光谱学与光谱分析 |
|
|
|
|
|
The Different Phase, Morphology Controllable Synthesis and Luminescent Properties Investigation of NaYF4∶Yb, Er |
HAN Yu-ting1, XU Jing1, QIAO Shu-liang3, YANG Bo1, LI Li2, LIU Cai-hong2, YAO Shuang*, YAN Jing-hui1*, ZOU Ming-qiang2* |
1. School of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China2. Chinese Academy of Inspection and Quarantine, Beijing 100123, China3. Baotou Entry-Exit Inspection and Quarantine Bureau,Baotou 014010, China |
|
|
Abstract Using sodium fluoride and rare earth nitrate as raw materials and sodium citrate as surfactant, micron grade NaYF4 upconversion luminescent materials were prepared by hydrothermal method. By X-ray diffraction(XRD), scanning electron microscope(SEM) and fluorescence spectrometer, the crystal phase, morphology and luminescent characteristics of the prepared samples were investigated. The results showed that the phase of the samples could generate a transition from cubic phase to hexagonal phase by adjusting the proportion (5, 6, 7, 8, 9, 11) of NaF/RE3+, and the X ray diffraction peaks for the cubic and hexagonal phase of samples exactly matched with those of the standard card of PDF#77-2042 and PDF#16-0334,respectively. The SEM photographs showed that the crystallinity of samples was high and the dispersibility was favourable, the morphology were translated from microrods to hexagonal microplates. The samples upconversion luminescent spectra showed the intensity enhancement of red and green light emission peaks with increasement of the ratio of NaF/RE3+. The green emission peaks of samples at 520 and 539 nm corresponded to the 2H11/2→4I15/2 and 4S3/2→4I15/2 level transition of Er3+ ion, and the red light emission peaks of samples at 653 nm corresponded to the 4F9/2→4I15/2 level transition of Er3+ ion. The chromaticity coordinate diagram exhibited that the change of the luminescent color of samples could be achieved by adjusting the ratio of NaF/RE3+. With the increasing of NaF/RE3+ ratio, for the whole light-emitting colors of samples, the shift from yellow region to near red region could be realized. It can be concluded that through the relatively simple experimental procedure and lower cost materials, the change of phase and morphology, the moving of light-emitting color for sample NaYF4∶Yb3+, Er3+ could be well controlled only by changing the single component (NaF) molar ratio in the raw materials. The effect of phase and morphology of fluorescent materials on their upconversion luminescence has great potential applications in photonic devices and bioanalysis research.
|
Received: 2014-09-03
Accepted: 2014-12-20
|
|
Corresponding Authors:
YAO Shuang, YAN Jing-hui, ZOU Ming-qiang
E-mail: yaoshuang@cust.edu.cn;yjh@cust.edu.cn;mingqiangz@sina.com
|
|
[1] Gu Z, Yan L, Tian G, et. al. Adv. Mater., 2013, 25:3758. [2] Huang W, Lu C, Jiang C, et. al. Mater. Res. Bull., 2012, 47(6):1310. [3] Ye X, Chen J, Engel M, et al. Nat. Chem., 2013, 5(6):466. [4] Fan W, Shen B, Bu W, et al. J. Am. Chem. Soc., 2013, 135(17):6494. [5] Dou Q, Idris N M,Zhang Y. Biomaterials, 2013, 34:1722. [6] LONG Dan-dan, ZHANG Qing-xia, WANG Yu, et al(龙丹丹,张清侠,王 煜,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2013, 33(8):2055. [7] Liu Y, Tu D, Zhu H, et. al. Nanoscale, 2013, 5:1369. [8] Liu J, Bu W, Pan L, et. al. Angew. Chem., Int. Ed., 2013, 52(16):4375. [9] Zheng W, Zhou S, Chen Z, et al. Angew. Chem., Int. Ed., 2013, 52(26):6671. [10] Dong H, Sun L D,Yan C H. Nanoscale, 2013, 13(5): 5703.
