Effect of Biomimetic Respiration Method on the Impregnation Effect of Silicate Modified Chinese Fir by XPS and FTIR Analysis
LI Ping1,2, WU Yi-qiang1, LÜ Jian-xiong3, YUAN Guang-ming1, ZUO Ying-feng1*
1. College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China
2. College of Art and Design, Xiangnan University, Chenzhou 423000, China
3. Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China
Abstract：After silicate impregnation, the content and distribution of elements in the modifier is an important index to evaluate the impregnation effect, which plays an important role in the physical and mechanical properties of the modified Chinese fir. The effects of the biomimetic respiration method on the density, bending strength, compressive strength, three section hardness and 24 h water absorption of silicate modified Chinese fir were studied. The chemical composition and structure of unmodified and modified Chinese fir were analyzed by XPS and FTIR, and the distribution depth and law of silicate modifier in the modified Chinese fir were discussed. The results showed that the average density of the modified Chinese fir was more than 0.721 g·cm-3, the bending strength and compressive strength increased by 170.19% and 286.64%, respectively. The hardness of the transverse section, radial section and tangential section of the modified Chinese fir increased in different degrees. The 24h water absorption of Chinese fir decreased from 91.17%±2.51% to 39.23%±1.62% after silicate modification, which indicated that the dimensional stability of Chinese fir was greatly improved. Compared with the unmodified Chinese fir, the absorption peaks of Na and Si elements appear in the XPS full-spectrum scanning of the modified Chinese fir wood, and the chemical structures of Si—O—C and Na-O appear in the narrow spectrum scanning. At the same time, the absorption peak of Si—O—Si appeared in the FTIR spectrum of the modified Chinese fir wood, the content of free hydroxyl decreased, and the associated hydroxyl increased. XPS and FTIR analysis showed that silicates were impregnated into the pores of Chinese fir wood, and sodium silicate formed a chemical bond and hydrogen bond with hydroxyl in Chinese fir wood. This was also an important reason for the improvement of mechanical properties and water resistance of modified Chinese fir. In addition, it was found by XPS that C, O, Na and Si elements appeared along the transverse direction from the surface to 30 mm. The absorption peak intensity of Si—O—C bonding structure was basically the same from the surface to 30 mm, which indicated that the chemical bond between sodium silicate and hydroxyl groups in Chinese fir wood was formed more evenly from the surface to the middle part.It was found that the relative contents of C, O, Na and Si element in the modified Chinese fir wood were slightly different from the surface to the middle part (30 mm). The results showed that the modifier was in the middle of Chinese fir wood, and the uniformity was good. The research results will provide data support for the impregnation modification effect of Chinese fir, and provide the basis for optimizing the modification process and method, and further improving the physical and mechanical properties of modified Chinese fir.
李 萍，吴义强，吕建雄，袁光明，左迎峰. XPS和FTIR分析仿生呼吸法对硅酸盐改性杉木浸渍效果的影响[J]. 光谱学与光谱分析, 2021, 41(05): 1430-1435.
LI Ping, WU Yi-qiang, LÜ Jian-xiong, YUAN Guang-ming, ZUO Ying-feng. Effect of Biomimetic Respiration Method on the Impregnation Effect of Silicate Modified Chinese Fir by XPS and FTIR Analysis. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1430-1435.
[1] ZHANG Wei-gang, BAO Bin-fu, LIU Jun-liang, et al（章卫钢, 鲍滨福, 刘君良, 等）. China Wood Industry（木材工业）, 2009, 23(2): 34.
[2] Yao M, Yang Y, Song J, et al. Industrial Crops and Products, 2017, 107: 38.
[3] Kamke F A, Lee J N. Wood and Fiber Science, 2007, 39(2): 205.
[4] HUANG Yan-hui, FEI Ben-hua, ZHAO Rong-jun（黄艳辉, 费本华, 赵荣军）. Spectroscopy and Spectral Analysis（光谱学与光谱分析）, 2015, 35(12): 3356.
[5] Lu J, Lin Z, Jiang J, et al. Journal of Forestry Research, 2005, 16(4): 293.
[6] Mahdian M, Huang L Y, Kirk D W, et al. Microporous and Mesoporous Materials, 2020, 303: 110258.
[7] Zuo Y, Gu J, Zhang Y, et al. Journal of Adhesion Science and Technology, 2012, 26(10-11): 1685.
[8] Pérez J, Munoz-Dorado J, De la Rubia T, et al. International Microbiology, 2002, 5(2): 53.
[9] Alexandre M, Dubois P. Materials Science & Engineering: R: Reports, 2000, 28(1-2): 1.
[10] Li P, Zhang Y, Zuo Y, et al. Journal of Materials Research and Technology, 2020, 9(1): 1043.
[11] Powell C J, Larson P E. Applications of Surface Science, 1978, 1(2): 186.
