| 光谱学与光谱分析 |
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| Synthesis, Structure and Special Study of 1D Cadmium Sulfate-H2biim Coordination Polymer |
| DENG Song, GE Su-zhi, LIU Qi, HU Heng-bin, SUN Yan-qiong*, CHEN Yi-ping, ZHANG Han-hui |
| College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China |
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Abstract A novel cadmium complexes of {[Cd(H2biim)2(SO4)]·3H2O}n (1) (H2biim=2,2’-biimidazole) was synthesized by hydrothermal reaction of 3CdSO4·8H2O and 2,2’-biimidazole ligand. The complex was built up by [Cd(H2biim)2]2+ units bridged sequentially by SO2-4 anions to form 1D zigzag chains parallel to the c-axis. The H2biim ligands were attached to the 1D chain as branches of the chain by coordinating to Cd2+ at two sides of the chain. The chains were held together by π—π interaction and O—H…O interactions, thus yielding a 3D extended supramolecular network. The responses of symmetric stretching vibration of SO2-4, N—C single bond, NC double bond and anti-symmetric stretching vibration of N—C single bond were detected in 2D IR correlation spectra under thermal perturbation. The complex exhibited strong blue emission peak at 498 nm (λex=397 nm) that can be assigned to a ligand-to-metal charge-transfer (LMCT) band.
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Received: 2012-03-15
Accepted: 2012-06-10
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Corresponding Authors:
SUN Yan-qiong
E-mail: sunyanqiong@fzu.edu.cn
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[1] Wu H, Liu H Y, Liu Y Y, et al. Chemical Communications, 2011, 47(6): 1818.
[2] Chaturvedi J, Singh S, Bhattacharya S, et al. Inorganic Chemistry, 2011, 50(20): 10056.
[3] Liu Q K, Ma J P, Dong Y B. Chemical Communications, 2011, 47(25): 7185.
[4] Liu Y Y, Zhang T T, Ma J F, et al. Inorganic Chemistry Communications, 2012, 17: 137.
[5] Sang R L, Li X. Inorganica Chimica Acta, 2006, 359(2): 525.
[6] Fu Y M, Zhao Y H, Lan Y Q, et al. Inorganic Chemistry Communications, 2007, 10(6): 720.
[7] Cheng L, Gou S H, Wang J Q. Journal of Molecular Structure, 2011, 991(1-3): 149.
[8] Jana A D, Ghosh A K, Ghoshal D, et al. CrystEngComm, 2007, 9(4): 304.
[9] Wu Q A, Fu X A, Zhao J W, et al. Journal of Coordination Chemistry, 2010, 63(11): 1844.
[10] Song P C, Song W C, Tao Y, et al. Solid State Science., 2010, 12(8): 1357.
[11] Mao W L, Hu Z Q, Ding Y. Chinese Journal of Structural Chemistry, 2010, 29(4): 587.
[12] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement. Gttingen, University of Gttingen, Germany, 1997.
[13] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution. Gttingen, University of Gttingen, Germany, 1997.
[14] Sun Y Q, Yang G Y. Dalton Trans., 2007, (34): 3771.
[15] Noda I, Dowrey A E, Marcott C. Modern Polymer Spectroscopy, 2007: 1.
[16] Noda I, Ozaki Y. Two-Dimensional Correlation Spectroscopy Applications in Vibrational and Optical Spectroscopy, 2005: i-xiii.
[17] Sang R L, Xu L. European Journal Inorganic Chemistry, 2006, (6): 1260.
[18] Su Y, Zang S, Li Y, et al. Crystal Growth Design, 2007, 7(7): 1277.
[19] Ding B, Yi L, Wang Y, et al. Dalton Trans., 2006(5): 665. |
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