| 光谱学与光谱分析 |
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| Study on Structural Properties of Biochar under Different Materials and Carbonized by FTIR |
| ZHENG Qing-fu1, 2, WANG Yong-he1, SUN Yue-guang1, NIU He-he1, ZHOU Jia-ru1, WANG Zhi-min1, ZHAO Ji3* |
1. Analysis and Testing Center, Inner Mongolia University for the Nationalities, Institute of Natural Products and Waste, Tongliao 028000, China
2. Biology Postdoctoral Research Stations，Inner Mongolia University，Huhhot 010021, China
3. Inner Mongolia Key Laboratory of Environmental Pollution Control & Waste Kesource Reuse，Huhhot 010021, China |
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Abstract Infrared spectroscopy (IR) is an important means of seeing the characteristics of the structural properties. Fourier transform infrared spectroscopy (FTIR ) was applied to analyze the structural properties of biochar from different materials with different methods. The results showed that: the biochars have IR absorption peaks of hydroxyls group, aromatic group and containing organic group with the activated?charcoal, but in other absorption peaks, with a significant difference. The high temperature can make —OH, —CH3, —CH2—, CO to be associated or loss, and promotes the formation of aromatic groups during Carbonization of corn straw. At the different carbonization mode, the heating and microwave carbonization, has a carbonize mechanism of biochar, heating method may make —OH in alcohol and phenol to combinative with each other or loss, and to form benzene ring group and an aromatic group, Aromatic group in microwave method was so preventing to participate in the hot reaction, to form the more benzene substances. These results show that the Infrared spectrum can well analysis the structural characteristics of biochar, and showed that it comprises —OH, the aromatic group and other active groups.
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Received: 2013-10-16
Accepted: 2014-01-20
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Corresponding Authors:
ZHAO Ji
E-mail: ndzj@imu.edu.cn
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[1] ZHANG Wei-ming, MENG Jun, WANG Jia-yu, et al(张伟明，孟 军，王嘉宇，等). Acta Agronmica Sinica(作物学报)，2013，39(8)：1445.
[2] Cao X D, Ma L N, Gao B, et al. Environ. Sci. Technol., 2009, 43(9): 3285.
[3] Cao X D, Ma L N, Liang Y. Environ. Sci. Technol., 2011, 45(11): 4884.
[4] Novak J M, Busschera W J, Watts D W, et al. Geoderma，2010, 154(3): 281.
[5] Marco Keiluweit, Peter S Nico, Mark G Johnson. Environ. Sci. Technol., 2010, 44(4): 1247.
[6] Joyleene T Yu, Amir Mehdi Dehkhoda, Naoko Ellis. Energy Fuels, 2011, 25: 337.
[7] Parmila Devi, Anil K Saroha. International Journal of ChemTech Research, 2013, 5(2): 682.
[8] AN Zeng-li, HOU Yan-wei, CAI Chao, et al(安增莉, 侯艳伟, 蔡 超，等). Environmental Chemistry(环境化学)，2011, 30(11): 1851.
[9] MIN Fan-fei，CHEN Qing-ru，ZHANG Ming-xu(闵凡飞, 陈清如, 张明旭). Journal of Anhui University of Science ＆ Technology·Nature Science Edition(安徽理工大学学报·自然科学版), 2008, 28(2): 55.
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