| 光谱学与光谱分析 |
|
|
|
|
|
| Measurement and Analysis of Nanometer Particles of Silica and Carbon Black by Diffuse Reflection FTIR Spectra |
| YANG Xiao-zhan1,TANG Chong-min1,LIU Zi-li2,YAO Yong-yi1,LI Rui-xia1,WU Da-cheng1* |
1. Textile Research Institute, Sichuan University, Chengdu 610065, China
2. Chengdu Donglanxing Sci-Tech Company, Chengdu 610051, China |
|
|
|
|
Abstract By using FTIR-FTS3000 spectrometer and infrared diffuse reflection accessory, the spectra of the nanometer particles of silica, carbon black and their blends with different weight ratio were collected and characterized. It was found from the measured results that blue-shift and broadening phenomenon occurred in the nanometer particle materials in comparison with the mass ones. These phenomena could be explained by the little size effect and quantum size effect. No perfect spectrum could be collected because of the strong absorbance of the nanometer particle materials. For the blends of silica and carbon black there was a maximum absorption corresponding to the critical concentration, where the weight ratio of silica to carbon black was 100∶20, and below this ratio the relationship between the function F(R) and the concentration obeyed Lambert-Beer’s law. Above this ratio, the absorbance will not increase with increasing the proportion of the carbon black in the system.
|
|
Received: 2006-10-08
Accepted: 2007-02-06
|
|
|
|
Corresponding Authors:
WU Da-cheng
E-mail: wdc@email.scu.edu.cn
|
|
[1] Nishizawa N, Nishimara J, Saitoh H, et al. Progress in Organic Coatings,2005, 53: 306.
[2] Jerome D, Jean-Pierre B, John B, et al. Thin Solid Film,2004, 466: 114.
[3] Tepper T, Berger S. Materials Science and Engineering C,2001, 15: 195.
[4] WU Jin-guang(吴瑾光). The Technique and Application of Neoteric FTIR Spectrum(近代傅里叶变换红外光谱技术及应用). Beijing: Science and Technology Literature Press(北京：科技文献出版社), 1994.
[5] WU Yan-ping, YUAN Hong-fu, LU Wan-zhen, et al(吴艳萍，袁洪福，陆婉珍，等). Acta Petrolei Sinica(Petroleum Processing Section)(石油学报·石油加工)，2003，19(5)：86.
[6] BAI Qi-lin, CHEN Shao-jiang, DONG Xiao-ling, et al(白琪琳，陈绍江，董晓玲，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2004，24(11)：1345.
[7] ZHANG Hong-yan, DING Dong, SONG Li-qiang, et al(张洪艳，丁 东，宋立强，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(6)：882.
[8] Lü Li-na, ZHANG Yue, ZHOU Ding-wen(吕丽娜，张玥，周定文). Journal of Tianjin University(天津大学学报)，2004，37(21)：1093.
[9] ZHANG Xiao-juan, LIU Ying(张小娟，刘 迎). Journal of Optoelectronics·Laser(光电子·激光)，2005，16(1)：124.
[10] DU De-guo, SUN Su-qin, ZHOU Qun, et al(杜德国，孙素琴，周 群，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2000，20(4)：474.
