光谱学与光谱分析 |
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Rapid Method for Determination of Furfural and 5-Hydroxymethyl Furfural of Ethanol-Water Hydrolysate of Biomass with UV Spectroscopy |
PAN Meng-li, PING Qing-wei*, ZHANG Jian, LI Na |
Dalian Polytechnic University, Liaoning Province Key Laboratory of Pulp and Paper, Dalian 116034, China |
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Abstract The soluble lignin and furan compounds in hydrolysate of lignocellulose biomass have absorbed peaks and inter-superimpose in UV spectroscopy. Therefore, this paper developed a method for the determination of furfural and 5-hydroxymethyl furfural in ethanol-water refining liquors of lignocellulose biomass based on UV spectroscopy. The study showed that there is a good and linear relationship between maximum absorption (λmax) and the concentration percent of 5-HMF (W5-HMF) of M, the regression coefficient up to 0.998 4 (R2=0.998 4). Furthermore, a better linear relationship was also observed between the concentration of mixture (cM) and absorptivity (A) when the W5-HMF was constant, the R2 of 0.998 6~1.000 0 and reproducibility are desirable. The contents of F and 5-HMF could be calculated accurately according to the perfect liner relationship of A and cM, λmax and W5-HMF, and the relative deviation of F and 5-HMF of 5.6% and 3.7%, recovery of 89%~96%, RSD of 0.21%~0.85%, respectively. Overall, The simple rapid and precise method in this paper can be applied to the determination of the F and 5-HMF in the hydrolysate of ethanol-water refining lignocellulose biomass.
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Received: 2015-08-22
Accepted: 2015-12-16
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Corresponding Authors:
PING Qing-wei
E-mail: pingqw@dlpu.edu.cn
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