|
[1] |
ZHAN Yan1, ZU Hong-ru1, HUANG Di1*, HU Chao-fan1,2*. Rapid Synthesis of Graphene Oxide Quantum Dots via Hydrothermal Strategy for Cell Imaging Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1458-1462. |
[2] |
WANG hua-yu1, YAN Jing-hui1*, ZOU Ming-qiang2, 3*. Influence of SO2-4/BO3-3 Doping on Properties of NaGd(MoO4)2∶Eu3+ Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 139-143. |
[3] |
HE En-jie1, DONG Jun2, GAO Wei2, ZHANG Zheng-long3. Upconversion Fluorescence Regulation of Single NaGdF4∶Yb3+,Er3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3347-3353. |
[4] |
ZHAI Hao-ying, ZOU Hao. Synthesis of Cr, Ag Co-Doped ZnS Nanomaterials and Its Adsorption Capability for Reactive Dyes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(08): 2638-2644. |
[5] |
XU Zheng1, ZHAO Su-ling1, PENG Xiao-bo2, GAO Chen-jia1, GAO Yi-qun1, WANG Yun2. Synthesis and Luminescence Properties of Monodisperse Spherical CaWO4∶Re3+(Sm3+, Eu3+) Red Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1363-1367. |
[6] |
HU Qing-song, ZHU Cheng-jing, XIA Yue-yi, WANG Li-li, LIU Wen-han, PAN Zai-fa* . Study on Hydrothermal Preparation and Luminescence Properties of Luminescent Material BaSrMg(PO4)2∶Eu3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 340-344. |
[7] |
XU Jing1, YAN Jing-hui1, HAN Yu-ting1, QIAO Shu-liang3, YANG Bo1, LI Li2, LIU Cai-hong2, YAO Shuang1*, ZOU Ming-qiang2*. The Synthesis, Luminescence and Energy Transmission of NaLa(MoO4)2∶Eu3+/Tb3+/Tm3+ Materials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2712-2717. |
[8] |
ZHANG Zhi-qing, LIAO Meng-chen, ZENG Hong-yan*, XU Sheng, XU Li-hua, ZHU Pei-han, YANG Yong-jie . Phase Transition Behavior and Thermodynamic Analysis of Hydrotalcite Flame-Retardant [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(01): 14-18. |
[9] |
MU Wan-jun, XIE Xiang, LI Xing-liang,ZHANG Rui, Lü Kai, WEI Hong-yuan* . Preparation and Optical Properties of Tantalum Tungsten Bronze [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(01): 24-28. |
[10] |
LIU Xiao-huan1, ZHANG Ming-ming1, WANG Ji-fu1, XU Yu-zhi1*, WANG Chun-peng1, 2, CHU Fu-xiang1, 2* . Chemical Structure of Bioethanol Lignin by Low-Temperature Alkaline Catalytic Hydrothermal Treatment [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(11): 2940-2944. |
[11] |
LONG Dan-dan1, ZHANG Qing-xia1, WANG Yu3, ZHANG Fan2, WANG Yan-fei2, ZHOU Xin2, QI Xiao-hua2, ZHANG Heng1, YAN Jing-hui1*, ZOU Ming-qiang2*. Color-Tunable Nano-Material α-NaYF4:Yb, Er, Tm Prepared by Microemulsion-Hydrothermal Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(08): 2055-2059. |
[12] |
ZHANG Qing-xia1, LONG Dan-dan1, ZHANG Fan2, QI Xiao-hua2, ZHANG Heng1, YAN Jing-hui1*, ZOU Ming-qiang2*. Influence of Bi3+ Doping on Properties of CaMoO4:Eu3+ Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(07): 1758-1762. |
[13] |
LIU En-zhou1, FAN Jun1*, HU Xiao-yun2, YE Yan-xi2, HOU Wen-qian1 . Upconversion Properties of Sodium and Aluminum Fluorides Coated BaF2 Material [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 61-64. |
[14] |
JIANG Gui-cheng1, WEI Xian-tao1, WANG Lin-xiang1, 2, WANG Xiao-chun1, CHEN Yong-hu1, YIN Min1* . Preparation and Luminescence of Down-Conversion Material β—NaYF4∶Tb3+, Yb3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(02): 331-334. |
[15] |
XIN Mei1,CAO Wang-he2, LUO Xi-xian2 . Hydrothermal Synthesis and Optical Properties of Full-Color-Emission ZnS∶Cu,Al Nanocrystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(09): 2451-2455. |
|
|
|
|