| 光谱学与光谱分析 |
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| Rhodamine-Triazine Fluorescence Probe Recognition for Al3+ and Cr3+ |
| CHEN Yi1, ZHANG Yan1, ZENG Xi1, MU Lan1*, LI Jun1, SUN Qiang1, WEI Gang2 |
1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
2. CSIRO Materials Science and Engineering, P.O. Box 218, Lindfield, NSW 2070, Australia |
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Abstract A symmetrical rhodamine-triazine derivative was synthesized through step-by-step substitution of rhodamine B ethylenediamine with two chlorines on cyanuric chloride. It showed an extreme selectivity for Al3+ and Cr3+ over other common metal ions and strong fluorescence emission and UV-Visible absorption in the ethanol solution of pH 4. Due to the difference in complexing ability, the recognition of the derivative for Al3+ and Cr3+was not interfered by other coexisting ions. Under certain conditions, the derivative can be used as high selectivity and high sensitivity Al3+ or Cr3+ fluorescence and colorimetric enhanced probe.
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Received: 2013-01-22
Accepted: 2013-03-12
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Corresponding Authors:
MU Lan
E-mail: sci.lmou@gzu.edu.cn
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