光谱学与光谱分析 |
|
|
|
|
|
Identification of Yougui and Jisheng Shenqi Pills with FTIR and EDS Fingerprint Spectra by New Visual Comparison |
WANG Li-shuang, ZOU Hua-bin*, TIAN Fang, DU Ai-qin, DONG Feng-juan, ZHANG Xin-ling |
School of Chemistry and Chemical Engineering of Shandong University, Ji’nan 250100, China |
|
|
Abstract FTIR combined with EDS fingerprint spectra was first applied to the identification of two kind of traditional Chinese compound formulae-Yougui pill and Jisheng shenqi pills, which have the similar composition. The IR FPS of extraction of two kinds of pills extracted with chloroform were measured by liquid membrane method. The exclusively characteristic peak groups of these two kinds of formulae were theoretically established based on the Shapiro-Wilk W testing method,and the characteristic radicals and compound species corresponding to each characteristic peak were determined. Meanwhile, EDS fingerprint spectra of the two kinds of original powders were also measured which can reflect the element species and content information. Based on the three kinds of information (characteristic peak groups, radicals and compound species, different elements), Yougui and Jisheng shenqi pills were identified quickly, precisely and reliably. In this method, infrared fingerprint spectra possess the similar ability with chromatograph fingerprint spectra in identification of traditional Chinese compound formulae. The results show that the new visual comparison method is suitable for identifying traditional Chinese compound formulae with the same dosage-form and similar composition.
|
Received: 2010-11-07
Accepted: 2011-02-20
|
|
Corresponding Authors:
ZOU Hua-bin
E-mail: huabinzou@hotmail.com
|
|
[1] Zou Huabin, Yang Guosheng, Qin Zhengran, et al. Analytical Letters, 2005, 38(9): 1457. [2] ZOU Hua-bin, ZHANG Xin-ling, ZHAI Hong, et al(邹华彬,张新玲,翟 红, 等). China Journal of Chinese Materia Medica(中国中药杂志), 2008, 33(13): 1543. [3] Zhu Hongbin, Wang Yuzhi, Liang Hao, et al. Talanta, 2010, 81: 129. [4] Vodnar Dan C, Socaciu Carmen, Rotar Ancuta M, et al. International Journal of Food Science and Technology, 2010, 45(11): 2345. [5] WANG Xian-hao, GU Hui(王贤浩,顾 辉). Journal of Chinese Electron Microscopy Society(电子显微学报), 2009, 28(4): 318. [6] LI Yun-fen(李云芬). Chinese Journal of Modern Applied Pharmacy(中国现代应用药学杂志),1999, 16(4): 57. [7] HUANG Rong-fa, TANG Chun-hua(黄荣发,唐春华). Journal of Jiangxi College of Traditional Chinese Medicine(江西中医学院学报), 2001, 13(3): 116. [8] SHE Meng-xiang(佘孟祥). Hubei Journal of Traditional Chinese Medicine(湖北中医杂志),1999, 22(1): 45. [9] ZOU Hua-bin, YUAN Jiu-rong, WANG Wei(邹华彬,袁久荣,王 伟). World Science Technology Modernization of Traditional Chinese Medicine(世界科学技术-中医药现代化), 2004, 6(2): 51. |
[1] |
ZHAO Wen-hua1, 2, HAN Xiang-na1*, YE Lin2, BAI Jiu-jiang2. Accurate Identification of Common Soluble Salts in Cultural Relics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3826-3831. |
[2] |
JIA Hao1, 3, 4, ZHANG Wei-fang1, 3, LEI Jing-wei1, 3*, LI Ying-ying1, 3, YANG Chun-jing2, 3*, XIE Cai-xia1, 3, GONG Hai-yan1, 3, DING Xin-yu1, YAO Tian-yi1. Study on Infrared Fingerprint of the Classical Famous
Prescription Yiguanjian[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3202-3210. |
[3] |
