| 光谱学与光谱分析 |
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| Analysis of the Process of Chinese Purple Pigment Synthesis Using X-Ray Diffraction and Thermal Analysis Methods |
| CHEN Xi1, QIN Ying1*, LI Xiao-li2 |
1. Department of History of Science and Technology and Archaeometry, University of Science and Technology of China, Hefei 230026, China
2. Suzhou Institute for Advanced Study, University of Science and Technology of China, Suzhou 215123, China |
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Abstract In the present article, according to the molecule formula of the Chinese purple and the result of most samples analysed in archaeology (PbO was contained more or less), the raw material of Chinese purple was prepared with the natural mineral resources, then the preparation was analyzed by thermogravimetry-differential thermal analysis (TG-DTA), X-ray diffraction and thermal analysis methods for discussing which materials and what condition were used to produce Chinese purple in ancient China, in an attempt to explore the reason why the Chinese purple was invented in ancient China. The result showed that the use of witherite makes the synthetic condition facile, implying that the emergence of Chinese purple in ancient China is concerned with the use of this unique mineral containing barium.
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Received: 2011-09-16
Accepted: 2011-12-08
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Corresponding Authors:
QIN Ying
E-mail: yingqin@ustc.edu.cn
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[1] Fitz Hugh E W, Zyeherman L A. Studies in Conservation, 1992, 37(3): 145.
[2] Ma Q L, Portmann A，Wild F, et al. Studies in Conservation, 2006, 51(2): 81.
[3] Zhou Tie. The Polychrom of Antique Sculptures and the Terracotta Army of the Firs Chinese Emperor. Studies on Materials, Painting Techniques and Conservation, International Conference in Xi’an, Shaanxi History Museum, March 22-28, 1999, Lintong, ICOMOS Munich, Germany, 2001.
[4] Shaanxi Archaeological Institute, The Museum on Qin Shihuang Terra Cotta Warriors and Horses(陕西省考古研究所，秦始皇兵马俑博物馆). Archaeological Report of Qin Shihuang Mausoleum 1999(秦始皇帝陵园考古报告1999). Beijing: Science Press(北京: 科学出版社), 2000. 219.
[5] Bouherour S, Berke H, Wiedemann H G. Ancient Man-Made Copper Silicate Pigments Studied by Raman Microscopy(古代人造硅酸铜盐颜料的显微拉曼光谱研究). Translated by SHEN Da-wa(沈大娲，译). Scientific and Technological Research on Cultural Relics. Vol.4(文物科技研究·第四辑). Beijing: Science Press(北京: 科学出版社), 2006. 81.
[6] Berke Heinz. The Invention of Blue and Purple Pigments in Ancient Times(古代蓝色和紫色颜料的发明). Translated by XIA Yin, SONG Yan(夏 寅, 宋 燕，译). Scientific and Technological Research on Cultural Relics. Vol.4(文物科技研究·第四辑). Beijing: Science Press(北京: 科学出版社)，2006. 97.
[7] Wiedemann H G, Bayer G. Proceedings of International Conference on the Conservation of Grotto Sites: Conservation of Ancient on the Silk Road. Dunhuang, China. 1993. 379.
[8] Lü Zhi-cheng, LIU Cong-qiang, LIU Jia-jun, et al(吕志成, 刘丛强, 刘家军，等). Geochemistry(地球化学), 2005, 34(6): 557.
[9] LIU Jia-jun, WU Sheng-hua, LIU Zhen-jiang, et al(刘家军, 吴胜华, 柳振江，等). Earth Sci Frontiers(地学前缘), 2010, 17(2): 222.
[10] XIA Yin, et al(夏 寅，等). Sciences of Conservation and Archaeology(文物保护与考古科学), 2008, 20(2): 13.
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