光谱学与光谱分析 |
|
|
|
|
|
Rapid Detection of 6-Benzylaminopurine Residues in Sprout Beans by Surface-Enhanced Raman Spectroscopy |
ZHANG Ping1, ZHENG Da-wei1, LIU Jing1, ZHONG Ru-gang1*, LIU Chun-wei2, GUO Xun2, WANG Hong2 |
1. The College of Life Science and Bio-engineering, Beijing University of Technology, Beijing 100124, China 2. OptoTrace Technologies, Inc.,Suzhou 215125, China |
|
|
Abstract New method for rapid and quantitative analysis of 6-benzylaminopurine (6-BA) residues in sprout beans was studied by using FAST-SPE and portable surface-enhanced Raman spectroscopy (SERS). With homemade sprout bean samples as blank control, 6-BA solutions extracted from inserted-treatment samples showed typical characteristic Raman peaks at 1 002 cm-1 tested by SERS, and normalized 1 002 cm-1 intensities had a good linear relationship with gradient concentrations of 6-BA insert-standard solutions. The high concentration linear range was 0.5~14 μg·mL-1, and the low one was 0.1~2 μg·mL-1. The quantitative detection limit was down to 0.02 mg·kg-1 that was below the maximum allowable residues (MAL) of 0.2 mg·kg-1 in related National Standard. The recoveries were 82.3%~95.1% and the RSD was below 5%. This method with portable equipment and simple pre-treatment showed good reproducibility, short test time-consuming and easy operating, and thus it would provide efficient and sensitive solutions for large-scale on-site and rapid detections.
|
Received: 2011-07-11
Accepted: 2011-11-15
|
|
Corresponding Authors:
ZHONG Ru-gang
E-mail: lifesci@bjut.edu.cn
|
|
[1] National Standard of the People’s Republic of China(中华人民共和国国家标准). GB 2760—1996, Hygienic Standards for Uses of Food Additives(食品添加剂使用卫生标准). [2] National Standard of the People’s Republic of China(中华人民共和国国家标准). GB/T 23381—2009, Determination of 6-Benzylaminopurine in Foods-High Performance Liquid Chromatography(食品中6-苄基腺嘌呤的测定高效液相色谱法). [3] Kneipp K, Wang Y, Kneipp H, et al. Physical Review Letters, 1997, 78(9): 1667. [4] Michaels A M, Nirmal M, Brus L E. Journal of the American Society, 1999, 121(43): 9932. [5] WANG Shi-tao, LU Hui-zong, MA Ning, et al(汪仕韬, 陆惠宗, 马 宁, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2011, 31(4): 1006. [6] Alvarez-Puebla R A, Dos Santos Jr D S, Aroca R F. Analyst, 2004,129(12): 1251. [7] Wachsmann-Hogiu S, Weeks T, Huser T. Current Opinion in Biotechnology, 2009, 20(1): 63. [8] CHEN An-yu, WANG Yan, JIAO Yi, et al(陈安宇, 王 燕, 焦 义, 等). China Medical Devices(中国医疗设备), 2008, 23(11): 4. [9] Sha M Y, Xu H X, Natan M J, et al. Journal of the American Society, 2008, 130(51): 17214. [10] Kim J H, Kim J S, Choi H, et al. Analatical Chemistry, 2006, 78(19): 6967. [11] Golightly R S, Doering W E, Natan M J. ACS Nano, 2009, 3(10): 2859. [12] Ryder A G. Current Opinion in Chemical Biology, 2005, 9(5): 489. [13] Alvarez-Puebla R A, Dos Santos D S, Aroca R F J. Analyst, 2007, 132(12): 1210. [14] Mulvihill M, Tao A, Benjauthrit K, et al. Angewandte Chemie International Edition, 2008, 47 (34): 6456. [15] CHEN An-yu, JIAO Yi, LIU Chun-wei, et al(陈安宇, 焦 义, 刘春伟, 等). Chinese Journal of Health Laboratory Technology (中国卫生检验杂志), 2009, 19(8): 1710. |
[1] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
[2] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
[3] |
GUO He-yuanxi1, LI Li-jun1*, FENG Jun1, 2*, LIN Xin1, LI Rui1. A SERS-Aptsensor for Detection of Chloramphenicol Based on DNA Hybridization Indicator and Silver Nanorod Array Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3445-3451. |
