| 光谱学与光谱分析 |
|
|
|
|
|
| Effect of Treatments of Hydrogen Peroxide and Sodium Dithionite- Citrate-Bicarbonate on Clay Minerals of Red Earth Sediments |
| LI Rong-biao1, 2, HONG Han-lie1*, YIN Ke1, WANG Chao-wen1, GAO Wen-peng1, HAN Wen1, WU Qing-feng3 |
1. Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074, China
2. School of Tourism, Kaili University, Kaili 556011, China
3. College of Physical Sciences and Technology, Yangtze University, Jingzhou 434023, China |
|
|
|
|
Abstract As classical procedures for pretreatment of soil sediments, hydrogen peroxide (H2O2) and sodium dithionite-citrate-bicarbonate (DCB) treatment methods are very important in removing the organic matter and iron oxides acting as cementing agents in the soils. However, both of these methods have less been focused on the effect on the clay minerals when separating. Here, we report the comparable methods between H2O2 and DCB to reveal their effect on clay minerals in red earth sediments using X-ray diffraction (XRD). The XRD results suggested that mineral particles can be totally decentralized by either H2O2 or DCB method in the soils and high purity clay minerals can be obtained by separating quartz and other impurities from clay minerals effectively. However, the XRD data were distorted by the DCB treatment owning to the cation exchange between Na+ and interlayer cation. On the contrary, the authentic data can be obtained by H2O2 treatment. Therefore, the H2O2 treatment seems to be a more appropriate method to obtain authentic information of clay mineralogy when separating of clay minerals from red earth sediments.
|
|
Received: 2012-08-27
Accepted: 2012-11-08
|
|
|
|
Corresponding Authors:
HONG Han-lie
E-mail: honghl8311@yahoo.com.cn
|
|
[1] XI Cheng-fan(席承藩). Quaternary Sciences(第四纪研究), 1991, (1): 1.
[2] GU Yan-sheng, XIAO Chun-e, ZHANG Ze-jun, et al(顾延生，肖春娥，章泽军，等). Journal of China Normal University·Natural Science(华东师范大学学报·自然科学版), 2002, (1): 69.
[3] HONG Han-lie, DU Deng-wen, LI Rong-biao, et al(洪汉烈，杜登文，李荣彪，等). Earth Science——Journal of China University of Geosciences(地球科学——中国地质大学学报), 2012, 37(3): 424.
[4] HONG Han-lie(洪汉烈). Geological Science and Technology Information(地质科技情报), 2010, 29(1): 1.
[5] Hong H, Gu Y, Li R, et al. Journal of Quaternary Science, 2010, 25(5): 622.
[6] ZHU Li-jun(朱立军). Geology Geochemistry(地质地球化学), 1997, (1): 42.
[7] Sumner M E. Clay Minerals Bull, 1963, 5(29): 218.
[8] Bergaya F, Theng B K G, Lagaly G. Handbook of Clay Science. Amsterdam: Elsevier Publication, 2006.
[9] TAN Zheng-xi(谭正喜). Progress in Soil Science(土壤学进展), 1991, 19(2): 18.
[10] Huang L, Tan W, Liu F, et al. Journal of Soils and Sediments, 2007, 7(4): 240.
[11] Churchman G J. Clay Minerals, 1980, 15(1): 59.
[12] ZHANG Nai-xian(张乃娴). Clay Mineral Research Methods(粘土矿物研究方法). Beijing: Science Press(北京: 科学出版社), 1990.
[13] Mehra O P, Jackson M L. Clays and Clay Minerals, 1960，317.
[14] WEN Jian-kang(温建康). China Mining Magazine(中国矿业), 1997, 6(5): 61.
[15] LIANG Ai-zhen, ZHANG Xiao-ping, YANG Xue-ming, et al(梁爱珍，张晓平，杨学明，等). Chinese Journal of Soil Science(土壤通报), 2006, 36(5): 748.
[16] Mikutta R, Kleber M, Jahn R, et al. Soil Science Society of America Journal, 2005, 69(1): 120.
[17] Ucgul E, Girgin I. Turkish Journal of Chemistry, 2002, 26(3): 431.
[18] Rosenberg P E, Hooper R L. Clays and Clay Minerals, 1997, 45(3): 486.
