| 光谱学与光谱分析 |
|
|
|
|
|
| Three-Dimensional Excitation Emission Matrix Fluorescence Spectroscopic Characterization of Dissolved Organic Matter in Water of Coal-Mining Area |
| YANG Ce1,ZHONG Ning-ning1,SHI Yu-lei1,WANG Fei-yu1,CHEN Dang-yi2 |
1. Key Laboratory for Hydrocarbon Accumulation, Ministry of Education, China University of Petroleum, Beijing 102249, China
2. Coal Administration of Henan Province, Zhengzhou 450000, China |
|
|
|
|
Abstract Three-dimensional excitation emission matrix was applied to characterize the fluorescence properties of dissolved organic matter in various waters of Shilong coal-mining area. Fluorescence peakⅠ (fulvic-like) and peak Ⅱ (humic-like) were strong, while peak Ⅳ and peak Ⅴ (protein-like) were weak or even undetected in some samples. Fluorescence peaks in various waters and different zones showed great difference in intensities and the fluorescence peaks in underground water tended to be much lower than those of surface waters. Furthermore, the fluorescence peaks of rivers and lakes were higher than those of mine drainage, and also the fluorescence peaks in coking zone and coal mining zone were higher than those in sewage-irrigated zone, or even much higher than those in farming zone. The reason may be that coal mining activities and coal industry can bring plenty of organic matter from coal to surroundings. Meanwhile, surface water would accept mine drainage, waste water of coal-washing and sewage from daily life easier than underground water, so surface water can be polluted seriously. Fluorescence peaks in waters from coal mining area are little influenced by pH of the water but can be influenced by the content of Ca2+ to water in some extent.
|
|
Received: 2006-08-16
Accepted: 2006-11-18
|
|
|
|
Corresponding Authors:
YANG Ce
E-mail: yangcece@126.com
|
|
[1] Baker A D. Journal of Hydrology, 1999,217: 19.
[2] LI Hong-bin, LIU Wen-qing, ZHANG Yu-jun(李宏斌, 刘文清, 张玉钧). Optical Technique(光学技术),2006, 32(1): 27.
[3] FU Ping-qing, LIU Cong-qiang, WU Feng-chang, et al(傅平青, 刘丛强, 吴丰昌, 等). Quaternary Sciences(第四纪研究),2004，24(6): 695.
[4] ZHAO Nan-jing, LIU Wen-qing, LIU Jian-guo, et al(赵南京, 刘文清, 刘建国, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(7): 1077.
[5] Digambara Patra, Mishra A K. Analytica Chimica Acta,2002, 454: 209.
[6] Paula G Coble. Marine Chemistry, 1996, 51: 325.
[7] Chen J, Gu B H, Le Boeuf E J, et al. Chemosphere,2002, 48: 59.
[8] Erich M S, Trusty G M. Canadian Journal of Soil Science, 1997, 77: 405.
[9] Ohno T, Cronan C S. International Journal of Environmental Analytical Chemistry, 1997, 66: 119.
[10] Burdige D J, Kline S W, Chen W H, et al. Marine Chemistry,2004, 89: 289.
[11] FU Ping-qing, LIU Cong-qiang, WU Feng-chang, et al(傅平青, 刘丛强, 吴丰昌, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(12): 2024.
[12] FU Ping-qing, LIU Cong-qiang, YIN Zuo-ying, et al(傅平青，刘丛强，尹祚莹, 等). Geochemistry(地球化学),2004, 33(3): 301.
[13] ZHAO Nan-jing, LIU Wen-qing, CUI Zhi-cheng, et al(赵南京, 刘文清, 崔志成, 等). Acta Optica Sinica(光学学报),2005,25(5): 687.
[14] ZHONG Jian-hua(钟建华). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 1997, 14(4): 12. |
| [1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [2] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [3] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2，WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
| [4] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
| [5] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
| [6] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
| [7] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
| [8] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
| [9] |
QIU Cun-pu1, 2, TANG Xiao-xue2, WEN Xi-xian4, MA Xin-ling2, 3, XIA Ming-ming2, 3, LI Zhong-pei2, 3, WU Meng2, 3, LI Gui-long2, 3, LIU Kai2, 3, LIU Kai-li4, LIU Ming2, 3*. Effects of Calcium Salts on the Decomposition Process of Straw and the Characteristics of Three-Dimensional Excitation-Emission Matrices of the Dissolved Organic Matter in Decomposition Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2301-2307. |
| [10] |
SHI Chuan-qi1, LI Yan2, HU Yu3, YU Shao-peng1*, JIN Liang2, CHEN Mei-ru1. Fluorescence Spectral Characteristics of Soil Dissolved Organic Matter in the River Wetland of Northern Cold Region, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1517-1523. |
| [11] |
LI Yuan-jing1, 2, CHEN Cai-yun-fei1, 2, LI Li-ping1, 2*. Spectroscopy Study of γ-Ray Irradiated Gray Akoya Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1056-1062. |
| [12] |
LIU Xia-yan1, CAO Hao-xuan1, MIAO Chuang-he1, LI Li-jun2, ZHOU Hu1, LÜ Yi-zhong1*. Three-Dimensional Fluorescence Spectra of Dissolved Organic Matter in Fluvo-Aquic Soil Profile Under Long-Term Composting Treatment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 674-684. |
| [13] |
LI Qing-bo1, BI Zhi-qi1, CUI Hou-xin2, LANG Jia-ye2, SHEN Zhong-kai2. Detection of Total Organic Carbon in Surface Water Based on UV-Vis Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3423-3427. |
| [14] |
LÜ Yang1, PEI Jing-cheng1*, ZHANG Yu-yang2. Chemical Composition and Spectra Characteristics of Hydrothermal Synthetic Sapphire[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3546-3551. |
| [15] |
ZHANG Yong-bin1, ZHU Dan-dan1, CHEN Ying1*, LIU Zhe1, DUAN Wei-liang1, LI Shao-hua2. Wavelength Selection Method of Algal Fluorescence Spectrum Based on Convex Point Extraction From Feature Region[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3031-3038. |
|
|
|
|
