光谱学与光谱分析 |
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Raman Spectroscopy Analysis of Impact of UV Radiation on Linoleic Acid Oxidation |
WANG Wei-dong, SHEN Jin-hu, WANG Jun-ling, QIN Guang-yong |
Henan Province Key Laboratory of Ion Beam Bioengineering, College of Physical Science & Technology, Zhengzhou University, Zhengzhou 450052, China |
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Abstract The authors studied on self oxidation of linoleic acid and the effect of UV irradiation on oxidation of linoleic by Raman spectroscopy.The result reflects that:the intensity of 1 266 cm-1which stands for CH olenic hydrogen in-plane bend is diminished, and it disappeared at 72 hours after the oxidation beginning.That indicates that double bond was lost or reduced. ν(CC) and the carboxylic acid CO vibrations are lies in 1 658 cm-1. The intensity of 1 658 cm-1 was increased in the beginning and decreased then.At the initial stage in the reaction, rearrangement of carbon chains and the formation of carboxylic acids caused the increasing. Later in the reaction, carboxyl of linoleic acid reacted with the generated hydroxy acids, hydroxy aldehyde. So it decreased. UV irradiation accelerated the oxidation reaction starting, increased the speed of the oxidation reaction. All the result shows that the changes of Raman spectroscopy indecate the changes of bulky group in fatty acid oxidation process and the effect of UV irradiation.It provides an effective research tool for the mechanism of lipid peroxidation reaction.
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Received: 2010-01-15
Accepted: 2010-05-30
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Corresponding Authors:
WANG Wei-dong
E-mail: wwd413@zzu.edu.cn
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[1] ZHANG Ming-sheng(张明生). Laser Light Scattering Spectroscopy(激光光散射谱学). Beijing: Science Press(北京: 科学出版社), 2008. [2] XU Yi-ming(许以明). Raman Spectroscopy and Its Application in Structural Biology(拉曼光谱及其在结构生物学中的应用). Beijing Chemical Industry Press(北京:化学工业出版社), 2005. [3] HENG Hang, KE Wei-zhong, JI Kang(衡 航,柯惟中,籍 康). Journal of Nanjing Normal University(Natural Science)(南京师大学报·自然科学版),2006,29(4):46. [4] LIU Gang, XING Da, WANG Hai-min(刘 刚,邢 达,王海珉). Acta Optica Sinica(光学学报), 2002, 22(4):441. [5] ZHOU Dian-feng, KE Wei-zhong, HENG Hang(周殿凤,柯惟中,衡 航). Chinese Journal of Light Scattering(光散射学报), 2006, 18(3):241. [6] YAN Xun-ling, DONG Rui-xin, WANG Qiu-guo, et al(闫循领,董瑞新,王秋国,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(1):58. [7] Beattie Renwick J. Lipids, 2004, 39(5): 407. [8] Lawson E E. Spectrochimica Acta,Part A, Molecular and Biomolecular Spectroscopy, 1998, 54: 543.
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