| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of 9 Heavy Metal Elements in Sediment by ICP-MS Using Microwave Digestion for Sample Preparation |
| LIANG Shu-xuan, WANG Xin, WU Hong, SUN Han-wen* |
| College of Chemistry and Environmental Science, Hebei University; Key Laboratory of Analytical Science and Technology of Hebei Province, Baoding 071002, China |
|
|
|
|
Abstract A method for determining 9 heavy metal elements in soil and sediment was developed by using microwave digestion-ICP-MS. The mixture of HNO3-H2O2-HF was found to give the best digestion results for soil and sediment of samples. Under the optimized conditions, the samples were analyzed by ICP-MS with the triple internal standard elements Ge, In and Bi. The results showed that all their correlation coefficients were over 0.999. The national standard soil referenee material (ESS-1 GSBZ50011-88) was analyzed by the described method and the results were accorded with the reference values. The measurement precision range was from 0.48％ to 5.73％ in terms of relative standard deviation.The recoveries and the limits of detection were in the ranges of 98.0％ to 100.7％ and 0.011 to 0.328 μg·L-1 respectively, and 11 sediment samples were determined by the proposed method. It was indicated that the method was reliable for determining heavy metal elements in soil and sediment samples.
|
|
Received: 2011-05-12
Accepted: 2011-08-28
|
|
|
|
Corresponding Authors:
SUN Han-wen
E-mail: hanwen@hbu.edu.cn
|
|
[1] Hoque Raza Rafiqul, Goswami K G，Kusre B C，et al. Environmental Monitoring and Assessment, 2011, 177(1): 457.
[2] YANG Li-yuan, SHEN Ji, ZHANG Zu-lu, et al(杨丽原，沈 吉，张祖陆，等). China Environmental Science(中国环境科学)，2003，23(2) ：206.
[3] CAO Hong-ying, LIANG Tao, WANG Li-jun, et al(曹红英，梁 涛，王立军，等). Environmental Science(环境科学)，2006，27(1)：126.
[4] Field M P, LaVigne M, Murphy K R, et al. Journal of Analytical Atomic Spectrometry, 2007, 22(9): 1145.
[5] Tinggi U, Gianduzzo T, Francis R, et al. Journal of Radioanalytical and Nuclear Chemistry, 2004, 259(3): 469.
[6] Sun Hanwen, Qiao Fengxia, Suo Ran, et al. Analytica Chimica Acta, 2004, 505(2): 255.
[7] Adrian A A. Journal of Mass Spectrometry, 2007, 42(4): 419.
[8] Linge K L. Geostandards and Geoanalytical Research, 2008, 32(4): 453.
[9] Tetsuya Nakazato, Mikio Akasaka, Hiroaki Tao. Analytical and Bioanalytical Chemistry, 2006, 386(5):1515.
[10] HUANG Zhi-wei, WANG Xian, QIU Hai-yuan, et al(黄智伟，王 宪，邱海源，等). Journal of Xiamen University(厦门大学学报)， 2007，46(A01)： 103.
[11] GU Xiao-zhi, ZHANG Gang-ya, DAI Rong-ling, et al(古小治，章钢娅，戴荣玲，等). Chinese Journal of Analysis Laboratory (分析试验室)，2008，27(8)：17.
[12] Yang X J, Low G K C. Environmental Chemistry Letters，2009，7(4)：381.
[13] Huang Yi, Zhang Taiming, Cao Juan, et al. Journal of Central South University of Technology, 2007, 14(4): 514.
[14] Amoli H Salar, Barker J, Flowers A. Journal of Radioanalytical and Nuclear Chemistry, 2007, 273(2): 281.
[15] Novozamsky Ivo, Lee Hans J van der. Mikrochim Acta, 1995, 119: 183.
[16] TIAN Bao-zhen, CAO Fu-cang, LEI Peng-ju, et al(田宝珍，曹福苍，雷鹏举，等). Food and Frementation Industries(食品与发酵工业)，2000，26(3)：15.
