| 光谱学与光谱分析 |
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| Study on Intermolecular Interaction between 4-Aminopyridine and Methacrylic Acid Using Two Dimensional FTIR Spectroscopy |
| LIU Xue-yong1,ZHOU Tao２,CHANG Kun1,WANG Lin1,ZHENG Min-xia1, LUO Yi-wei1 |
1. Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China
2. State Key Lab of Polymer Materials Engineering, Polymer Research Institute, Sichuan University, Chengdu 610065, China |
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Abstract A two-dimensional infrared (2D IR) correlation spectroscopy technique has been introduced to study the intermolecular interaction between 4-aminopyridine and methacrylic acid. The type and relationship of the bond between 4-aminopyridine and methacrylic acid molecule could not be characterized directly using the one-dimensional FTIR spectroscopy. On the contrary, the interactions between 4-aminopyridine and methacrylic acid molecule were determined using 2D IR correlation spectroscopy. The synchronous cross peaks exist between stretching vibrations of hydroxyl group of methacrylic acid at 1 298 and 1 202 cm-1 and CN group of 4-aminopyridine at 1 531 cm-1, and between carbonyl group of methacrylic acid at 1 705 cm-1 and N—H group of 4-aminopyridine at 3 382 and 3 212 cm-1, respectively. According to the two-dimensional correlation rules, the interactions of static electricity and hydrogen bonding exist between 4-aminopyridine and methacrylic acid molecule. Such successful applications demonstrate that two-dimensional infrared correlation spectroscopy may be a convenient and effective means in the study of the intermolecular and intramolecular interaction.
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Received: 2007-03-16
Accepted: 2007-06-26
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Corresponding Authors:
LIU Xue-yong
E-mail: xyliu73@hotmail.com
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