光谱学与光谱分析 |
|
|
|
|
|
Study on the n=5 Complex Transitions for Ions Nd Ⅷ-Sm ⅩⅤ in Cd Ⅰ Isoelectronic Sequence |
DING Kai, MU Zhi-dong*, YE Shi-wang |
Department of Physics, College of Science, China University of Mining and Technology, Xuzhou 221008,China |
|
|
Abstract The energy levels of the n=5 complex configuration 5s2, 5s5p, 5s5d and 5p2 were computed for Cd Ⅰ isoelectronic sequence ions from I Ⅵ to Sm ⅩⅤ by Hartree-Fock with relativistic corrections (HFR) method. By analyzing the variation of difference ΔE between energy levels calculated by HFR method and the experimental values with Zc along this isoelectronic sequence, the authors put forward a new fitting formula for generalized-least-square-fit (LSF) calculation. Using this formula and the FORTRAN programme designed by us, the energy levels of configurations mentioned above were calculated. The unknown energy levels of configuration 5s2, 5s5p, 5s5d and 5p2 for ions from Nd Ⅷ-Sm ⅩⅤ were predicted by extrapolation (or interpolation). Also, the wavelengths and HFR probabilities of transition 5s2—5s5p, 5s5p—5p2 and 5s5p—5s5d were computed. The calculated energy levels and wavelength results are in good agreement with corresponding experimental data reported in the references.
|
Received: 2010-02-12
Accepted: 2010-05-16
|
|
Corresponding Authors:
MU Zhi-dong
E-mail: muzhidong@126.com
|
|
[1] Kaufman V, Sugar J. J. Opt. Soc. Am., 1987, B4: 1919. [2] Tauheed A, Joshi Y N, Pinnington E H. Physica Scripta, 1997, 56: 289. [3] Gayasov R, Joshi Y N. J. Opt. Soc. Am., 1999, 16(8): 1280. [4] Churilov S S, Joshi Y N. Physica Scripta, 2000, 62: 282. [5] Joshi Y N, Ryabtsev A N, Churilov S S. J. Opt. Soc. Am. B, 2001, 18(12): 1935. [6] Churilov S S, Joshi Y N. Physica Scripta, 2002, 65: 35. [7] Ryabtsev A N, Churilov S S, Joshi Y N. Physica Scripta, 2002, 65: 227. [8] Churilov S S, Joshi Y N. Physica Scripta, 2003, 68: 128. [9] Churilov S S, Joshi Y N, Ryabtsev A N. Physica Scripta, 2005, 71: 43. [10] Cowan R D. The Theory of Atomic Structure and Spectra. California: University California Press, 1981. [11] Paul H Mokler. Hyperfine Interactions, 1998, 114: 21. [12] Alnaser A S, Landers A L, Tanis J A. Physical Review A, 2005, 94: 023201. [13] Blundell S A, Johnson W R, Safronova M S. Physical Review Letters A, 2008, 77: 032507. [14] YE Shi-wang,MU Zhi-dong, WEI Qi-ying(叶世旺,牟致栋,魏琦瑛). J. At. Mol. Phys.(原子与分子物理学报), 2006, 23(3): 566. [15] MU Zhi-dong, WEI Qi-ying(牟致栋,魏琦瑛). Acta Physica Sinica(物理学报), 2005, 54(6): 2614.
|
[1] |
YE Chang-qing, YU Xue, CHEN Shuo-ran, LIANG Zuo-qin, ZHOU Yu-yang, WANG Xiao-mei*. Study on the Structure/Energy-Level of Palladuim-Porphyrin Sensitizers on the Triplet-Triplet-Annihilation Upconversion Performance[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 71-79. |
[2] |
QUAN Cong1, 2, SUN Dun-lu1*, LUO Jian-qiao1, ZHANG Hui-li1,3, FANG Zhong-qing1, 2, ZHAO Xu-yao1, 2, HU Lun-zhen1, 2, HAN Zhi-yuan1, 2, CHENG Mao-jie1,YIN Shao-tang1. Investigation on the Multiwavelength Laser Operation and Polarization Characteristics of Er∶YAP Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2325-2331. |
[3] |
ZHANG Xue-fu1, Lü Bing1, SONG Xiao-shu1*, LINGHU Rong-feng2. Theoretical Study of Ro-Vibrational Spectrum of CO Molecule[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1001-1006. |
[4] |
FU Xu1,2, WANG Fang-bao1,2, XU Ling-yan1,2, XU Ya-dong1,2, JIE Wan-qi1,2*. Study on the Analytical Method of Thermally Stimulated Current Spectroscopy of CdZnTe Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 340-345. |
[5] |
WANG Wen-liang, LI Zhi-ming, SHEN Xiao-pan, XU Jiang, ZHAI Li-hua, DENG Hu, WEI Guan-yi. A Laser Resonance Ionization Spectroscopy Apparatus for Study on Atomic Energy Level[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3653-3657. |
[6] |
ZHANG Qiu-hui1, ZHOU Cheng-hu1, WU Xing-hui1, HUANG Quan-zhen1*, FENG Guo-ying2, LU Xiao-xiang3. The Experimental Research on Br2 Doping Effect on Multi-Layer Graphene Bandgap[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2294-2297. |
[7] |
ZHOU Xiao-yun1,2, YE Hong-gang1*, HUANG Ao2, LU Zhi-peng2 . Direct Evidences of Shallow Donor Level Enhanced Green Emission in ZnO Quantum Dots[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 624-628. |
[8] |
LI Yao, DAI Chang-jian* . Precise Temperature Measurement with Imaged Spectral Technique [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(01): 38-41. |
[9] |
ZHAO Jun, ZENG Hui*. Study on the Spectroscopic Data and Vibrational Levels of the Ground SiH+ Molecular Ion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(12): 3192-3196. |
[10] |
TAO Dong-liang1, 3, ZHANG Kun1, ZHANG Hong1, CUI Yu-min1, 3, XU Yi-zhuang2*, LIU Yu-hai2 . Study on Synthesis and Matching Degree of Energy Level of Terbium Complexes Using o-Fluoro-Benzoic Acid as Ligand [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(04): 994-998. |
[11] |
LI Xiao-li1, 2, MENG Xu-dong3, YANG Zi-cai1, SUN Jiang1 . EIT and MOLLOW Spectrum in N-Type Four-Level System [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(03): 590-594. |
[12] |
ZHANG Wan-xin, WANG Yin-hai*, LI Hai-ling, WANG Xian-sheng, ZHAO Hui . Structure and Luminescence Properties of MgGa2O4∶Cr3+ with Zn Substituted for Mg[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(01): 31-35. |
[13] |
WANG Yue-hui1, SHEN Jian-hong2, LI Na-jing1, JIN Fan1, HE Qiang1. Photoluminescence of Silver Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(11): 2935-2938. |
[14] |
FAN Xian-guang1, LI Ai-hua1, XU Ying-jie1, ZUO Yong2. Infrared Energy Level Lifetime Measurement System by Visible Upconversion Luminescence Detection Based on Double-Pulse Injection LD Module[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(11): 2966-2970. |
[15] |
PENG Tie-qiu, WANG Yin-hai*, LI Ya,XIONG Yi. Thermoluminescence Study on Sr2SiO4 Long Afterglow Material Doped with Eu2+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(12): 3223-3227. |
|
|
|
|