[19] HE Ji-zheng, LI Xue-yuan, XU Feng-lin(贺纪正，李学垣，徐凤琳). Chinese Science Bulletin(科学通报), 1993, 38(22): 2096. |
| [1] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
| [2] |
ZHU Yu-qi1, 2, ZHANG Xin2, DU Pan-pan2, LIU Shu1, ZHANG Gui-xin1, 2, GUAN Song-lei2*, ZHENG Zhong1*. Infrared Spectroscopy and X-Ray Spectroscopy Combined With
Inductively Coupled Plasma Mass Spectrometry for Quality
Control of Mongolian Medicine Yu Grain Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3163-3169. |
| [3] |
LI Yu-tang1, WANG Lin-zhu1, 2*, LI Xiang3, WANG Jun1. Characterization and Comparative Analysis of Non-Metallic Inclusions in Zirconium Deoxidized Steel[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2916-2921. |
| [4] |
GAO Ya1, LIAO Cui-ping1, ALATAN Chaolumen2, CHEN Jian-bo3, TU Ya4*. X-Ray Diffraction and Infrared Spectral Analysis of the Differential Chemical Indicators Between the Raw and Milk-Processed Corals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2494-2499. |
| [5] |
XU Ming-kun, LIN Jia-xiang, ZHANG Xiao-lin, LI Zhen-yin, WANG Ya-ming, LIU Chun-tai, SHEN Chang-yu, SHAO Chun-guang*. In Situ Detection of Structural Evolution of Isotropic Polypropylene Crystals During Uniaxial Stretching by Two-Dimensional X-Ray Diffraction Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1426-1433. |
| [6] |
SHI Zhi-feng1, 2, LIU Jia2, XIAO Juan2, ZHENG Zhi-wen1*. Investigation of Novel Method for Detecting Vanillin Based on X-Ray Diffraction Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1563-1568. |
| [7] |
WANG Mei-li1, 2, SHI Guang-hai2*, ZHANG Xiao-hui1, YANG Ze-yu2, 3, XING Ying-mei1. Experimental Study on High-Temperature Phase Transformation of Calcite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1205-1211. |
| [8] |
SHAO Jin-fa1, LI Rong-wu2, PAN Qiu-li1, CHENG Lin1*. The Study of Non-Destructive Analysis of Tang Sancai Firing Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 781-787. |
| [9] |
ZHANG Dian1, WANG Hui1, CHEN Yin-wei2, 3, WANG Ju-lin2, 3*. Identification and Influence of Color Components in Red Lime From the Roof of Yangxin Hall in the Palace Museum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 877-882. |
| [10] |
ZHANG Yan1, 2, WANG Hui-le1, LIU Zhong2, ZHAO Hui-fang1, YU Ying-ying1, LI Jing1, TONG Xin1. Spectral Analysis of Liquefaction Residue From Corn Stalk Polyhydric
Alcohols Liquefaction at Ambient Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 911-916. |
| [11] |
FAN Qing-jie, SONG Yan, LAI Shi-quan*, YUE Li, ZHU Ya-ming, ZHAO Xue-fei. XRD Structural Analysis of Raw Material Used as Coal-Based Needle Coke in the Coking Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1979-1984. |
| [12] |
PAN Qiu-li1, SHAO Jin-fa1, LI Rong-wu2, CHENG Lin1*, WANG Rong1. Non-Destructive Analysis of Red and Green Porcelain in Qing Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 732-736. |
| [13] |
WANG Yi1, 2, LI Chang-rong1, 2*, ZENG Ze-yun1, 2，XI Zuo-bing1, 2, ZHUANG Chang-ling1, 2. Study on Alumina/Cerium Oxide X-Ray Diffraction and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1841-1845. |
| [14] |
HUANG Wei-bo, CHEN Jia-yun, HUANG Fang, HUANG Li-shan, OUYANG Jian-ming*. Effects of Different Molecular Weight of Gracilaria Lemaneiformis Polysaccharide on Calcium Oxalate Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1163-1170. |
| [15] |
DONG Pei-jie1, ZHANG Wen-bo1*, LU Wei2. A NIR Study on Hydrogen Bonds of Bamboo-Based Cellulose Ⅱ[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1260-1264. |
|
|
|
|
