with a good accuracy and precision only after about 4 times of iterations,and the relative error can be controlled in 3.63%. So this method can be used for quantitative analysis of overlapping UV spectra.
Key words :Ultraviolet spectra;Hierarchical clustering;Multi-component quantitative analysis;Iteration;Nonlinear programming
收稿日期: 2006-03-10
修订日期: 2006-06-16
通讯作者:
刘慧
E-mail: huizi421@126.com
引用本文:
刘慧,胡仰栋,卢彦越. 紫外光谱重叠的多组分混合物体系的同时定量测定[J]. 光谱学与光谱分析, 2007, 27(07): 1416-1419.
LIU Hui,HU Yang-dong,LU Yan-yue. Study of Simultaneous Quantitative Analysis of Overlapping UV Spectra . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(07): 1416-1419.
链接本文:
https://www.gpxygpfx.com/CN/Y2007/V27/I07/1416
[1] ZHANG Li-qing,WU Xiao-hua,TANG Xi,et al(张立庆,吴晓华,唐 曦,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(3): 427. [2] GAO Ling,REN Shou-xin(高 玲,任守信). Journal of Analytical Science(分析科学学报),2004,20(6): 607. [3] SUN Xiu-yun,LI Yan,WANG Jun-de(孙秀云,李 燕,王俊德). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2003,23(4): 739. [4] LI Zhi-liang,ZENG Ge-ming,XIA Zhi-ning,et al(李志良,曾鸽鸣,夏之宁,等). Analytical Instrumentation(分析仪器),1998,2: 46. [5] Liu Shiqing,Wang Weiwen. Chemometrics and Intelligent Lab Systems,1999,45,131. [6] FANG Kai-tai,PAN En-pei(方开泰,潘恩沛). Cluster Analysis(聚类分析). Beijing: Geologic Press(北京: 地质出版社),1982. 37. [7] SUN Xiao-yun,HU Yang-dong,LU Yan-yue(孙小云,胡仰栋,卢彦越). Computers and Applied Chemistry(计算机与应用化学),2005,22(9): 720. [8] DUAN Hui-qi,LU Xiao-hua(段慧琦,陆晓华). Journal of Analytical Science(分析科学学报),2003,19(1): 86. [9] ZHANG Li-qing,LI Ping,MU Jie(张立庆,李 萍,穆 洁). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(10): 1238. [10] ZHENG Jing,LIN Kai-li,ZHOU Wei-liang(郑 静,林开利,周伟良). Analytical Laboratory(分析试验室),2004,23(11): 14. [11] YIN Chun-sheng,SHEN Yang,et al(印春生,沈 阳,等). Chemical Research in Chinese Universities(高等学校化学学报),2000,21(1): 49.
[1]
安柏耸,王雪梅,黄晓宇,卡吾恰提·白山. 基于随机蛙跳波段选择算法的土壤铅含量高光谱估测 [J]. 光谱学与光谱分析, 2023, 43(10): 3302-3309.
[2]
朱自民,邢 键. 基于二分迭代递推的多光谱辐射测温反演算法 [J]. 光谱学与光谱分析, 2023, 43(09): 2674-2678.
[3]
常 振,钟鸣宇,苏静明,司福祺,王 煜,周海金,窦 科,张 泉. MAX-DOAS重建NO2 竖直平面分布的方法研究 [J]. 光谱学与光谱分析, 2023, 43(08): 2413-2418.
[4]
蒋大鹏,高礼彬,陈金浩,张怡卓. 木材抗拉强度的近红外光谱MC-UVE-IVSO建模方法 [J]. 光谱学与光谱分析, 2023, 43(08): 2488-2493.
[5]
李子仪,李瑞兰,李灿琳,王柯入,范久余,古 锐. 傅里叶红外光谱结合化学计量学的渣驯优劣鉴别研究 [J]. 光谱学与光谱分析, 2023, 43(02): 526-532.
[6]
张雪菲,段 宁,降林华,程 雯,于兆胜,李维栋,朱广彬,徐艳丽. 深紫外分光光度检测系统的稳定性及灵敏度研究 [J]. 光谱学与光谱分析, 2022, 42(12): 3802-3810.
[7]
郑开逸,沈 烨,张 文,周晨光,丁福源,张 钖,张柔佳,石吉勇,邹小波. 双光谱区间遗传算法及其在模型转移中的应用 [J]. 光谱学与光谱分析, 2022, 42(12): 3783-3788.
[8]
韩嘉庆,周桂霞,胡 军,程介虹,陈争光,赵胜雪,刘奕伶. 改进的随机蛙跳算法对农机润滑油污染浓度的近红外光谱检测研究 [J]. 光谱学与光谱分析, 2022, 42(11): 3482-3488.
[9]
陈维娜,国中正,李开开,杨玉柱,杨 旭. 显微共聚焦拉曼光谱技术结合化学计量法鉴别静电复印纸 [J]. 光谱学与光谱分析, 2022, 42(07): 2033-2038.
[10]
陈凤霞,杨天伟,李杰庆,刘鸿高,范茂攀*,王元忠*. 基于偏最小二乘法判别分析与随机森林算法的牛肝菌种类鉴别 [J]. 光谱学与光谱分析, 2022, 42(02): 549-554.
[11]
. 基于密度泛函理论的肾上腺素分子的光谱分析 [J]. 光谱学与光谱分析, 2022, 42(01): 248-252.
[12]
. 基于密度泛函理论的维生素C紫外光谱与激发性质的计算 [J]. 光谱学与光谱分析, 2022, 42(01): 304-309.
[13]
. β-CD降低AEO-9对紫外光谱检测TDBAC的影响 [J]. 光谱学与光谱分析, 2021, 41(12): 3931-3935.
[14]
. Lucy-Richardson迭代解谱在X射线荧光分析的应用 [J]. 光谱学与光谱分析, 2021, 41(09): 2823-2828.
[15]
. WCARS-ISPA火焰光谱特征选择的转炉炼钢终点预测 [J]. 光谱学与光谱分析, 2021, 41(08): 2332-2336.