光谱学与光谱分析 |
|
|
|
|
|
Adaptability of Different Nebulizer Systems to Different Silicon Chemical Forms for Gasoline in Inductively Coupled Plasma Optical Emission Spectrometry |
ZHAO Yan, CHEN Xiao-yan*, XU Dong-yu, ZHANG Shi-yuan, LIAO Jia |
Shenzhen Academy of Metrology Quality and Inspection,Shenzhen 518131,China |
|
|
Abstract Silicon is not a natural component of gasoline but it can cause silica deposition in vehicle combustion system which may lead to severe engine failure. Silicon is present in gasoline in different chemical forms. The analysis of oil products by directly measuring under organic phase through inductively coupled plasma optical emission spectrometry (ICP-OES) is becoming a widely accepted approach as it is found to be simple and fast. The work focused on the influence of the sample nebulizer systems to different silicon chemical forms by ICP-OES. For a sample introduction system consisting of micronebulizer coupled to a cyclonic spray chamber, the results indicated that the ICP-OES signals depended strongly on the silicon chemical forms, and the higher emission intensities have been attributed to the compound volatility. The variability of the signals induced by the different silicon compounds was less significant for the same nebulizer system with a temperature control device. Nevertheless, the interferences were not effectively mitigated. Nevertheless, direct injection high efficiency nebulizer (DIHEN) introduced in the present work can effectively mitigate the interferences of different silicon chemical forms, is suitable for the determination of silicon in gasoline. The quantitative method with the potential DIHEN nebulizer system showed good linearity and the recoveries ranged from 92.8%~108.7%, the limit of detection was 0.05 mg·kg-1. The relative standard deviation (RSD) was between 1.05% and 4.63%. Compared with the microwavedigestion method, the proposed method was found to be highly simple, rapid, sensitive and accurate, which has foreseen a promising application for silicon determination in gasoline.
|
Received: 2015-09-06
Accepted: 2016-01-22
|
|
Corresponding Authors:
CHEN Xiao-yan
E-mail: 634403201@qq.com
|
|
[1] Wordwide Fuel Charter. 5th ed. Belgium:European Automobile Manufacturers Association,Alliance of Mobile Manufacturers,Truck and Engine Manufacturers Association,and Japan Automobile Manufacturers Association,2013. [2] National Standards of the People’s Republic of China(中华人民共和国国家标准). Gasoline for Motor Vihicle(车用汽油). GB17930-2013. Beijing: Standards of Press of China(北京: 中国标准出版社), 2013. [3] YAN Fang, REN Shang, LIN De-lian(严 方,任 熵,林德莲). China Meas Urement Technology(中国测试技术), 2006, 32(5): 57. [4] Amais R S, Donati G L, Schiavo D, etal. Microchemical Journal., 2013, 106: 318. [5] Lienemann C P. Oil Gas Sci. Technol., 2005, 60: 951. [6] Carduner K R, Carter R O, Westwood L C. Applied Spectroscopy, 1988, 42(7): 1265. [7] ZHANG Wen-mei, WEN Huan, Lü Huan-ming, et al(张文媚,闻 环,吕焕明,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2015, 35(3): 760. [8] Standard Test Method for Silicon in Gasoline and Related Products by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry. ASTM D7757. 2012. [9] WANG Hui, SONG Qiang, YAO Qiang, et al(王 珲,宋 蔷,姚 强,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(6): 1662. [10] XU Xue-qin(许雪芹). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2013, 33(7): 1961. [11] Lopez-Molinero A, Benito M, Aznar Y, et al. J. Anal. At. Spectrom., 1998, 13: 215. [12] Bertenyi I, Barnes R M. Anal. Chem., 1988, 58: 1734. [13] Sohrin Y. Anal. Chim. Acta., 1991, 247: 1. [14] Sanz-Medel A, Sanchez Uria J E, Arribas Jimeno S. Analyst, 1985, 110: 563. [15] Lopez-Molinero A, Castillo J R, Mermet J M. Talanta, 1990, 3: 895. [16] Adachi T, Takeishi H, Sasaki Y, et al. Anal. Chim. Acta, 1989, 218: 77. [17] Yang J, Conver T S, Koropchak J A. Anal. Chem., 1996, 68: 4064. [18] Langlois B, Dautheribes J L, Mermet J. M. J. Anal. At. Spectrom., 2003, 18: 76. [19] Sanchez R, Todoli J L, Lienemann C P, et al. J. Anal. At. Spectrom., 2009, 24: 391. [20] Hagmann M, Heimbrand E, Hentschel P P. in Proceedings of the 7th International Waste Management and Landfill Symposium: Proceedings Sardinia, Cagliari, Italy, 1999. 483. [21] Montiel J, Grindlay G , Gras L, et al. Spectrochimica Acta Part B, 2013, 81: 36. [22] ZHAO Yan, CHEN Xiao-yan, XU Dong-yu, et al(赵 彦,陈晓燕,徐董育,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2014, 34(12): 3406. |