[4] |
LI Wen-wen1, 2, LONG Chang-jiang1, 2, 4*, LI Shan-jun1, 2, 3, 4, CHEN Hong1, 2, 4. Detection of Mixed Pesticide Residues of Prochloraz and Imazalil in
Citrus Epidermis by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3052-3058. |
[5] |
GUO Ge1, 3, 4, ZHANG Meng-ling3, 4, GONG Zhi-jie3, 4, ZHANG Shi-zhuang3, 4, WANG Xiao-yu2, 5, 6*, ZHOU Zhong-hua1*, YANG Yu2, 5, 6, XIE Guang-hui3, 4. Construction of Biomass Ash Content Model Based on Near-Infrared
Spectroscopy and Complex Sample Set Partitioning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3143-3149. |
[6] |
ZHAO Ling-yi1, 2, YANG Xi3, WEI Yi4, YANG Rui-qin1, 2*, ZHAO Qian4, ZHANG Hong-wen4, CAI Wei-ping4. SERS Detection and Efficient Identification of Heroin and Its Metabolites Based on Au/SiO2 Composite Nanosphere Array[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3150-3157. |
[7] |
SU Xin-yue1, MA Yan-li2, ZHAI Chen3, LI Yan-lei4, MA Qian-yun1, SUN Jian-feng1, WANG Wen-xiu1*. Research Progress of Surface Enhanced Raman Spectroscopy in Quality and Safety Detection of Liquid Food[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2657-2666. |
[8] |
ZHU Shao-hao1, SUN Xue-ping1, TAN Jing-ying1, YANG Dong-xu1, WANG Hai-xia2*, WANG Xiu-zhong1*. Study on a New Sensing Method of Colorimetric and Fluorescence Dual Modes for Pesticide Residue[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2785-2791. |
[9] |
CHENG Fang-beibei1, 2, GAN Ting-ting1, 3*, ZHAO Nan-jing1, 4*, YIN Gao-fang1, WANG Ying1, 3, FAN Meng-xi4. Rapid Detection of Heavy Metal Lead in Water Based on Enrichment by Chlorella Pyrenoidosa Combined With X-Ray Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2500-2506. |
[10] |
LI Bin, SU Cheng-tao, YIN Hai, LIU Yan-de*. Hyperspectral Imaging Technology Combined With Machine Learning for Detection of Moldy Rice[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2391-2396. |
[11] |
ZHAO Yu-wen1, ZHANG Ze-shuai1, ZHU Xiao-ying1, WANG Hai-xia1, 2*, LI Zheng1, 2, LU Hong-wei3, XI Meng3. Application Strategies of Surface-Enhanced Raman Spectroscopy in Simultaneous Detection of Multiple Pathogens[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2012-2018. |
[12] |
ZHANG Jing, GUO Zhen, WANG Si-hua, YUE Ming-hui, ZHANG Shan-shan, PENG Hui-hui, YIN Xiang, DU Juan*, MA Cheng-ye*. Comparison of Methods for Water Content in Rice by Portable Near-Infrared and Visible Light Spectrometers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2059-2066. |
[13] |
CHENG Chang-hong1, XUE Chang-guo1*, XIA De-bin2, TENG Yan-hua1, XIE A-tian1. Preparation of Organic Semiconductor-Silver Nanoparticles Composite Substrate and Its Application in Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2158-2165. |
[14] |
LI Chun-ying1, WANG Hong-yi1, LI Yong-chun1, LI Jing1, CHEN Gao-le2, FAN Yu-xia2*. Application Progress of Surface-Enhanced Raman Spectroscopy for
Detection Veterinary Drug Residues in Animal-Derived Food[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1667-1675. |
[15] |
HUANG Xiao-wei1, ZHANG Ning1, LI Zhi-hua1, SHI Ji-yong1, SUN Yue1, ZHANG Xin-ai1, ZOU Xiao-bo1, 2*. Detection of Carbendazim Residue in Apple Using Surface-Enhanced Raman Scattering Labeling Immunoassay[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1478-1484. |
|
|
|
|