光谱学与光谱分析 |
|
|
|
|
|
Fingerprint Properties of Cephalosporin Pharmaceutical Wastewater |
WU Jing, ZHAO Yu-fei, CAO Jiong-zhun, YANG Lin, LI Zhong-hua, TANG Jiu-kai |
Environmental Simulation and Pollution Control State Key Joint Laboratory, School of Environment, Tsinghua University, Beijing 100084, China |
|
|
Abstract Fluorescence spectrum is unique for each water sample, and is called “aqueous fingerprint”. Aqueous fingerprint could indicate the contamination in water and thus is a new technology for early warning. Cephalosporin is one of the most commonly used antibiotics worldwide yet with environmental hazards. The production of cephalosporin in China is growing every year. Therefore, the study of aqueous fingerprint of cephalosporin pharmaceutical wastewater is significantly important for both monitoring the discharge of pharmaceutical wastewater and protecting the aquatic environment. In this study we investigated the properties of water fingerprint of cephalosporin pharmaceutical wastewater. There existed 6 peaks in the fingerprints. According to the emission wavelength, these peaks could be divided into two groups: the first group included the peaks locating at excitation wavelength/emission wavelength of 230/350, 275/350,315/350 nm and the second group consisted of the peaks locating at excitation wavelength/emission wavelength of 225/405, 275/410 and 330/420 nm respectively. The highest intensity was found at excitation wavelength/emission wavelength of 230/350 nm. In each group, the fluorescence intensity of the peaks with shorter excitation wavelength is higher. pH could significantly change the position and intensity of the peaks. When pH rose, the peak intensity of first group decreased and that of the second group increased. The intensity decrease is called fluorescence quenching and the intensity increase is called fluorescence sensitizing. The sensitizing and quenching was probably related to the fluorescence organic components with acid and alkaline radical groups in the wastewater. Because if a fluorescent substance contains weak acid or base groups, both the molecular configuration and ionic configurations exist in the solution at the same time. The spatial structure of these configurations are different. This makes the luminescent properties of the configurations different. When pH changes, the ratio of molecular configuration and ionic forms also changes, which causes the change of location and intensity of the fluorescence peaks. Above all, the properties of aqueous fingerprint of cephalosporin pharmaceutical wastewater is distinct and distinguishable. The properties of aqueous fingerprint can be used as a novel tool to identify the appearance of cephalosporin pharmaceutical wastewater.
|
Received: 2014-12-08
Accepted: 2015-03-23
|
|
Corresponding Authors:
WU Jing
E-mail: wu_jing@mail.tsinghua.edu.cn
|
|
[1] LIU Zhi-hong, CAI Ru-xiu(刘志宏, 蔡汝秀). Journal of Analytical Science(分析科学学报), 2000, 16(6): 516. [2] CHEN Mo-fu, WU Jing, Lü Yan-li, et al(陈茂福, 吴 静, 律严励, 等). Acta Optica Sinica(光学学报), 2008, 28(3): 578. [3] Creusot N, Ait-Aissa S, Tapie N, et al. Environmental Science & Technology, 2014, 48(7): 3649. [4] Gauthier T D, Shane E C, Guerin W F, et al. Environmental Science & Technology, 1986, 20(11): 1162. [5] FU Ping-qing, LIU Cong-qiang, YIN Zuo-ying, et al(傅平青, 刘丛强, 尹祚莹, 等). Geochimica(地球化学), 2004, 33(3): 301. |
[1] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
[2] |
HE Yan-ping, WANG Xin, LI Hao-yang, LI Dong, CHEN Jin-quan, XU Jian-hua*. Room Temperature Synthesis of Polychromatic Tunable Luminescent Carbon Dots and Its Application in Sensitive Detection of Hemoglobin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3365-3371. |
[3] |
HU Bin1, 2, WANG Pei-fang1, 2*, ZHANG Nan-nan3, SHI Yue4, BAO Tian-li1, 2, JIN Qiu-tong1, 2. Effect of pH on Interaction Between Dissolved Organic Matter and Copper: Based on Spectral Features[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1628-1635. |
[4] |
YE Zhi-peng1, 2, 3, ZHAO Shu-nan4, LI Xun-feng1, 2, 3*, HUAI Xiu-lan1, 2, 3. Study on Reflection Characteristics of Completely Oxidized DZ125[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 230-238. |
[5] |
GE Deng-yun, XU Min-min, YUAN Ya-xian*, YAO Jian-lin*. Surface-Enhanced Raman Spectroscopic Investigation on the Effect of
Solution pH on Dehydroxylation of Hydroxythiophenol Isomers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2076-2081. |
[6] |
SHAO Ke-man, FU Gui-yu, CHEN Su-yan, HONG Cheng-yi, LIN Zheng-zhong*, HUANG Zhi-yong*. Preparation of Molecularly Imprinted Fluorescent Probe for Rare Earth Complex and Determination of Malachite Green Residue[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 808-813. |
[7] |
TIAN Peng1, XIAO Xue-song1, SU Gui-tian1, DUAN Han-feng1,JIN Yao-dong1, SONG Yang-yang1, HUANG Tao2, ZHANG Hang1*. Fluorescence Spectra Analysis of N-n-Octyl Oyridine Acetate Ionic Liquid in Different Solvents[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 147-151. |
[8] |
XIAO Shi-jie1, WANG Qiao-hua1, 2*, FAN Yi-kai3, LIU Rui3, RUAN Jian3, WEN Wan4, LI Ji-qi4, SHAO Huai-feng4, LIU Wei-hua5, ZHANG Shu-jun3*. Rapid Determination of αs1-Casein and κ-Casein in Milk Based on Fourier Transform Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3688-3694. |
[9] |
TAN Yang, JIANG Qi-gang*, LIU Hua-xin, LIU Bin, GAO Xin, ZHANG Bo. Estimation of Organic Matter, Moisture, Total Iron and pH From Back Soil Based on Multi Scales SNV-CWT Transformation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3424-3430. |
[10] |
ZHOU Zi-hao1, YANG Fan2, 3, LI Dong1, WANG Jian-ping2, 3, XU Jian-hua1*. pH Dependent Time-Resolved Fluorescence Spectra of ZnSe Quantum Dots Based on Glutathione Ligands[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3178-3183. |
[11] |
Lamia A. Albedair. Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) Complexes With the Widely Used Herbicide 2,4-Dichlorophenoxyacetic Acid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1982-1987. |
[12] |
LIU Hong-fang, WANG Rui, LIAN Xia-yu, HUO Li-juan, MA Jun. Research of the Removal of SeO2-3 With Pyrite Based on XPS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1458-1462. |
[13] |
ZENG Jian-hua, MENG Yan, LIU Lin-lin, YANG Yang, LI Mei-ying, WANG Zi-yue, ZHU Xiu-qing*, SHI Yan-guo*. Characterization and Effects of pH on the Conformation of Hemp Protein Isolate Based on Multi-Spectroscopic Technique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3748-3754. |
[14] |
ZHANG Lu1, XU Liang1, TU Zong-cai1, 2*, ZHOU Qi-ming1, ZHOU Wen-na1. Mechanism of Isoquercitrin Inhibiting Advanced Glycation Products Formation Based on Fluorescence Spectroscopy Technique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3755-3760. |
[15] |
JIA Hui-jie, ZHU Ning, GAO Yuan-yuan, WANG Ya-qi, SUO Quan-ling*. Effect of Substituent Structure of Benzothiazole Probe on Recognition to Metal Ion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3594-3598. |
|
|
|
|