Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) Complexes With the Widely Used Herbicide 2,4-Dichlorophenoxyacetic Acid
Lamia A. Albedair
Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia
Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) Complexes With the Widely Used Herbicide 2,4-Dichlorophenoxyacetic Acid
Lamia A. Albedair
Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia
摘要: 2,4-Dichlorophenoxyacetic acid (2,4-D) is a board-leaf selective herbicide and globally used in agricultural activities. Complexation mode, spectroscopic investigations and biological properties of complexes formed between 2,4-D (C6H3Cl2OCH2·COOH; HL) with Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) metal ions were investigated. To characterize the binding mode between 2,4-D and the metal ions, many physicochemical approaches were employed. The complexes obtained are characterized quantitatively and qualitatively by using micro elemental analysis, FTIR spectroscopy, UV-Vis spectroscopy, 1H-NMR, and magnetic susceptibility measurements. Results of these approaches suggested that the gross formula of the complexes obtained with the metal ions were [ZnL2](2H2O (1), [CuL2(H2O)2] (2), [NiL2](3H2O (3), [CoL2(H2O)2] (4), and [MnL2(H2O)2] (5). In all complexes, two L- anion were coordinated the metal ion by their bidentate carboxylate groups. From the spectral study, all the complexes obtained as monomeric structure and the metals center moieties are six-coordinated with octahedral geometry except Ni(Ⅱ) and Zn(Ⅱ) complexes which existed as a tetrahedral and square pyramidal geometry respectively. The complexes were screened in vitro against several microbes (fungi and bacteria) using Kirby-Bauer disc diffusion method, and data has demonstrated that complex 3 showed excellent antifungal activity.
Abstract:2,4-Dichlorophenoxyacetic acid (2,4-D) is a board-leaf selective herbicide and globally used in agricultural activities. Complexation mode, spectroscopic investigations and biological properties of complexes formed between 2,4-D (C6H3Cl2OCH2·COOH; HL) with Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) metal ions were investigated. To characterize the binding mode between 2,4-D and the metal ions, many physicochemical approaches were employed. The complexes obtained are characterized quantitatively and qualitatively by using micro elemental analysis, FTIR spectroscopy, UV-Vis spectroscopy, 1H-NMR, and magnetic susceptibility measurements. Results of these approaches suggested that the gross formula of the complexes obtained with the metal ions were [ZnL2](2H2O (1), [CuL2(H2O)2] (2), [NiL2](3H2O (3), [CoL2(H2O)2] (4), and [MnL2(H2O)2] (5). In all complexes, two L- anion were coordinated the metal ion by their bidentate carboxylate groups. From the spectral study, all the complexes obtained as monomeric structure and the metals center moieties are six-coordinated with octahedral geometry except Ni(Ⅱ) and Zn(Ⅱ) complexes which existed as a tetrahedral and square pyramidal geometry respectively. The complexes were screened in vitro against several microbes (fungi and bacteria) using Kirby-Bauer disc diffusion method, and data has demonstrated that complex 3 showed excellent antifungal activity.
基金资助: the deanship of scientific Research at Princess Nourah bint Abdulrahman University through the Fast-track Research Funding program
作者简介: lamiaalbedair@gmail.com
引用本文:
Lamia A. Albedair. Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) Complexes With the Widely Used Herbicide 2,4-Dichlorophenoxyacetic Acid[J]. 光谱学与光谱分析, 2021, 41(06): 1982-1987.
Lamia A. Albedair. Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) Complexes With the Widely Used Herbicide 2,4-Dichlorophenoxyacetic Acid. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1982-1987.
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