光谱学与光谱分析 |
|
|
|
|
|
Synthesis, Structure and Surface Photovoltage Spectrum of Coordination Supramolecule: [Cu(phen)(H2O)2·SO4] |
KOU Jin |
Police Technology Department, Liaoning Police Academy, Dalian 116036, China |
|
|
Abstract A novel transition metal coordination supramolecule [Cu(phen)(H2O)2·SO4] has been synthesized by hydrothermally method. The single crystal structure was determined by X-ray diffraction, and the complex was characterized by IR and UV-Vis-NIR spectra. The structure analysis indicates that there are a lot of hydrogen bonds in the crystal, which make the complex form a 1D double chain coordination supramolecule. Surface photovoltage spectroscopy (SPS) technique was applied to detect surface electron behavior and study the photoelectric conversion capability of the complexes. SPS is a useful tool for surveying the charge change of solid material surface. Its sensitivity comes to 108 q·cm-2,which exceeds that of conventional spectroscopy such as XPS and Auger spectroscopy by many orders of magnitude. But long time, the study of SPS has mainly focused on inorganic semiconductor and organic semiconductor. There are seldom reports about the coordination polymers and supramolecules. The results of surface photovoltage spectrum (SPS) indicate that the complex exhibit positive surface photovoltage responses in the range of 300-800 nm. The induced surface photovoltage spectrum (FISPS) proved that the complex possesses the characteristic of p-type semiconductor.
|
Received: 2007-05-12
Accepted: 2007-08-09
|
|
Corresponding Authors:
KOU Jin
E-mail: koujin2008@sina.com
|
|
[1] Mukhopadhyay S, Armstroong W H. J. Am. Chem. Soc.,2003, 125(43): 13010. [2] Panak P, Klenze R, Kim J I. J. Alloys Compounds, 1995,225:261. [3] LI G, HOU H W, NIU Y Y. Inorg. Chim. Acta,2002, 332: 216. [4] Wang Yaoyu, Shi Qian, Shi Qizhen. Polyhedron, 1999, 18(5): 2009. [5] XIANG Yang, LU Chun-su(向 阳, 鲁纯素). Acta Biochim. Biophys. Sinica(生物化学与生物物理学报), 1992,24: 117. [6] Godbole M D, Kloskowski M. European Journal Inorg. Chem., 2005,(2): 305. [7] ZHANG Dong-mei, FAN Yu-hua, BI Cai-feng, et al(张栋梅, 范玉华, 毕彩丰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27(2): 335. [8] ZHAO Yong-liang, YANG Xiao-hua, MO Ri-gen(赵永亮, 杨晓华, 莫日根). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(2): 223. [9] FANG Y Y, LIU H, DU M. J. Mol. Struct.,2002, 608(2-3): 229. [10] ZHAO Guang-chao, ZHU Jun-jie, CHEN Hong-yuan(赵广超, 朱俊杰, 陈洪渊). Chemical Journal of Chinese Universities(高等学校化学学报),2003,24: 414. [11] Breuning E, Ziener U, Lehn J M. European Journal of Inorg. Chem.,2001, (6): 1515. [12] NIU Shu-yun, FAN Hong-tao, JIN Jing(牛淑云, 范洪涛, 金 晶). Chinese Science Bulletin(科学通报),2004, 49(15): 1499. [13] ZHANG Fang, ZHANG Qian-qian, LU Xiao-lan, et al(张 芳, 张前前, 陆小兰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27(2): 302. [14] LE Xue-yi, TONG Ming-liang(乐学义, 童明良). Chinese Journal of Inorganic Chemistry(无机化学学报),2002, 18(10): 1023. [15] WANG Zhong-ming, ZHOU Zhi-fen, LIN Hua-kuan, et al(汪中明,周志芬,林华宽,等). Chinese Journal of Inorganic Chemistry(无机化学学报),2000,16(3):503. [16] LI Hong, LE Xue-yi, WU Jian-zhong, et al(李 红,乐学义,吴建中,等). Acta Chimica Sinica(化学学报),2003,61(2):245. [17] Hirohama Tomoya, Yuko Kuranuki, Ebina Ebina, et al. Journal of Inorganic Biochemistry,2005, 99: 1205. [18] ZHOU Qing-hua, YANG Pin(周庆华,杨 频). Acta Chimica Sinica(化学学报),2005,63:71. [19] LI Rui-ping, FAN Qiong-fang, GUO Jian-xiong(李瑞萍,范琼芳,郭建雄). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2003,23(2):288. [20] LIN Y H, WANG D J, ZHAO Q D. J. Phys. Chem. B,2004, 108(10): 3202. [21] YU Jian-feng, WU Tong-hao, WANG De-jun(于剑锋,吴通好,王德军). Acta Chimica Sinica(化学学报),1996, 54:853. |
