| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of Trace Elements Be, Cd, As and Pb in Air of Residential Areas by Inductively Coupled Plasma-Mass Spectrometry Coupled with Ultrasonic Leaching |
| CHEN Xi, DING Liang, HE Gong-li, XU Xiao-ya, ZHANG Miao, XU Dong-qun，LIN Shao-bin* |
| Institute of Environmental Health & Related Products Safety, Chinese Center for Disease Control Prevention, Beijing 100021, China |
|
|
|
|
Abstract In the present paper, the method for determining the trace elements Be, Cd, As and Pb in air of residential areas by inductively coupled plasma-mass spectrometry was established. Ultrasonic leaching procedures were applied to extract the trace elements from the filter membrane of the atmospheric particulates. The operating condition of the instrument was optimized. 72Ge, 115In and 204Tl were chosen as the internal elements and the effect of matrix, interface and fluctuation of instrument was overcome effectively. Satisfactory linearity of working curves of four elements was obtained, giving all the correlation coefficients over 0.999 5, and the detection limit of the method was between 0.006 and 0.045 ng·m-3. The mean values of National Standard Reference Material GBW(E)080212 were in agreement with the certified values. The sampling filters membranes, divided into four equal parts and with added standard solution with different concentions were analyzed, and the recovery rate of samples were in the range of 91.6%～109.7% with the related standard deviation between 0.7% and 4.8%. The obtained results showed that the method of determining the trace elements Be, Cd, As and Pb in air of residential areas by inductively coupled plasma-mass spectrometry proved to be simple, accurate, sophisticated and stable.
|
|
Received: 2011-03-07
Accepted: 2011-05-08
|
|
|
|
Corresponding Authors:
LIN Shao-bin
E-mail: shaobin_lin@yahoo.com.cn
|
|
[1] ZHONG Ge-mei, TANG Zhen-zhu(钟格梅, 唐振柱). Journal of Environment and Health(环境与健康杂志)，2010, 23(6): 562.
[2] Winchester J W, Bi Mutian. Atmospheric Environment，1984, 18: 1399.
[3] Frank Schaumann, Paul J A Borm, Andreas Herbrich, et al. American Journal of Respiratory and Critical Care Medicine，2004, 170: 898.
[4] LI Jin-xiang, QIU Qi-hong, XIN Lian-zhong，et al(李金香, 邱启鸿, 辛连忠, 等). Environmental Monitoring of China(中国环境监测), 2007, 23(2): 89.
[5] PENG Rong-fei, HOU Jian-rong, HUANG Cong(彭荣飞, 侯建荣, 黄 聪). Chinese Journal of Health Laboratory Technology(中国卫生检验杂志)，2010, 20(12): 3166.
[6] YANG Chao-yong, ZHUANG Zhi-xia, GU Sheng, et al(杨朝勇, 庄峙厦, 谷 胜, 等). Journal of Instrumental Analysis(分析测试学报)，2001, 20(2)：87.
[7] LI Bing, HU Jing-yu, ZHAO Mo-tian(李 冰, 胡静宇, 赵墨田). Journal of Chinese Spectroetry Society(质谱学报), 2010, 31(1)：2.
[8] WANG Xiao-ru(王小如). Application of Inductively Coupled Plasma Mass Spectrometry(电感耦合等离子体质谱应用实例). Beijing：Chemical Industry Press(北京: 化学工业出版社), 2005. 80.
[9] DAI Shu-gui(戴树桂). Advances in Environmental Chemistry(环境化学进展). Beijing：Chemical Industry Press(北京: 化学工业出版社), 2005. 12, 21, 48.
[10] US EPA. Standard Operating Procedure for the Determination of Metals In Ambient Particulate Matter Analyzed By Inductively Coupled Plasma/Mass Spectrometry (ICP/MS), 2005.
[11] US EPA Method 6020A. Inductively Coupled Plasma-Mass Spectrometry，2007.
[12] LIU Hu-sheng, SHAO Hong-xiang(刘虎生，邵宏翔). Technology and Application of Inductively Coupled Plasmas-Mass Spectrometry(电感耦合等离子体质谱技术与应用). Beijing：Chemical Industry Press(北京: 化学工业出版社), 2005. 120.
[13] GAO Yan, WANG Dong-hai, LIN Yu-bin(高 焰, 王东海, 林玉斌). Environmental Monitoring of China(中国环境监测), 2003, 19(4): 36.
