| 光谱学与光谱分析 |
|
|
|
|
|
| Study of Ultrasonic Nebulizer Assisted Spark Induced Breakdown Spectroscopy as a Metal Elements Analysis Method for Aqueous Sample |
| ZHONG Shi-lei1, 3, QI Fu-jun2*, SUN Xin1, 3, CHENG Kai2, MA Jun-yan1, 3, SUN Yu-xiang1 |
1. College of Physics Science, Qingdao University, Qingdao 266071, China
2. Optics and Optoelectronics Laboratory, Ocean University of China, Qingdao 266100, China
3. Key Laboratory of Photonics Materials and Technology in Universities of Shandong (Qingdao University), Qingdao 266071, China |
|
|
|
|
Abstract In order to develop a high sensitive and low cost metal elements analysis method for aqueous sample, an ultrasonic nebulizer assisted spark induced breakdown spectroscopy (UN-SIBS) system is established, where an ultrasonic nebulizer is employed to transform the bulk liquid sample into aerosol composed by intensive droplets. And a high tension coil and a couple of electrodes are combined to induce the plasma. The spectra emitted are collected to analysis the metal elements in the aqueous samples. Based on the experimental system, the features of emission spectra are studied. The electron density and electron temperature are calculated to understand the physics characteristic of the plasma in UN-SIBS experiments. Samples of different concentration of lead are analyzed by UN-SIBS method to make clear of the relationship between concentration and the peak intensity of the heavy metal element Pb. Besides, the atomic line of lead at 261.37 nm detected by the sample with the concentration of 2.07 ppt could be easily distinguished which is better than the LOD reported in references. The aqueous samples with calcium, as a lower activity metal element, are also studied. At last, the possible mechanism is discussed according to the experimental results.
|
|
Received: 2014-09-07
Accepted: 2015-01-21
|
|
|
|
Corresponding Authors:
QI Fu-jun
E-mail: qifujun@ouc.edu.cn
|
|
[1] Hunter A J R, Davis S J, Piper L G, et al. Applied Spectroscopy, 2000, 54(4)：575.
[2] XIN Ren-xuan(辛仁轩). Analasis of Emission Spectroscopy of Plasma(等离子体发射光谱分析). Beijing: Chemical Industry Press(北京：化学工业出版社), 2005.
[3] Fraser M E, Panagiotou T, Hunter A J R, et al. Plating & Surtace Finishing, 2000, 87(1): 80.
[4] Hunter A J R，Wainner R T，Piper L G，et al. Appl. Optics, 2003, 42(12): 2102.
[5] Srungaram P K, Ayyalasomayajula K K, Yu-Yueh F, et al. Spectrochimica Acta，Part B，2013，87：108.
[6] Namihira T, Sakai S, Yamaguchi T, et al. IEEE Transactions on Plasma Science, 2007, 35(3): 614.
[7] Samek O, Beddows D C S, Kaiser J, et al. Optical Engineering，2000，39：2248.
[8] Schmidt N E，Goode S R. Applied Spectroscopy，2002，56：370.
[9] Chen Z, Li H, Zhao F, et al. Journal of Analytical Atomic Spectrometry, 2008，23(6): 871.
[10] Jagdish P Singh, Jose R Almirall, Mohamad Sabsabi, et al. Anal. Bioanal. Chem., 2011, doi: 10.1007/S00216-011-5073-5.
[11] Parigger C G, Dackman M, Hornkohl J O. Applied Optics, 2008，47(31): G1.
[12] Griem H R. Plasma spectroscopy. New York: McGraw-Hill, 1964.
