| 光谱学与光谱分析 |
|
|
|
|
|
| Temperature Effect on the Hydrogen Bonding Behavior between DMSO and Water in Aqueous DMSO Solutions Studied by Raman Spectroscopy |
| OUYANG Shun-li1, 2, LI Zheng-qiang3, WU Nan-nan1, LI Zuo-wei1, SUN Cheng-lin1, FAN Li-mei1,4* |
1. College of Physics, Jilin University, Changchun 130023, China
2. Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources，Inner Mongolia University of Science & Technology, Baotou 014010, China
3. Key Laboratory for Molecular Enzymology and Engineering, Ministry of Education, Jilin University, Changchun 130023, China
4. Second Hospital of Jilin University, Changchun 130041, China |
|
|
|
|
Abstract In the present paper, DMSO/H2O mixture with the ratio of volume 1∶1 was measured in the cooling process by Raman spectroscopy, and the Raman assignments was made to the DMSO molecular and water molecular. The results showed that the behavior between intra-molecular hydrogen bonds and inter-molecular hydrogen bonds of DMSO and water leads to the change in the Raman spectra of the SO stretching vibration of DMSO and the O—H stretching vibration of water. Further analysis showed that the hydrogen bond between DMSO and water was enhanced in the course of temperature decreasing process (27 to -30 ℃), and the intramolecular hydrogen bonds between water and water replaced the intermolecular hydrogen bonds of DMSO and water in the course of temperature decreasing process (-30 to -60 ℃). The research provides experimental basis for hydrogen bonding theory in aqueous solution.
|
|
Received: 2012-12-04
Accepted: 2013-03-10
|
|
|
|
Corresponding Authors:
FAN Li-mei
E-mail: fanlimei1971@126.com
|
|
[1] Rasmussen D H, Mackenzie A P. Nature, 1968, 220: 1315.
[2] Mancera R L, Chalaris M, Samios J. J. Mol. Liq., 2004, 110: 147.
[3] Fox M F, Whittingham K P. J. Chem. Soc. Faraday Trans., 1974, 75: 1407.
[4] Kaatze U, Brai M, Sholle F D, et al. J. Mol. Liq., 1990, 44: 197.
[5] Gordalla B C, Zeidle M D. Mol. Phys. 1991, 74: 975.
[6] Kaatze U, Pottel R, Schafer M. J. Phys. Chem., 1989, 93: 5623.
[7] Vaisman I I, Berkowitz M L. J. Am. Chem. Soc., 1992, 114: 7889.
[8] OUYANG Shun-li, ZHOU Mi, CAO Biao, et al(欧阳顺利，周 密，曹 彪，等). Chem. J. Chinese Universiuies(高等学校化学学报), 2008, 29(10): 2055.
[9] OUYANG Shun-li, WU Nan-nan, SUN Cheng-lin, et al(欧阳顺利，吴楠楠，孙成林，等). Chin. Phys. B(中国物理B), 2010, 19: 123101.
[10] Wakabayashi K, Meada Y, Ozutsumi K, et al. J. Mol. Liq., 2004, 110: 43.
[11] Durickovic I, Claverie R, Bourson P, et al. J. Raman Spectrosc., 2011, 42: 1408.
[12] Madigosky W M, Warfield R W. J. Chem. Phys., 1983, 78: 1912. |
| [1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
| [2] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
| [3] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
| [4] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
| [5] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
| [6] |
LI Wei1, TAN Feng2*, ZHANG Wei1, GAO Lu-si3, LI Jin-shan4. Application of Improved Random Frog Algorithm in Fast Identification of Soybean Varieties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3763-3769. |
| [7] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
| [8] |
WAN Mei, ZHANG Jia-le, FANG Ji-yuan, LIU Jian-jun, HONG Zhi, DU Yong*. Terahertz Spectroscopy and DFT Calculations of Isonicotinamide-Glutaric Acid-Pyrazinamide Ternary Cocrystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3781-3787. |
| [9] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1，ZHAO Yan-jie1*，NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
| [10] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
| [11] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
| [12] |
GUO He-yuanxi1, LI Li-jun1*, FENG Jun1, 2*, LIN Xin1, LI Rui1. A SERS-Aptsensor for Detection of Chloramphenicol Based on DNA Hybridization Indicator and Silver Nanorod Array Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3445-3451. |
| [13] |
ZHU Hua-dong1, 2, 3, ZHANG Si-qi1, 2, 3, TANG Chun-jie1, 2, 3. Research and Application of On-Line Analysis of CO2 and H2S in Natural Gas Feed Gas by Laser Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3551-3558. |
| [14] |
LIU Jia-ru1, SHEN Gui-yun2, HE Jian-bin2, GUO Hong1*. Research on Materials and Technology of Pingyuan Princess Tomb of Liao Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3469-3474. |
| [15] |
ZHANG Yan-dong1, WU Xiao-jing1*, LI Zi-xuan1, CHENG Long-jiu2. Two-Dimensional Infrared Spectroscopic Study of Choline
Chloride/Glycerin Solution Disturbed by Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3047-3051. |
|
|
|
|