[14] GOU Yong, CHEN Zi-jin(苟 勇, 陈子金). Modern Preventive Medicine(现代预防医学), 2009, 36(10): 1941. |
| [1] |
GUO Xiao-hua1, ZHAO Peng1, WU Ya-qing1, TANG Xue-ping3, GENG Di2*, WENG Lian-jin2*. Application of XRF and ICP-MS in Elements Content Determinations of Tieguanyin of Anxi and Hua’an County, Fujian Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3124-3129. |
| [2] |
ZHANG Fei1, 5，HUA Xia2*，YUAN Jia-ying3，YOU Fan1，YE Ren-cai4，DING Li4, ZHAO Jian-mei4. Determination of Thallium in Blood of Occupational Exposed Population by Inductively Coupled Plasma Mass Spectrometry With High Matrix Introduction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2870-2874. |
| [3] |
ZHANG Xuan1, 2, 3, WANG Chang-hua1, 2, HU Fang-fei1, 2, MO Shu-min1, 2, LI Ji-dong1, 2, 3*. Determination of Nb and Re in High Purity Tungsten by Precipitation Separation-Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2169-2174. |
| [4] |
ZHU Zhao-zhou1*, YANG Xin-xin1, LI Jun1, HE Hui-jun2, ZHANG Zi-jing1, YAN Wen-rui1. Determination of Rare Earth Elements in High-Salt Water by ICP-MS
After Pre-Concentration Using a Chelating Resin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1862-1866. |
| [5] |
ZHANG Fei1，HUA Xia2，YOU Fan1，WANG Bin3，MAO Li3*. Determination of Thallium and Its Compounds in Workplace Air by Ultrasonic Extraction-Inductively Coupled Plasma Mass Spectrometry Using No Gas Mode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2279-2283. |
| [6] |
ZHAO Ting1,2,3, CHI Hai-tao1,2,3*, LIU Yi-ren1,2,3, GAO Xia1,2,3, HUANG Zhao1,2,3, ZHANG Mei1,2,3, LI Qin-mei1,2,3. Determination of Elements in Health Food by X-Ray Fluorescence Microanalysis Combined With Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 750-754. |
| [7] |
ZHOU An-li1, JIANG Jin-hua1, SUN Chun-xiao2, XU Xin-zhong2, LÜ Xin-ming1,2*. Identification of Different Origins of Hetian Jade Based on Statistical Methods of Multi-Element Content[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3174-3178. |
| [8] |
ZHANG Liang-liang, WANG Chang-hua, HU Fang-fei, MO Shu-min, LI Ji-dong*. Determination of Trace Impurity Elements in Zircaloy by Ion Exchange-Inductively Coupled Plasma Mass Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2622-2628. |
| [9] |
ZHAO Qian-qian1, YAN Lai-lai1,2, XIE Qing1,2, LIU Ya-qiong1,2, YANG Si-yu1, GUO Chen1, WANG Jing-yu1,2*. Effect of Zinc on the Growth and Element Content of Lactobacillus Acidophilus[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1489-1494. |
| [10] |
LIAO Qin-jing, HUANG Wei-zhi, ZHANG Qian, PEI Jing-cheng*. Gemological and Spectral Characterization of Brownish Yellow Tourmaline from Mozambique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(12): 3844-3848. |
| [11] |
SUN Qi-xuan, WEI Xing, LIU Xun, YANG Ting, CHEN Ming-li*, WANG Jian-hua*. Atomic Spectrometry/Elemental Mass Spectrometry in Bioanalytical Chemistry: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1340-1345. |
| [12] |
LIU Rui1, Lü Yi1，2*. Metal Stable Isotope Tagging-Based Bioassay[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1346-1353. |
| [13] |
LIU Liu1, 2, LIU Zhe1, YANG Yi-bing3, WANG Qin1, XU Dong-qun1*. Determination of 21 Inorganic Elements in Urine Samples by ICP-MS Using KED System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(04): 1262-1266. |
| [14] |
LIANG Piao-piao1, WANG Yi-run1, WANG Ru-ming1, FAN Li-yun1, CHEN Tian-tian1, BAI Ya-hong1, YU Qian-ru1, ZHOU Shan-shan1, LIU Ying1,2*. Level and Risk Assessment of Arsenic in Muti-Media near Mining Area in Yunnan by Using Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(03): 990-996. |
| [15] |
LIANG Piao-piao1, XING Yun-xin1, WEI Chun-li1, LI Yuan-yuan1, LIU Yi-ming1, HU Yu1, LIU Ying1,2*. Distribution and Assessment of Heavy Metals in the Overlying Water-Sediment-Plant-Fish System in the Wuliangsuhai Lake by Using Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 652-658. |
|
|
|
|
