光谱学与光谱分析 |
|
|
|
|
|
Structure Effect on K Shell Fluorescence Parameters at Bis-4-Bromobenzyl-1,2,4-Triazol-3-Ones |
V. Aylkc1*, Y. ünver2, N. Kup Aylkc3, E. T r o lu4, K. Sancak2, Z. Laap2 |
1. Department of Metallurgical and Materials Engineering, Faculty of Technology, skenderun Technical University, 31040, Hatay, Turkey 2. Department of Chemistry, Faculty of Science, Karadeniz Technical University, 61080, Trabzon, Turkey 3. Department of Energy Systems Engineering, Faculty of Technology, skenderun Technical University University, 31040, Hatay, Turkey 4. Department of Physics, Faculty of Sciences, Karadeniz Technical University, 61080, Trabzon, Turkey |
|
|
Abstract In this study; the effect of the electron density over the Br atoms raising with increasing number of CH2 group using the results of the K X-ray cross-sections and average fluorescence yields of bromine in quaternary-imidazole ring. In the experimental set-up, 50 mCi 241Am source and a collimated Ultra-LEGe detector were used. The electron density on the Br atoms raises according to the number of the CH2 groups on the contrary of the inductive effect. The decreasing of the X-ray fluorescence parameters is interested with the increasing the electron density of Br atoms.
|
Received: 2015-04-10
Accepted: 2015-07-29
|
|
Corresponding Authors:
V. Aylkc
E-mail: vaylikci@mku.edu.tr
|
|
[1] Isloor A M, Kalluraya B, Rao M, et al. Chem. Soc., 2000,4:265. [2] Amir M, Kumar H, Javed S A. Eur. J. Med. Chem.,2008,43(10):2056. [3] Sztanke K, Tuzimski T, Rzymowska J, et al. Eur. J. Med. Chem.,2008,43(2):404. [4] Kus C, Klcgil G A, zbey S, et al. Bioorg. Med. Chem.,2008,16(8):4294. [5] Padmavathi V, Thriveni P, Sudhakar G,et al. Eur. J. Med. Chem.,2008,43(5):917. [6] Kalluraya B, Isloor A M, Shenoy S. Indian J. Heterocycl. Chem.,2001,11:159. [7] Kalluraya B, Isloor A M, Priya F V, et al. Indian J. Heterocycl. Chem.,2004,13(3):245. [8] Koparir M, Orek C, Parlak A E, et al. European Journal of Medicinal Chemistry,2013,63:340. [9] Brunner G, Nagel M, Hartmann E. E. Arnt, J. Phys. B: At. Mol. Phys.,1982,15:4517. [10] Folkmann F. Nucl. Instr. and Meth. B,1996,109/110:39. [11] Raj S, Padhi H C, Polasik M. Nucl. Instr. and Meth. B, 1998, 145: 485. [12] Mukoyama T, Taniguchi K, Adachi H. X-Ray Spectrom., 2000,29:426. [13] Raj S, Padhi H C, Polasik M. Nucl. Instr. and Meth. B, 2000, 160: 443. [14] Mukoyama T, Taniguchi K, Adachi H. Phys. Rev. A, 2001, 63: 042514. [15] Kawai J, Ohta M, Konishi T. Analytical Sciences, 2005, 21: 865. [16] Mukoyama T, Kaji H, Taniguchi K, et al. X-Ray Spectrom.,1997,26:269. [17] Kulshreshtha S K, Wagh D N, Bajpei H N. X-Ray Spectrom., 2005, 34: 200. [18] Porikli S, Han I, Yaln P, et al. Spectroscopy Letters,2011,44:38. [19] Sogut O, Seven S, Baydas E, et al. Spectrochim. Acta, Part B,2001,56:1367. [20] Iwatsuki M, Fukasawa T. X-Ray Spectrom.,1987,16:73. [21] Kucukonder A. Eur. Phys. J. D,2001,17:293. [22] Kucukonder A, Sogut O, Buyukkasap E, et al. X-Ray Spectrom.,2003,32:60. [23] Aylikci V, Unver Y, Dugdu E, et al. Chem. Phys. Lett.,2013,556:365. [24] Berger M J, Hubbell J H. XCOM: Photon Cross-Sections on a Personnel Computer (version 1.2), NBSIR85-3597, National Bureau of Standarts, Gaithersburg, MD, USA, for version 3.1, 1999, see http://physics.nist.gov/. [25] Apaydin G, Aylikci V, Biyiklioglu Z, et al. Chinese J. Chem. Phys.,2008,21:591. [26] Scofield H. Lawrence Livermore Laboratory (UCRL), 1973. 51326. [27] Aylikci V, Cengiz E, Apaydin G, et al. Chem. Phys. Lett.,2008,461:332. [28] Krause M O. J. Phys. Chem. Ref., 1979, Data 8, 307. |
[1] |
N. Kup Aylıkcı1*, Y. Unver2, V. Aylıkcı3, D. Unluer2, E. Dugdu2. The Investigation of K Shell X-Ray Fluorescence Parameters for Sulphur Atom in Different 1,2,4-Triazoles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2961-2965. |
[2] |
V. Aylikci. K Shell and L Subshell Photoeffect Cross-Sections of Some Elements in the Atomic Range 50≤Z≤65 at 59.5 keV[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(01): 29-33. |
|
|
|
|