WU Shan, ZHANG Ming-zhe, YU Hui-zhen, CHEN Zhe, YIN Wen-xiu, ZHANG Quan, SHEN Xu-fang, SUN Chao, QIU Hui, SHUAI Jiang-bing, ZHANG Xiao-feng*. Ivory Identification Based on Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2397-2406. |
[4] |
DENG Xiao-jun1, 2, MA Jin-ge1, YANG Qiao-ling3, SHI Yi-yin1, HUO Yi-hui1, GU Shu-qing1, GUO De-hua1, DING Tao4, YU Yong-ai5, ZHANG Feng6. Visualized Fast Identification Method of Imported Olive Oil Quality Grade Based on Raman-UV-Visible Fusion Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1117-1125. |
[5] |
LIU Xin-yu1, SHAO Wen-wu2*, ZHOU Shi-rui3. Spectral Pattern Recognition of Cardiac Tissue in Electric Shock Death and Post-Mortem Electric Shock[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1126-1133. |
[6] |
ZHANG Li-qian1, 2, LIU Yang-jie2, 3, LIN Bing-lan2, DUAN Jun1. Comparative Study on Mineralogical Identification and Spectral
Characteristics of Halloysitum Album, a Commercial Mineral
Medicine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 897-902. |
[7] |
LIU Feng-xiang, HE Shuai, ZHANG Li-hao, HUANG Xia, SONG Yi-zhi*. Application of Raman Spectroscopy in Detection of Pathogenic Microorganisms[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3653-3658. |
[8] |
ZHU Gui-jun, WANG Gan-zhen, PENG Jun*, TIAN Zong-ping, HOU Zhi-hua. The Mineralogical and Spectroscopic Characteristics of Phosphohedyphane From Chenzhou of Hunan Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3017-3023. |
[9] |
ZHANG Li-qian1, 2, LIU Yang-jie2, 3. Comparative Study on Mineralogical Identification and Spectral
Characteristics of Four Iron-Containing Mineral Medicines[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2884-2889. |
[10] |
JING Jian-yuan, YUAN Liang, ZHANG Shui-qin, LI Yan-ting, ZHAO Bing-qiang*. Multispectral Structural Characterization of Humic Acid-Enhanced Urea[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2610-2615. |
[11] |
LI Huan-tong1, 2, ZHU Zhi-rong1, 2, QIAO Jun-wei1, 2, LI Ning3, YAO Zheng3, HAN Wei1, 2. Molecular Representations of Jurassic-Aged Vitrinite-Rich and
Inertinite-Rich Coals in Northern Shannxi Province by
FTIR, XPS and 13C NMR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2624-2630. |
[12] |
ZHANG Fu1, 2, 3, CUI Xia-hua1, DING Ke4*, ZHANG Ya-kun1, WANG Yong-xian1, PAN Xiao-qing5. Study on the Influence of Different Pretreatment Methods on Gender Determination of Multiposition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 434-439. |
[13] |
TANG Ming-zhu1, WANG Zhi-ying1, WANG Yun-shan2*, BAO Wei-jun2, YANG Gang2, SUN Yong3. Characterization of the Impurity Phases in Phosphogypsum by the EBSD-XPS Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 136-140. |
[14] |
RUAN Zhen1, ZHU Peng-fei3, ZHANG Lei3, CHEN Rong-ze3, LI Xun-rong3, FU Xiao-ting3, HUANG Zheng-gu4, ZHOU Gang4, JI Yue-tong5, LIAO Pu1, 2*. Study on Identification of Non-Tuberculosis Mycobacteria Based on Single-Cell Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3468-3473. |
[15] |
ZHANG Ying-qiang1, ZHANG Shui-qin2, WANG Li-yan1*, YUAN Liang2, LI Yan-ting2, XIONG Qi-zhong3, LIN Zhi-an2, ZHAO Bing-qiang2*. Multispectral Structural Characterization of Low-Molecular-Weight Organic Acids Modified Urea[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3129-3136. |
|
|
|
|