光谱学与光谱分析 |
|
|
|
|
|
Determination of Aqueous Potassium and Sodium Ions with Liquid-Phase Diaphragm Glow Discharge-Atomic Emission Spectrometry |
LIU Yong-jun1, WANG Lei2 |
1. College of Environmental Science & Engineering, Dalian Maritime University, Dalian 116026, China 2. Department of Environmental Engineering, Xiamen University of Technology, Xiamen 361024, China |
|
|
Abstract The present paper described the determination of potassium and sodium ions with a liquid-phase diaphragm glow discharge emission spectroscopy (LDGD-AES) in aqueous solution. The discharge was formed in a pin hole on a dielectric diaphragm interposed between two submerged graphite electrodes. Effects of applied voltage and the addition of organic additive methanol on the determination were examined. It was found that increasing the applied voltage and adding of methanol can increase the detection sensitivity and decrease the detection limit. Limits of detection for K and Na were 0.007 and 0.001 mg·L-1 under the applied voltage of 850 V and addition of 0.6%~0.8% methanol, respectively. It was demonstrated that the LDGD-AES is a promising technique in measurements of metal ions in aqueous solution, because no optical interferences from the electrodes and the background molecular bands from air were found.
|
Received: 2012-11-28
Accepted: 2013-03-19
|
|
Corresponding Authors:
LIU Yong-jun
E-mail: lyjglow@sohu.com
|
|
[1] Mezei P, Cserfalvi T. Appl. Spectrosc. Rev.,2007, 42: 573. [2] Liu Y, Sun B, Wang L, et al. Plasma Chem. Plasma Process,2012,32(2): 359. [3] Cserfalvi T, Mezei P, Apai P. J. Phys. D: Appl. Phys.,1993, 26: 2184. [4] Park Y S, Ku S H, Hong S H, et al. Spectrochimica Acta B, 1998, 53: 1167. [5] Davis W C, Marcus R K. J. Anal. At. Spectrom.,2001, 16: 931. [6] Zhu Z, Chan G, Ray S J, et al. Anal. Chem.,2008, 80: 7043. [7] XI Xiao-qin, ZHENG Pei-chao, WANG Hong-mei, et al(席晓琴,郑培超,王鸿梅,等). Chin. J. Anal. Chem.(分析化学), 2010, 38(3): 449. [8] Liu Y J, Jiang X Z. Environ. Sci. Technol. 2005, 39: 8512. [9] Wu J, Yu J, Li J, et al. Spectrochimica Acta Part B, 2007, 62: 1269. [10] Kohara Y, Terui Y, Ichikawa M, et al. J. Anal. At. Spectrom.,2012, 27: 1457. [11] http://physics.nist.gov/PhysRefData/ASD/lines_form.html. [12] Mezei P, Cserfalvi T, Kim H J, et al. Analyst, 2001, 126(5): 712. |
[1] |
ZHENG Hong-quan, DAI Jing-min*. Research Development of the Application of Photoacoustic Spectroscopy in Measurement of Trace Gas Concentration[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 1-14. |
[2] |
YANG Guang1, JIN Chun-bai1, REN Chun-ying2*, LIU Wen-jing1, CHEN Qiang1. Research on Band Selection of Visual Attention Mechanism for Object
Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 266-274. |
[3] |
GAO Hong-sheng1, GUO Zhi-qiang1*, ZENG Yun-liu2, DING Gang2, WANG Xiao-yao2, LI Li3. Early Classification and Detection of Kiwifruit Soft Rot Based on
Hyperspectral Image Band Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 241-249. |
[4] |
WU Hu-lin1, DENG Xian-ming1*, ZHANG Tian-cai1, LI Zhong-sheng1, CEN Yi2, WANG Jia-hui1, XIONG Jie1, CHEN Zhi-hua1, LIN Mu-chun1. A Revised Target Detection Algorithm Based on Feature Separation Model of Target and Background for Hyperspectral Imagery[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 283-291. |
[5] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
[6] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
[7] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
[8] |
LIU Bo-yang1, GAO An-ping1*, YANG Jian1, GAO Yong-liang1, BAI Peng1, Teri-gele1, MA Li-jun1, ZHAO San-jun1, LI Xue-jing1, ZHANG Hui-ping1, KANG Jun-wei1, LI Hui1, WANG Hui1, YANG Si2, LI Chen-xi2, LIU Rong2. Research on Non-Targeted Abnormal Milk Identification Method Based on Mid-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3009-3014. |
[9] |
MU Da1, 2, WANG Qi-shu1, 2*, CUI Zong-yu1, 2, REN Jiao-jiao1, 2, ZHANG Dan-dan1, 2, LI Li-juan1, 2, XIN Yin-jie1, 2, ZHOU Tong-yu3. Study on Interference Phenomenon in Terahertz Time Domain
Spectroscopy Nondestructive Testing of Glass Fiber Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3031-3040. |
[10] |
YU Hao-zhang, WANG Fei-fan, ZHAO Jian-xun, WANG Sui-kai, HE Shou-jie*, LI Qing. Optical Characteristics of Trichel Pulse Discharge With Needle Plate
Electrode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3041-3046. |
[11] |
TAO Bei-bei, WU Ning-ning, WANG Hai-bo*. Highly Sensitive Determination of Rutin Based on Fluorescent Glutathione Stabilized Copper Nanoclusters[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3158-3162. |
[12] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[13] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
[14] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
[15] |
GUO Ge1, 3, 4, ZHANG Meng-ling3, 4, GONG Zhi-jie3, 4, ZHANG Shi-zhuang3, 4, WANG Xiao-yu2, 5, 6*, ZHOU Zhong-hua1*, YANG Yu2, 5, 6, XIE Guang-hui3, 4. Construction of Biomass Ash Content Model Based on Near-Infrared
Spectroscopy and Complex Sample Set Partitioning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3143-3149. |
|
|
|
|