陶寺、殷墟白灰面的红外光谱研究

doi:10.3964/j.issn.1000-0593(2015)03-0613-04

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Abstract Archaeological lime powders samples from Taosi and Yinxu sites, natural limestone and experimentally prepared lime mortar were investigated by means of Fourier transform infrared spectrometry (FTIR) to identify the raw material of lime powders from Taosi and Yinxu sites. Results show that ν₂/ν₄ ratio of calcite resulted from carbonation reaction of man-made lime is around 6.31, which is higher than that of calcite in natural limestone and reflects the difference in the disorder of calcite crystal structure among the natural limestone and prepared lime mortar. With additional grinding, the values of ν₂and ν₄ in natural limestone and prepared lime mortar decrease. Meanwhile, the trend lines of ν₂ versus ν₄ for calcite in experimentally prepared lime mortar have a steeper slope when compared to calcite in natural limestone. These imply that ν₂/ν₄ ratio and the slope of the trend lines of ν₂ versus ν₄ can be used to determine the archaeological man-made lime.Based on the experiment results, it is possible that the archaeological lime powder from Taosi and Yinxu sites was prepared using man-made lime and the ancient Chinese have mastered the calcining technology of man-made lime in the late Neolithic period about 4 300 years ago.

Key words：Lime powders;Man-made lime;Natural limestone;Infrared spectrum

Received: 2014-02-16 Accepted: 2014-05-26

ZTFLH:

O657.3

Corresponding Authors: ZHANG Bing-jian E-mail: zbj@mail.hz.zj.cn

Cite this article:

WEI Guo-feng,ZHANG Chen,CHEN Guo-liang, et al. Study on Archaeological Lime Powders from Taosi and Yinxu Sites by FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(03): 613-616.

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https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2015)03-0613-04 OR https://www.gpxygpfx.com/EN/Y2015/V35/I03/613

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