光谱学与光谱分析 |
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Study on Characteristics of Elements in PM2.5 during Haze-Fog Weather in Winter in Urban Beijing |
WANG Qin, CHEN Xi, HE Gong-li, LIN Shao-bin, LIU Zhe, XU Dong-qun* |
Institute of Environmental Health and Related Product Safety, Chinese Center for Disease and Prevention, Beijing 100021, China |
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Abstract The concentrations and pollution characteristics of metal elements in fine particulate matter (PM2.5) during haze-fog days in winter in the urban area of Beijing were investigated. Aerosol samples of PM2.5 were collected in Beijing for 23 consecutive days from January to February, 2013. The concentrations of PM2.5 were measured by filter membrane weighting method. The samples were treated by ultrasound exacting procedures and the total amounts of the 36 metal elements were determined by inductively couple plasma-mass spectrometry (ICP-MS). The pollution characteristics of metal elements were analyzed by enrichment factor (EFs) method. The concentrations of PM2.5 significantly increased in haze-fog days, which were much higher than the 24 h mean value (75 μg·m-3) in National Ambient Air Quality Standard issued by Ministry of Environmental Protection of the People’s Republic of China. Among the 36 metal elements, the concentrations of 27 metal elements in PM2.5 were higher in haze-fog days than those in normal days. As, Cr, Pb, Ti and V were the principal inorganic components of PM2.5 in winter in the urban area of Beijing. In haze-fog days, the metal elements could be roughly divided into 3 groups by EFs, including high-enrichment group (EFs were higher than 10, including As, Cr, Cu, and Pb), medium-enrichment group (EFs were between 10 to 1, including Sb, Sn, etc) and low-enrichment group (EFs were close to 1, including Ti, V, etc). It was concluded that ICP-MS has good precision and accuracy in determining multi elements in atmospheric particulate samples, and can meet the requirements of monitoring principal and trace elements of pollutants simultaneously. In haze-fog days, the increase of As, Cr, Pb were strongly correlated with the pollutions caused by anthropogenic activities, such as vehicle exhaust emissions, and oil and coal combustions in winter. This study can probably provide a useful analytical method for the elements characteristic detection of PM2.5 in haze-fog days, and provide scientific basis for decreasing air pollution in Beijing and protecting the people’s health.
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Received: 2013-03-05
Accepted: 2013-04-24
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Corresponding Authors:
XU Dong-qun
E-mail: dongqunxu@126.com
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[1] DAI Shu-gui(戴树桂). Advances in Environmental Chemistry(环境化学进展). Beijing:Chemical Industry Press(北京: 化学工业出版社), 2005. 50. [2] Norbert Englert. Toxicology Letters, 2004,149: 235. [3] Ariana Zeka, James R Sullivan, Pantel S Vokonas. International Journal of Epidemiology,2006,35: 1347. [4] JI Ya-qin, ZHU Tan, BAI Zhi-peng,et al(姬亚芹,朱 坦,白志鹏,等). Ecology and Environment(生态与环境), 2005, 14(4): 518. [5] PENG Rong-fei, HOU Jian-rong, HUANG Cong (彭荣飞, 侯建荣, 黄 聪). Chinese Journal of Health Laboratory Technology(中国卫生检验杂志),2010, 20(12): 3166. [6] LI Bing, HU Jing-yu, ZHAO Mo-tian(李 冰, 胡静宇, 赵墨田). Journal of Chinese Mass Spectrometry Society(质谱学报), 2010, 31(1):2. [7] Duce R A, Hoffmann G L, Zoller W H. Science, 1975, 187: 59. [8] Woitke P, Wellmit z J, H elm D, et al. Chemosphere, 2003, 51: 633. [9] ZHANG Xiu-zhi, BAO Zheng-yu, TANG Jun-hong(张秀芝, 鲍征宇, 唐俊红). Geological Science and Technology Information, 2006,(25): 65. [10] FENG Xi-dan, DANG Zhi, HUANG Wei-lin(冯茜丹, 党 志, 黄伟林). Environmental Science, 2008, 29(3): 569. [11] China National Environmental Monitoring Centre(中国环境监测总站). China’s Soil Element Background Values(中国土壤元素背景值). Beijing: China Environmental Science Press(中国环境科学出版社), 1990. [12] CHEN Xi, DING Liang, HE Gong-li, et al(陈 曦,丁 亮,何公理,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2011, 31(7): 1942. [13] JI Ya-qin, ZHU Tan, FENG Yin-chang, et al(姬亚芹, 朱 坦, 冯银厂,等). Acta Scientiarum Naturalium Universitatis Nankaiensis(南开大学学报·自然科学版), 2006, 39(2): 94. [14] ZHANG Ren-jian, WANG Ming-xing, HU Fei, et al(张仁健, 王明星, 胡 非,等). Journal of the Graduate School of the Chinese Academy of Sciences(中国科学院研究生院学报), 2002, 19(1): 75. [15] Zoll er W H, Gladn ey E S, Duce R A. Science, 1974, 183: 199. |
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