光谱学与光谱分析 |
|
|
|
|
|
Identification of Ginseng and Its Counterfeit by Laser Raman Spectroscopy |
WAN Qiu-e1, 2, LIU Han-ping1, 2*, ZHANG He-ming1, LIU Song-hao1, 2 |
1. Tertiary Laboratory of Chinese Medicine & Photonics,State Administration of Traditional Chinese Medicine,South China Normal University,Guangzhou 510631, China 2. Ministry of Education Key Laboratory of Laser Life Science & Laboratory of Photonic Chinese Medicine, College of Biophotonics,South China Normal University,Guangzhou 510631, China |
|
|
Abstract The objective of the present study is to identify Ginseng and its false sample :Anthriscus sylvestris, Radix glehniae and balloonflower root by Laser Raman spectroscopy, second derivative Raman spectroscopy. The structural information of the samples indicated that Ginseng and its false samples contains a large amount of carbohydrates, since some characteristic vibration peaks of the carbohydrates, such 1 640,1 432,1 130,1 086,942,483 cm-1can be observed. The characteristic vibration peak of Radix glehniae which arouse at 2 206 cm-1 in the aman spectra, totally different from the other three kinds of traditional Chinese medicines. Anthriscus sylvestris appeare the characteristic vibration peak in 1 050 cm-1 and the corresponding 1 869 cm-1 because of the chain ester compounds. The characteristic vibration peak of balloonflower root, such as 1 227,691,600 cm-1 can be observed, significantly different from the other three herbs in the Raman spectra. Further more,the previous identification results can be verified again with second derivative Raman spectroscopy. This identification method is more fast, convenient, and keeping the integrity of the samples than the routine spectroscopic method.
|
Received: 2011-07-06
Accepted: 2011-10-01
|
|
Corresponding Authors:
LIU Han-ping
E-mail: liuhp@scnu.edu.cn
|
|
[1] Dan M, Su M M, Gao X F, et al. Photochemistry, 2008, 69: 2237. [2] Parmacopiea Committee of the Ministry of Health of the People’s Republic of China(中华人民共和国国家药典委员会编). Parmacopiea the People’s Republic of China(中华人民共和国药典). Beijing: China Medical Science Press(北京:中国医药科技出版社),2010. [3] Hasegawa H. J. Pharmacol Sci., 2004; 95: 153. [4] Chen J Y, Jinn T R, Chen Y C, et al. Acta Pharmacologica Sinica, 2011, 32: 141. [5] LU Wan-zhen(陆婉珍). Modern Near Infrared Spectroscopy Analytival Technoligy(现代近红外光谱分析技术). Beijing: China Petrochemical Press(北京:中国石油化工出版社),2007. [6] Leung K S, Chan K, Bensoussan A, et al. Phytochemical Analysis, 2007, 18(2): 146. [7] CHEN Zi-yi, Lü Xu-nan, CHENG Zhou, et al(陈子易, 吕旭楠, 程 舟, 等). Journal of Fudan University·Natural Science(复旦大学学报·自然科学版),2011,50(2):185. [8] Pan T, Hashimoto A, Kanou M, et al. Bioprocess Biosyst. Eng., 2003, 26: 133. [9] ZHANG Qi-ming, ZHANG Xin, LIU Zhao-xia(张启明, 张 新, 刘朝霞). Chinese Pharmaceutical Journal(中国药学杂志), 2008, 43(24): 1903. [10] YANG Xu-gang(杨序纲). Raman Spectrum Analysis and Application(拉曼光谱的分析与应用). Beijing: National Defense Industry Press(北京:国防工业出版社),2008. [11] Patrick Herdra, Catheriae Jones, Garin Wanes. Fourier Transform Raman Spectroscopy, Ellis Horword Limited, 1991. [12] Ricci Camilla, Nyadong Leonard, Yang Felicia, et al. Analytica Chimica Acta, 2008, 623: 178.