[17] FAN Ying, HUANG Yun, MENG Zhao-yu, et al(樊 瑛，黄 云，孟昭宇，等). Arid Environmental Monitoring(干旱环境监测)，2007，21(2)：73.
|
| [1] |
FAN Ping-ping，LI Xue-ying，QIU Hui-min，HOU Guang-li，LIU Yan*. Spectral Analysis of Organic Carbon in Sediments of the Yellow Sea and Bohai Sea by Different Spectrometers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 52-55. |
| [2] |
JIA Zong-chao1, WANG Zi-jian1, LI Xue-ying1, 2*, QIU Hui-min1, HOU Guang-li1, FAN Ping-ping1*. Marine Sediment Particle Size Classification Based on the Fusion of
Principal Component Analysis and Continuous Projection Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3075-3080. |
| [3] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
| [4] |
WANG Yan1, HUANG Yi1, 2*, YANG Fan1, 2*, WU Zhong-wei2, 3, GUAN Yao4, XUE Fei1. The Origin and Geochemical Characteristics of the Hydrothermal Sediments From the 49.2°E—50.5°E Hydrothermal Fields of the Southwest Indian Ocean Ultra-Slow Spreading Ridge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2868-2875. |
| [5] |
GUO Xiao-hua1, ZHAO Peng1, WU Ya-qing1, TANG Xue-ping3, GENG Di2*, WENG Lian-jin2*. Application of XRF and ICP-MS in Elements Content Determinations of Tieguanyin of Anxi and Hua’an County, Fujian Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3124-3129. |
| [6] |
WU Bing, YANG Ke-ming*, GAO Wei, LI Yan-ru, HAN Qian-qian, ZHANG Jian-hong. EC-PB Rules for Spectral Discrimination of Copper and Lead Pollution Elements in Corn Leaves[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3256-3262. |
| [7] |
ZHANG Fei1, 5，HUA Xia2*，YUAN Jia-ying3，YOU Fan1，YE Ren-cai4，DING Li4, ZHAO Jian-mei4. Determination of Thallium in Blood of Occupational Exposed Population by Inductively Coupled Plasma Mass Spectrometry With High Matrix Introduction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2870-2874. |
| [8] |
ZHANG Xuan1, 2, 3, WANG Chang-hua1, 2, HU Fang-fei1, 2, MO Shu-min1, 2, LI Ji-dong1, 2, 3*. Determination of Nb and Re in High Purity Tungsten by Precipitation Separation-Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2169-2174. |
| [9] |
ZHU Zhao-zhou1*, YANG Xin-xin1, LI Jun1, HE Hui-jun2, ZHANG Zi-jing1, YAN Wen-rui1. Determination of Rare Earth Elements in High-Salt Water by ICP-MS
After Pre-Concentration Using a Chelating Resin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1862-1866. |
| [10] |
ZHENG Pei-chao, LIU Ran-ning, WANG Jin-mei, FENG Chu-hui, HE Yu-tong, WU Mei-ni, HE Yu-xin. Solution Cathode Glow Discharge-Atomic Emission Spectroscopy Coupled With Hydride Generation for Detecting Trace Mercury and Tin in Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1139-1143. |
| [11] |
LI Xue-ying1, 2, LI Zong-min3*, CHEN Guang-yuan4, QIU Hui-min2, HOU Guang-li2, FAN Ping-ping2*. Prediction of Tidal Flat Sediment Moisture Content Based on Wavelet Transform[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1156-1161. |
| [12] |
LI Xue-ying1, 3, LI Zong-min2*, HOU Guang-li3, QIU Hui-min3, LÜ Hong-min3, CHEN Guang-yuan4, FAN Ping-ping3*. Carbon Content Detection of Marine Sediments Based on Multispectral Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2898-2903. |
| [13] |
MENG Ru2,4, DU Jin-hua1,2*, LIU Yun-hua1,2, LUO Lin-tao1,3, HE Ke1,2, LIU Min-wu1,2, LIU Bo1,3. Exploration of Digestion Method for Determination of Heavy Metal Elements in Soil by ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2122-2128. |
| [14] |
ZHANG Fei1，HUA Xia2，YOU Fan1，WANG Bin3，MAO Li3*. Determination of Thallium and Its Compounds in Workplace Air by Ultrasonic Extraction-Inductively Coupled Plasma Mass Spectrometry Using No Gas Mode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2279-2283. |
| [15] |
BO Wei, LI Xiao-li*, DU Xue-miao, LIU Bin, ZHANG Qin, BAI Jin-feng. Investigation of a High-Pressure Pressed Powder Pellet Covered With Polyester Film Technique for the Determination of Chlorine in Soil and Sediment by X-Ray Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1828-1833. |
|
|
|
|