[11] ZHANG Li-de, MOU Ji-mei(张立德, 牟季美). Nanometer Materials Science(纳米材料学). Beijing: Science Press(北京：科学出版社),2001. 81. |
| [1] |
LIU Wen-bo, LIU Jin, HAN Tong-shuai*, GE Qing, LIU Rong. Simulation of the Effect of Dermal Thickness on Non-Invasive Blood Glucose Measurement by Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2699-2704. |
| [2] |
YAN Xue-jun1, ZHOU Yang2, HU Dan-jing1, YU Dan-yan1, YU Si-yi1, YAN Jun1*. Application of UV-VIS Diffuse Reflectance Spectrum, Raman and
Photoluminescence Spectrum Technology in Nondestructive
Testing of Yellow Pearl[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1703-1710. |
| [3] |
CUI De-jian1, LIU Yang-yang1, XIA Yuan-tian1, JIA Wei-e1, LIAN Zheng-xing2, LI Lin1*. Non-Destructive Detection of Egg Fertilization Status Based on Hyperspectral Diffuse Reflectance[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3685-3691. |
| [4] |
YAN Jun1, FANG Shi-bin1, YAN Xue-jun1, SHENG Jia-wei2, XU Jiang1, XU Chong3, ZHANG Jian2*. Study on the Common Effect of Heat Treatment, Dyeing or Irradiation Treatment on UV-Vis Diffuse Reflectance Spectra of Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3697-3702. |
| [5] |
FANG Shi-bin1, JIANG Yang-ming1, YAN Jun1, 2, YAN Xue-jun1, ZHOU Yang3, ZHANG Jian2*. The Types of UV-Vis Diffuse Reflectance Spectra of Common Gray Pearls and Their Coloring Mechanism[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3703-3708. |
| [6] |
WANG Jing1, 2*, CHEN Zhen3, GAO Quan-zhou1. Diffuse Reflectance Spectroscopy Study of Mottled Clay in the Coastal
Area of Fujian and Guangdong Provinces and the Interpretation of Its
Origin and Sedimentary Environment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2494-2498. |
| [7] |
ZHU Meng-yuan1, 2, LÜ Bin1, 2*, GUO Ying2. Comparison of Haematite and Goethite Contents in Aeolian Deposits in Different Climate Zones Based on Diffuse Reflectance Spectroscopy and Chromaticity Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1684-1690. |
| [8] |
ZHANG Fu1, 2, 3, CUI Xia-hua1, DING Ke4*, ZHANG Ya-kun1, WANG Yong-xian1, PAN Xiao-qing5. Study on the Influence of Different Pretreatment Methods on Gender Determination of Multiposition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 434-439. |
| [9] |
YANG Jiong1, 2, QIU Zhi-li1, 4*, SUN Bo3, GU Xian-zi5, ZHANG Yue-feng1, GAO Ming-kui3, BAI Dong-zhou1, CHEN Ming-jia1. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 446-453. |
| [10] |
XU Zhao-jin, LI Dong-liang, SHEN Li*. Study on Diffuse Reflection and Absorption Spectra of Organic and Inorganic Chinese Painting Pigments[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3915-3921. |
| [11] |
ZHANG Fu1, 2, 3, CUI Xia-hua1, ZHANG Ya-kun1, WANG Yong-xian1. Relationship Between Visible/Near Infrared Spectral Data and Fertilization Information at Different Positions of Hatching Eggs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3064-3068. |
| [12] |
LI Hao-guang1,2, YU Yun-hua1,2, PANG Yan1, SHEN Xue-feng1,2. Study on Near-Infrared Spectrum Acquisition Method of Non-Uniform Solid Particles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2748-2753. |
| [13] |
LIU Yan-de, WANG Jun-zheng, JIANG Xiao-gang, LI Li-sha, HU Xuan, CUI Hui-zhen. Research on Vis/NIR Detection of Apple’s SSC Based on Multi-Mode Adjustable Optical Mechanism[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2064-2070. |
| [14] |
WANG Peng1,2, SUN Di2, MU Mei-rui3, LIU Hai-xue3, ZHANG Ke-qiang2, MENG Xiang-hui1, YANG Ren-jie1*, ZHAO Run2*. Rapid Detection of Total Nitrogen Through the Manure Movement of in Large-Scale Dairy Farm by Near-Infrared Diffuse Reflectance Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3287-3291. |
| [15] |
ZHOU Peng, LI Min-zan*, YANG Wei, JI Rong-hua, MENG Chao. Development of Vehicle-Mounted in-situ Soil Parameters Detector Based on NIR Diffuse Reflection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2856-2861. |
|
|
|
|
