红外和拉曼光谱在金属氢化物结构分析中的应用

doi:10.3964/j.issn.1000-0593(2018)01-0008-07

Abstract
References
Related Citation (15)

Download: PDF (2737 KB)
Export: BibTeX | EndNote (RIS)

Abstract Infrared and Raman spectroscopy are powerful technologies in metal hydrides structure analysis. If theoretical calculation is combined with Infrared and Raman analysis technology, they can provide information on the local bonding environment between metal atoms and hydrogen atoms of binary (MgH₂, CaH₂, AlH₃) and ternary (Mg₂FeH₆) metal hydrides. Thereby, different phase structures of metal hydrides can be identified, they can also provide structure difference information in ternary metal hydride M₂RuH₆ (M=Ca, Sr, Eu) due to the different metal atom composition, and the structure differences between ternary metal hydride and deuteride also can be obtained. Moreover, the structure change of metal hydride can be monitored during compression and decompression by in situ Raman spectroscopy analysis, which helps us interpret diffraction data deeply. In order to avoid the disadvantageous effect of air and moisture on FTIR experiment results, PAIR spectrum was developed to increase the intensities of Infrared and Raman combination bands. Infrared and Raman spectroscopy even can be applied on metal tritides structure analysis, and it can provide the information on the local bonding differences between metal atoms and hydrogen isotopic atoms which helped us research the hydrogen isotopic effect better. Raman spectroscopy has also been used to in situ monitoring of the formation and decomposition of metal hydride under high pressure or high temperature, and has also been successfully applied in hydrogen isotope mixture gases analysis, such as tritium analysis and management in ITER project. If structure analysis is combined with hydrogen isotope mixture gas analysis by Infrared and Raman, the reaction kinetics and isotopic effect between metal and hydrogen isotope gases reaction can be researched.

Key words：Metal hydrides; Infrared; Raman; Structure

Received: 2016-05-21 Accepted: 2016-10-10

ZTFLH:

O611.7

Corresponding Authors: PENG Shu-ming E-mail: chenmiao409@126.com

Cite this article:

URL:

https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2018)01-0008-07 OR https://www.gpxygpfx.com/EN/Y2018/V38/I01/8

[1] Louis Schlapbach, Andreas Züttel. Nature, 2001, 414: 353.
[2] Billur Sakintuna, Farida Lamari-Darkrim, Michael Hirscher. International Journal of Hydrogen Energy, 2007, 32：1121.
[3] Michael Hirscher. Handbook of Hydrogen Storage. WILEY-VCH Verlag Gmbh＆Co. KGaA, Weinheim, 2010. 83.
[4] Lsser R. Tritium and Helium-3 in Metals. Berlin Heidelberg, Springer-Verlag, 1989. 22.
[5] JIANG Guo-qiang, LUO De-li, LU Guang-da, et al(蒋国强, 罗德礼, 陆光达, 等). Tritium and Industry Techniques of Tritium(氚和氚的工程技术). Beijing: National Defense Industry Press(北京: 国防工业出版社), 2007. 407
[6] YANG Ke, SONG Li, Lü Man-qi(杨柯, 宋莉, 吕曼祺). Chinese Atomic Energy Science and Technology(原子能科学技术), 2004，38(4): 328.
[7] Parker S F. Coordination Chemistry Reviews, 2010, 254: 215.
[8] Reed D, Book D. Current Opinion in Solid State and Materials Science, 2011, 15: 62.
[9] Santisteban J R, Cuello G J, Dawidowski J, et al. Physical Review B, 2000，62(1): 37.
[10] Lasave J, Dominguez F, Koval S, et al. J. Phys: Condens. Matter., 2005, 17: 7133.
[11] Kuzovnikov M A, Efimchenko V S, Filatov E V, et al. Solid State Communications, 2013, 154: 77.
[12] Li Bing, Li Yinwei, Yang Kaifeng, et al. J. Phys: Condens. Matter., 2007, 19: 226205.
[13] Tkacz M, Palasyuk T, Graetz J, et al. J. Raman Spectrosc., 2008, 39: 922.
[14] Wang Yan, Yan Jiaan, Chou M Y. Physical Review B, 2008, 77: 014101.
[15] Manciu F S, Reza L, Durrer W G, et al. J. Raman Spectrosc., 2011, 42: 512.
[16] Vadym Drozd, Subrahmanyam Garimella, Surendra Saxena, et al. The Journal of Physical Chemistry C, 2012, 116: 3808.
[17] Zhou H L, Yu Y, Zhang H F, et al. Eur. Phys. J. B, 2011, 79: 283.
[18] Lester Andrews, Wang Xuefeng. Journal of Chemical Physics, 2001，114(4): 1559.
[19] Wang Xuefeng, Lester Andrews. J. Phys. Chem. A，2003, 107: 4081.
[20] Wang Xuefeng, Lester Andrews. J. Phys. Chem. A，2004, 108: 11511.
[21] Wang Xuefeng, Lester Andrews. J. Phys. Chem. A，2005, 109: 9021.
[22] Roger Domènech-Ferrer, Frank Ziegs, Sabrina Klod, et al. Analytical Chemistry, 2011, 83：3199.
[23] Shinsuke Yamanaka, Kazuriho Yamada, Ken Kurosaki, et al. Journal of Alloys and Compounds, 2002, 330-332: 99.
[24] Parker S F, Williams K P J, Bortz M, et al. Inorg. Chem., 1997, 36: 5218.
[25] Hans Hagemann, Ralph O Moyer. Journal of Alloys and Compounds, 2002, 330-332: 296.
[26] Barsan M M, Butler I S, Gilson D F R, et al. The Journal of Physical Chemistry A, 2012, 116: 2490.
[27] Barsan M M, Moyer R O Jr, Butler I S, et al. Journal of Alloys and Compounds, 2006, 424: 73.
[28] WANG Hong-zu, SHEN Chun-lei, LONG Xing-gui, et al(王洪祖，沈春雷，龙兴贵，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2013, 33(3), 991.
[29] Sturm M, Schlsser M, Lewis R J, et al. Laser Physics, 2010, 20：493.
[30] Godot A, Coindet G, Hubinois J C. Fusion Science and Technology, 2011, 60：998.
[31] Demange D, Alecu C G, Bekris N, et al. Fusion Engineering and Design, 2012, 87：1206.
[32] Simone Rupp, Timothy M James, Helmut H Telle, et al. Fusion Science and Technology, 2015, 67：547.
[33] Magnus Schlsser, Oskari Pakari, Simone Rupp, et al. Fusion Science and Technology, 2015, 67：559.
[34] Magnus Schlsser, Beate Bornschein, Sebastian Fischer, et al. Fusion Science and Technology, 2015, 67：555.