光谱学与光谱分析 |
|
|
|
|
|
Quantitative Analysis of Mg, Fe and Ca in Jade with Laser Induced Breakdown Spectroscopy |
MA Fang-li, DONG Qian-min*, LIANG Pei, WU Yan-xiong |
College of Opto-Electronic Science and Technology, China Jiliang University, Hangzhou 310018, China |
|
|
Abstract Based on laser induced breakdown spectroscopy and X-ray fluorescence spectroscopy, The calibration curve of the main elements Mg, Cr and trace element Fe in the Jade samples is obtained based on experimental results. In the experiment, LIBS experiment conditions were 3 μs delay, 110 accumulated laser pulse, 100 mJ·pulse-1, 10 Hz pulse repetition frequency, plasma in Nanyang jade was induced using nono-second Nd∶YAG (wavelength: 1 064 nm) laser as the excitation source in the atmosphere envtronment of the laboratory. The spectral lines in the 300~1 000 nm wavelength range have been identified with the laser-induced breakdown spectroscopy. Through comparing the characteristic spectrum with the National Institute of standards and Technology Research Institute (NIST) database, the element of Mg, Ca and Fe are found in the Jade samples. Using the X-ray fluorescence spectra analyzed the metal elements Mg, Cr and Fe in Nanyang standard jade and obtained the content of elemental oxides, taking the content as standard data and selecting the high content element Al as internal standard element. According to LIBS calibration curve, we can calculate the content of 3 elements in the measured sample. The result shows that the concentration of elements locate in their corresponding standards range, for example, go(0.28%~1.73%), and Fe2O3 (0~0.8%), CaO ( 18%~20%).Because of its unique features, like the absence of sample preparation, the ability to perform real-time, and in situ analysis as well as the quasi non-destruction and micro-analysis character of the measurements, so as to verify the feasibility of LIBS application in jade.
|
Received: 2015-07-10
Accepted: 2015-11-15
|
|
Corresponding Authors:
DONG Qian-min
E-mail: qmdong@cjlu.edu.cn
|
|
[1] WANG Kai, GAN Fu-xi, ZHAO Hong-xia(王 凯, 干福熹, 赵虹霞). Journal of the Chinese Ceramic Society(硅酸盐学报), 2015, 43: 205. [2] RAN Xiao-hong, LU Li, WU Jian(冉晓红, 鲁 力, 吴 健). Resources Environment &Engineering(资源环境与工程), 2015, 29: 91. [3] M-ablet, FANG Yan(阿布来提·麦麦提, 方 炎). The Journal of Light Scattering(光散射学报), 2013, 25(2): 147. [4] LI Guan, JIANG Jie, ZHANG Qian(李 关, 姜 杰, 张 谦). Chinese J. Lasers(中国激光), 2011, 38(7): 0715002. [5] Fayeac B, Amodeoa T, Frejafon E. Spectrochimica Acta Part B, 2014, 91: 5. [6] Giacomo A D, Gaudiuso R, Koral C. Anal. Chem., 2013, 85(21): 10180. [7] JI Qin, SHA Wen, LU Cui-ping(季 琴, 沙 文, 鲁翠萍). Applied Laser(应用激光), 2015, 35(1): 110. [8] LIU Yue-hua, CHEN Ming, LIU Xiang-dong(刘月华, 陈 明, 刘向东). Acta Phys. Sin.(物理学报), 2013, 62: 025203. [9] Bahreinim, Ashrafkhani B, Tavassoli S H. Applied Physics B, 2014, 114(3): 439. [10] Mildner J, Sarpe C, Gtte N, et al. Appl. Surf. Sci., 2014, 302: 291. [11] Clegg S M, Wiens R, Misra A K, et al. Appl. Spectrosc., 2014, 68: 925. [12] YU Qi, MA Xiao-hong, WANG Rui, et al(余 琦, 马晓红, 王 锐, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2014, 34(11): 3095. [13] Pareja J, Lo′ pez S,Jaramillo D,et al. Appl. Opt., 2013, 52: 2470. |
[1] |
LIU Jia1, 2, GUO Fei-fei2, YU Lei2, CUI Fei-peng2, ZHAO Ying2, HAN Bing2, SHEN Xue-jing1, 2, WANG Hai-zhou1, 2*. Quantitative Characterization of Components in Neodymium Iron Boron Permanent Magnets by Laser Induced Breakdown Spectroscopy (LIBS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 141-147. |
[2] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
[3] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
[4] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1,ZHAO Yan-jie1*,NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
[5] |
YANG Wen-feng1, LIN De-hui1, CAO Yu2, QIAN Zi-ran1, LI Shao-long1, ZHU De-hua2, LI Guo1, ZHANG Sai1. Study on LIBS Online Monitoring of Aircraft Skin Laser Layered Paint Removal Based on PCA-SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3891-3898. |
[6] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
[7] |
SUN Cheng-yu1, JIAO Long1*, YAN Na-ying1, YAN Chun-hua1, QU Le2, ZHANG Sheng-rui3, MA Ling1. Identification of Salvia Miltiorrhiza From Different Origins by Laser
Induced Breakdown Spectroscopy Combined with Artificial Neural
Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3098-3104. |
[8] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
[9] |
ZHAO Yang1, ZHANG Lei2, 3*, CHENG Nian-kai4, YIN Wang-bao2, 3*, HOU Jia-jia5, BAI Cheng-hua1. Research on Space-Time Evolutionary Mechanisms of Species Distribution in Laser Induced Binary Plasma[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2067-2073. |
[10] |
ZHOU Qing-qing1, LI Dong-ling1, 2, JIANG Li-wu1, 3*, WAN Wei-hao1, ZENG Qiang4, XUE Xin4, WANG Hai-zhou1, 2*. Quantitative Statistical Study on Dendritic Component Distribution of Single Crystal Blade Based on Microbeam X-Ray Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2112-2118. |
[11] |
WANG Bin1, 2, ZHENG Shao-feng2, GAN Jiu-lin1, LIU Shu3, LI Wei-cai2, YANG Zhong-min1, SONG Wu-yuan4*. Plastic Reference Material (PRM) Combined With Partial Least Square (PLS) in Laser-Induced Breakdown Spectroscopy (LIBS) in the Field of Quantitative Elemental Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2124-2131. |
[12] |
HU Meng-ying1, 2, ZHANG Peng-peng1, 2, LIU Bin1, 2, DU Xue-miao1, 2, ZHANG Ling-huo1, 2, XU Jin-li1, 2*, BAI Jin-feng1, 2. Determination of Si, Al, Fe, K in Soil by High Pressure Pelletised Sample and Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2174-2180. |
[13] |
LI Chang-ming1, CHEN An-min2*, GAO Xun3*, JIN Ming-xing2. Spatially Resolved Laser-Induced Plasma Spectroscopy Under Different Sample Temperatures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2032-2036. |
[14] |
DU Zhi-heng1, 2, 3, HE Jian-feng1, 2, 3*, LI Wei-dong1, 2, 3, WANG Xue-yuan1, 2, 3, YE Zhi-xiang1, 2, 3, WANG Wen1, 2, 3. A New EDXRF Spectral Decomposition Method for Sharpening Error Wavelets[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1719-1724. |
[15] |
WU Shu-jia1, 2, YAO Ming-yin2, 3, ZENG Jian-hui2, HE Liang2, FU Gang-rong2, ZENG Yu-qi2, XUE Long2, 3, LIU Mu-hua2, 3, LI Jing2, 3*. Laser-Induced Breakdown Spectroscopy Detection of Cu Element in Pig Fodder by Combining Cavity-Confinement[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1770-1775. |
|
|
|
|