光谱学与光谱分析 |
|
|
|
|
|
Experimental Study on Raman Spectroscopy of Alkane Gases in Simulated Deep-Sea Extreme Environments |
MA Jun, QU Ye-fei, HUANG Yang-yu, YANG Cheng-en, SHI Xiao-feng, ZHENG Rong-er |
College of Information Science and Engineering, Ocean University of China, Qingdao 266100, China |
|
|
Abstract In the present work, Raman spectra of alkane gases aqueous solution under simulated deep-sea hydrothermal environment were acquired by high temperature and high pressure deep-sea simulation experiment system. The variation laws of the Raman spectral features with various temperature and pressure were analyzed and mathematical model between them were established. The results show that for all Raman peaks of these alkane gases in aqueous solution the frequency is lower than gaseous state because of hydrogen bond; the variations of their Raman spectrum were not obvious as the pressure increased (≤40 MPa) in room temperature; and all peak positions move to lower wave number and their full width at half maximum (FWHM) increased along with changing temperature in the range of room temperature to 350 ℃ at 40 MPa pressure. The results provide an experimental basis for the in-situ detection of deep sea by Raman laser spectroscopy system in hydrothermal environment.
|
Received: 2010-04-22
Accepted: 2010-07-26
|
|
Corresponding Authors:
MA Jun
E-mail: majun@ouc.edu.cn
|
|
[1] White S N,Dunk R M,Peltzer E T,et al. Geochemistry Geophysics Geosystems,2006,7(5):1. [2] Jill D P,Brigitte W J,Freeman J J. Applied Spectroscopy,2004,58(7):195. [3] Fabre D,Oksengorn B. Applied Spectroscopy,1992,46(3):468. [4] LIU Guang-qi,MA Lian-xiang,LIU Jie(刘光启,马连湘,刘 杰). Chemistry and Chemical Properties Data Sheet(化学化工物性数据手册). Beijing:Chemical Industry Press(北京:化学工业出版社),2002. 85. [5] Chapoy A,Mohammadi A H,Richon D,et al. Fluid Phase Equil,2004,220(1):116. [6] Hester K C,White S N,Peltzer E T,et al. Marine Chemistry,2006,98:309. [7] Gauglitz G,Vo-Dinh T. Handbook of Spectroscopy,Wiley-vch Verlag Gmb H & Co,2003. 99. [8] Gu Y,Zhou Y,Tang H,et al. Applied Physics B,2000,71:865. [9] Hanse S B,Berg R W. Applied Spectroscopy,2001,55(1):55. [10] CHENG Guang-xu(程光煦). Raman Brillouin Scattering(拉曼布里渊散射). Beijing:Science and Technology Press(北京:科学技术出版社),2007. [11] LU Tong-xing,LU Yi-qun(陆同兴,路轶群). Principle and Application of Laser Spectroscopy(激光光谱技术原理与应用). Hefei:China Science and Technology University Press(合肥:中国科学技术大学出版社),1999. [12] ZHANG Ming-sheng(张明生). Laser Light Scattering Spectroscopy(激光散射光谱学). Beijing:Science and Technology Press(北京:科学技术出版社) ,2008.
|
[1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
[2] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
[3] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
[4] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
[5] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
[6] |
LI Wei1, TAN Feng2*, ZHANG Wei1, GAO Lu-si3, LI Jin-shan4. Application of Improved Random Frog Algorithm in Fast Identification of Soybean Varieties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3763-3769. |
[7] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
[8] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1,ZHAO Yan-jie1*,NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
[9] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
[10] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
[11] |
GUO He-yuanxi1, LI Li-jun1*, FENG Jun1, 2*, LIN Xin1, LI Rui1. A SERS-Aptsensor for Detection of Chloramphenicol Based on DNA Hybridization Indicator and Silver Nanorod Array Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3445-3451. |
[12] |
ZHU Hua-dong1, 2, 3, ZHANG Si-qi1, 2, 3, TANG Chun-jie1, 2, 3. Research and Application of On-Line Analysis of CO2 and H2S in Natural Gas Feed Gas by Laser Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3551-3558. |
[13] |
LIU Jia-ru1, SHEN Gui-yun2, HE Jian-bin2, GUO Hong1*. Research on Materials and Technology of Pingyuan Princess Tomb of Liao Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3469-3474. |
[14] |
LI Wen-wen1, 2, LONG Chang-jiang1, 2, 4*, LI Shan-jun1, 2, 3, 4, CHEN Hong1, 2, 4. Detection of Mixed Pesticide Residues of Prochloraz and Imazalil in
Citrus Epidermis by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3052-3058. |
[15] |
ZHAO Ling-yi1, 2, YANG Xi3, WEI Yi4, YANG Rui-qin1, 2*, ZHAO Qian4, ZHANG Hong-wen4, CAI Wei-ping4. SERS Detection and Efficient Identification of Heroin and Its Metabolites Based on Au/SiO2 Composite Nanosphere Array[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3150-3157. |
|
|
|
|