|
[1] |
LIU Liang-yu, YIN Zuo-wei*, XU Feng-shun. Spectral Characteristics and Genesis Analysis of Gem-Grade Analcime From Daye, Hubei[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2799-2804. |
[2] |
LIN Jing-tao, XIN Chen-xing, LI Yan*. Spectral Characteristics of “Trapiche-Like Sapphire” From ChangLe, Shandong Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1199-1204. |
[3] |
YAN Wen-hao1, YANG Xiao-ying1, GENG Xin1, WANG Le-shan1, LÜ Liang1, TIAN Ye1*, LI Ying1, LIN Hong2. Rapid Identification of Fish Products Using Handheld Laser Induced Breakdown Spectroscopy Combined With Random Forest[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3714-3718. |
[4] |
FANG Ping1, 2, YANG He1, 3, NIU Chen1, 3, DONG Xing-min1, 3, XU Yong-hua1, 3*, LIU Zhi3*. Effects of Different LED Light Quality on the Physiological Characteristics and Ultrastructure of Ginseng Seedling Leaves[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3864-3871. |
[5] |
MA Ping1, 2, Andy Hsitien Shen1*, LUO Heng1, ZHONG Yuan1. Study on Laser Raman Spectrum Characteristics of Jadeite From Common Origins[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3441-3447. |
[6] |
LI Meng1, 2, ZHANG Xiao-bo2, LIU Shao-bo3, CHEN Xing-feng4*, HUANG Lu-qi5*, SHI Ting-ting2, YANG Rui6, LIU Shu7, ZHENG Feng-jie8. Partly Interpretable Machine Learning Method of Ginseng Geographical Origins Recognition and Analysis by Hyperspectral Measurements[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1217-1221. |
[7] |
REN Yue-ying2, NIU Chen1, 2, WANG Jing-jing1, 2, YANG He1, 2, XU Yong-hua1, 2*, LIU Zhi2*. Effects of Different Light Qualities on Growth and Ginsenoside Contents in Callus of Panax ginseng[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1318-1322. |
[8] |
CHEN Bei1, ZHENG En-rang1*, GUO Tuo2. Application of Various Algorithms for Spectral Variable Selection in NIRS Modeling of Red Ginseng Extraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2443-2449. |
[9] |
FU Xing-hu, ZHAO Fei, WANG Zhen-xing, LU Xin, FU Guang-wei, JIN Wa, BI Wei-hong. Quantitative Analysis of Goat Serum Protein Content by Raman Spectroscopy Based on IABC-SVR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 540-545. |
[10] |
CHEN Quan-li1, WANG Hai-tao2*, LIU Xian-yu3, QIN Chen1, BAO De-qing1. Study on Gemology Characteristics of the Turquoise from Mongolia[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2164-2169. |
[11] |
LI Jia-jia1*, LIU Jing-li1, JIN Ru-yi1, TANG Yu-ping1, YUE Shi-jun1,WANG Li-wen2, LONG Xu1, ZHANG Guang-hui1, MENG Qing-hua1, LI Rong-xi3. Quantitative Measurement of Artemisinin Content in Chinese Traditional Compound Medicine by Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2403-2408. |
[12] |
ZHANG Yan-jun1, 2, ZHANG Fang-cao1, FU Xing-hu1*, JIN Pei-jun1, HOU Jiao-ru1. Detection of Fatty Acid Content in Mixed Oil by Raman Spectroscopy Based on ABC-SVR Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2147-2152. |
[13] |
LIU Chun-hao, GUO Jin-jia*, YE Wang-quan, LIU Qing-sheng, LI Nan, ZHENG Rong-er. Development of a Combined Underwater LIBS-Raman Detection System and a Preliminary Test[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(12): 3753-3757. |
[14] |
LI Hong1, XU Qian1, ZHENG Xiao-li1, XU Hui1*, CHEN Geng2, MENG Qing-guo1*. Study of Stereoselective Interaction Between Ginsenoside Rh2 and Serum Albumin by Spectroscopic Methods and Molecular Docking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(12): 3839-3845. |
[15] |
XI Shi-chuan1, 3, ZHANG Xin1, 2, 3*,DU Zeng-feng1, LUAN Zhen-dong1, LI Lian-fu1, 3, WANG Bing1, LIANG Zheng-wei1, 3, LIAN Chao1, YAN Jun1. The Application of Raman Shift of Sulfate in Temperature Detection of Deep-Sea Hydrothermal Fluid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3390-3394. |
|
|
|
|