[13] ZHONG Shi-lei, LU Yuan, CHENG Kai, et al(钟石磊，卢 渊，程 凯，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2011，31(6)：1458. |
| [1] |
XU Yang-biao, WANG Hai-shui*. The Removal of Water Peaks From IR Spectra of BSA Aqueous Solution by Two ATR Background Samples and Thermal Behavior of Proteins[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 642-646. |
| [2] |
LIU Tan1, 2, XU Tong-yu1, 2*, YU Feng-hua1, 2, YUAN Qing-yun1, 2, GUO Zhong-hui1, XU Bo1. Chlorophyll Content Estimation of Northeast Japonica Rice Based on Improved Feature Band Selection and Hybrid Integrated Modeling[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2556-2564. |
| [3] |
YAO Meng, WANG Hai-shui*. To Make a Good Infrared Spectrum in NaCl Aqueous Solution Where Lambert-Beer’s Law is Not to be Obeyed[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 65-70. |
| [4] |
CHEN Shuai1, WANG Xu-yang1, LI Fei1, 2, YUAN Jun-sheng1, 2*. Study of Raman Spectroscopy on the Structure of NH4Cl Aqueous Solution Under Strong Magnetic Field[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 116-121. |
| [5] |
ZHOU Mo1, 2, ZOU Bin1, 2*, TU Yu-long1, 2, XIA Ji-pin1, 2. Hyperspectral Modeling of Pb Content in Mining Area Based on Spectral Feature Band Extracted from Near Standard Soil Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2182-2187. |
| [6] |
HAN Si-qin-gao-wa1, 2, ZHANG Chen1, CHEN Xin-xuan1, ZHANG Yan-hua3*, HASI Wu-li-ji1*. Research on the Rapid Detection of Midazolam in Aqueous Solution, Urine and Serum by SERS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2073-2078. |
| [7] |
ZHAO Hai-xia, WANG Xin-wei*, LI Ru-xue, WANG Deng-kui, FANG Xuan, FANG Dan, WEI Zhi-peng, WANG Xiao-hua. Effect of Passivation Substrates Surface to CsPbBr3 Quantum Dot Films Optical Stability[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(06): 1706-1710. |
| [8] |
FU Ping-jie1,2, YANG Ke-ming1,2*, CHENG Long1,2, WANG Min1,2,3. HHT Identification and BC-PLSR Prediction Model of Soil Lead Pollution Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1543-1550. |
| [9] |
OUYANG Shun-li1, ZHANG Ming-zhe1, HU Qing-cheng1, WEI Hai-yan1, WU Nan-nan2*. Hydrogen Bonding Effect on the Surface Tension and Viscosity of DMSO Aqueous Solutions Studied by Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(09): 2778-2781. |
| [10] |
ZHU Wei-yi1, JIN Min-feng1, TU Xie-hao1, ZHANG Ye-feng1, YIN Yue-hong2, Lü Zhao-yue1*. Bimolecular Excited States Based on 3DTAPBP: Electromer and Exciplex[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2344-2349. |
| [11] |
PENG Heng, LIU Shuai, CHEN Xiang-bai*. Raman Study of Perovskite (C6H5CH2NH3)2PbBr4[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1763-1765. |
| [12] |
CAI Shi-shi1，ZHANG En1, 2*. Trace Elements and U-Pb Ages of Zircons from Myanmar Jadeite-Jade by LA-ICP-MS: Constraints for Its Genesis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1896-1903. |
| [13] |
GUO Hui1,2, YANG Ke-ming1*, ZHANG Wen-wen1, LIU Cong1, XIA Tian1. Spectra Recognition of Corn Pollution Degree under Copper and Lead Ion Stress[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 212-217. |
| [14] |
HU Wen-hua, DONG Jun, CHI Zi-fang*, REN Li-ming. Preparation and Spectroscopy Characterization of Magnetic Pb(Ⅱ)-Ion Surface Imprinted Polymers(Fe3O4/GO-IIP)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3499-3503. |
| [15] |
TIAN Meng-jing1, JIA Jia1, QIAO Yu1, WU Ting-yan1, LI He-xiang1, LIU Ying1, 2*. Study on Adsorption and Desorption Characteristics of Pb(Ⅱ) and Cr(Ⅵ) onto the Surface Sediments of Hequ Section of the Yellow River with ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1902-1907. |
|
|
|
|