[1] |
LIU Yu-juan1, 2, 3 , LIU Yan-da1, 2, 3, SONG Ying1, 2, 3*, ZHU Yang1, 2, 3, MENG Zhao-ling1, 2, 3. Near Infrared Spectroscopic Quantitative Detection and Analysis Method of Methanol Gasoline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1489-1494. |
[2] |
ZHANG Bin-bin1, 2, LI Jing-bin1, 2, WANG Shi-ning1, 2, HE Peng-fei1, 2, ZHA Xiao-qin1, 2, 3. Determination of Lithium, Iron and Phosphorus in Carbon Composite Lithium Iron Phosphate by Perchloric Acid Digestion-Inductively Coupled Plasma Optical Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2703-2709. |
[3] |
LI Mao-gang1, YAN Chun-hua2, DU Yao1, ZHANG Tian-long2, LI Hua1, 2*. Study on Rapid Quantitative Analysis Method of Methanol Content in Methanol Gasoline by Raman Spectroscopy and Partial Least Squares[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2099-2104. |
[4] |
HUANG Kai-sheng, XU Dong-yu, CHEN Shu-di, CHEN Xiao-yan*, ZHAO Yan. Determination of Sodium and Zinc in Ethanol Gasoline for Motor Vehicles (E10) by ICP-OES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 973-977. |
[5] |
LIU Wei-yi, MENG Yuan, JIN Bai-chuan, JIANG Meng-yun, LIN Zu-hong, HU Li-yang, ZHANG Ting-ting*. Distribution Characteristics and Ecological Risk Assessment of Heavy Metals in Surface Sediments of the North Canal Using ICP-OES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3912-3918. |
[6] |
HU Jun, LIU Yan-de*, HAO Yong, SUN Xu-dong, OUYANG Ai-guo. Qualitative Discrimination and Quantitative Determination Model Research of Methanol Gasoline and Ethanol Gasoline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1640-1644. |
[7] |
YANG Lu-wei1, LI Ming2*, GAO Wen-feng2, LIU Gang1, WANG Yun-feng2, WANG Wei1, LI Kun1. Determination of Heavy Metal Elements in Stagnation Water of Flat-Plate Solar Collectors With ICP-OES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(06): 1947-1952. |
[8] |
LIU Yan-de,HU Jun, TANG Tian-yi, ZHANG Yu, OUYANG Yu-ping, OUYANG Ai-guo. Methanol Content Determination in Methanol Gasoline with Mid Infrared Spectroscopy Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 459-464. |
[9] |
YIN Bo1, 2, KANG Tian-he1*, KANG Jian-ting1, CHEN Yue-juan1, 2. Ions-Leaching Rates Rules of Low-Calcium Fly Ash in NaOH Solutions Based on ICP-OES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(09): 2943-2950. |
[10] |
MEI Yan-jun1, SHAO Da1, WANG Yu-hong1, YANG Zhong-kang1, YANG Wen-qing1, GAO Yue-song1, HE Shang-ming2, ZHENG Yi2, LI Ai-guo2, SUN Li-guang1*. Measurement of Sr/Ca Ratio in Tridacna spp. Shells from South China Sea: A Comparison of SR-XRF and ICP-OES Analysis Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1640-1647. |
[11] |
PENG Zhang-kuang1, 3, LI Hai-jun2, CHAI Xiao-li2, XIAO Ying-kai1, ZHANG Yan-ling1, YANG Jian1, 3, MA Yun-qi1, 2*. Accurate Determination of Boron Content and Isotope in Salt[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(08): 2564-2568. |
[12] |
YANG Hong-jun1, SUN Jing-kuan1*, SONG Ai-yun1, QU Fan-zhu1, DONG Lin-shui1, FU Zhan-yong2. A Probe into the Contents and Spatial Distribution Characteristics of Available Heavy Metals in the Soil of Shell Ridge Island of Yellow River Delta with ICP-OES Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(04): 1307-1313. |
[13] |
ZHOU Kun-peng1, 2, BI Wei-hong1*, XING Yun-hai1, CHEN Jun-gang1, ZHOU Tong1, FU Xing-hu1 . Multi Spectral Detection of Ethanol Content in Gasoline Based on SiPLS Feature Extraction and Information Fusion [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 429-434. |
[14] |
RONG Hai-teng1, SONG Chun-feng1*, YUAN Hong-fu1, LI Xiao-yu1, HU Ai-qin1, XIE Jin-chun1, YAN De-lin2 . Rapid Quantitative Analysis of Content of the Additive in Gasoline for Motor Vehicles by Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2757-2760. |
[15] |
ZHOU Hui, TAN Qian, GAO Ya-ling, SANG Shi-hua, CHEN Wen* . Pretreatment of Aluminum-Lithium Alloy Sample and Determination of Argentum and Lithium by Spectral Analysis [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2886-2890. |
|
|
|
|