卟啉钯敏化剂构效性质与三线态-三线态湮灭上转换性能研究

叶常青, 于雪, 陈硕然, 梁作芹, 周宇扬, 王筱梅^*

Study on the Structure/Energy-Level of Palladuim-Porphyrin Sensitizers on the Triplet-Triplet-Annihilation Upconversion Performance

YE Chang-qing, YU Xue, CHEN Shuo-ran, LIANG Zuo-qin, ZHOU Yu-yang, WANG Xiao-mei^*

在532 nm半导体激光器激发下(功率400 mW·cm^-2), 随发光剂浓度增加得到的上转换光谱及效率曲线; (a, b)PdOEP(10 μmol·L^-1); (c, d)PdBrTPP (4 μmol·L^-1), Rh6G荧光光谱作为参比(实际数据缩6倍展示), 溶剂为脱气正丙醇