[1] |
WAN Mei, ZHANG Jia-le, FANG Ji-yuan, LIU Jian-jun, HONG Zhi, DU Yong*. Terahertz Spectroscopy and DFT Calculations of Isonicotinamide-Glutaric Acid-Pyrazinamide Ternary Cocrystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3781-3787. |
[2] |
ZHANG Yan-dong1, WU Xiao-jing1*, LI Zi-xuan1, CHENG Long-jiu2. Two-Dimensional Infrared Spectroscopic Study of Choline
Chloride/Glycerin Solution Disturbed by Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3047-3051. |
[3] |
ZHU Xiang1, 2, YUAN Chao-sheng2, LIANG Yong-fu2, WANG Zheng2, LI Hai-ning2, HUANGFU Zhan-biao1, ZHOU Song1, ZHOU Bo1, DONG Xing-bang1, CHENG Xue-rui2*, YANG Kun1*. Study on the Effect of Cooling Rate on Crystallization Process and
Product of [C12mim][BF4] Melt Based on POM, Raman and SAXS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 801-805. |
[4] |
HU Qing-cheng, ZHAO Hai-wen. A Flexible Water Structure: Evidence From Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3753-3758. |
[5] |
ZHANG Tong-jun, LI De-hua, CAO Qiu-hong, LIN Hong-mei, HAO Jian-jun. Experimental Measurement and Theoretical Simulation on Terahertz Spectra of Crystal Acetamiprid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2012-2017. |
[6] |
QIAN Kun, BAI Zhi-chen, WU Rui, WANG Jia-hui, SU Bo*, WEN Yi-wei, ZHANG Cun-lin. Terahertz Transmission Characteristics of Electrolyte Solution[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2018-2022. |
[7] |
DONG Pei-jie1, ZHANG Wen-bo1*, LU Wei2. A NIR Study on Hydrogen Bonds of Bamboo-Based Cellulose Ⅱ[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1260-1264. |
[8] |
College of Information Science and Technology, Nanjing Forestry University, Nanjing 210037, China
. Investigation on Terahertz Spectroscopy of Food Additives Based on Dispersion-Correction Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 100-104. |
[9] |
WANG Yu1, LUO Lan1, 2*, GUO Rui1, SUN Chuan-yao1, GAO Ming-yuan1. Cation Substitution-Dependent Phase Transition and Color-Tunable Emission in (Ca1-xBax)2SiO4∶Eu Phosphor Series[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1895-1901. |
[10] |
HE Jian, LI Ai-sen, WANG Jing, XU Shu-ping, XU Wei-qing*. Spectral and Structural Investigation on Weak Interactions of Bipyridine/Pentafluorophenol and Bipyridine/Pentafluorobenzoic Acid Co-Crystals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1393-1396. |
[11] |
FANG Zi-qiu1,2, CHEN Guo-qing1,2*, WU Ya-min1,2. Studyon the Spectral Properties of Riboflavin in Different Polar Solvents[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1132-1136. |
[12] |
REN Yu-fen, CHENG Xue-rui*, WANG Yong-qiang, YANG Kun, YUAN Chao-sheng, ZHANG Meng-wei. Research on Hydrogen Bonds and Conformations of n-Pentanol under High Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 694-699. |
[13] |
ZHANG Hong1, WANG Le1*, LUO Dong1, ZHENG Zi-shan1, LI Yang-hui1, 2, PAN Gui-ming1. Structural and Luminescence Properties of Eu2+ Doped CaAlSiN3 Silicon Nitride Red Emitting Phosphor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 59-64. |
[14] |
LIN Qing-feng, ZHOU Liang-liang, SUN Yan-qiong*, CHEN Yi-ping. The Hydrothermal Synthesis, Crystal Structure and Spectral Properties of a 2D Pr-Cd Heterometal Complex[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(10): 3034-3039. |
[15] |
WU Ya-xiong, SU Bo*, HE Jing-suo, ZHANG Cun-lin. Terahertz Absorption Properties of Electrolyte Solutions Based on Microfluidic Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2348-2353. |
|
|
|
|