光谱学与光谱分析 |
|
|
|
|
|
Raman Spectra Analysis of Calcium Metaphosphate Glass-Ceramics |
LIANG Xiao-feng1,2, YIN Guang-fu1*,YANG Shi-yuan2, MA Guo-hua2, WANG Jun-xia2 |
1. School of Materials Science and Engineering of Sichuan University, Chengdu 610065,China 2. Analytical and Testing Center, Southwest University of Science and Technology, Mianyang 621010,China |
|
|
Abstract In the present paper, calcium metaphosphate glass with molar ratio of Ca/P=0.45 was prepared and Ca(PO3)2 glass-ceramics were obtained by reheating the glass at 300-700 ℃. The Raman spectra of samples were measured. The bands of these Raman spectra were assigned and analyzed. The length of P—O bonds was calculated by using Raman wavenumbers. The results show that the crystal phase in glass was obtained when preserved at 300 ℃ for 3 h;Along with temperature increase, νs(PO2) and νs(POP) bands are stable in frequency, the bands intensity increases and fine structure appears in the Raman spectra fingerprint. The crystallization degree of glass-ceramics surface is higher than the inner. The length of P—O bonds changes during the heating process and crystallization. The length of O—P—O chain bonds changes to 158.27 pm from 159.96 pm, and terminal P—O changes to 149.02 pm from 147.92 pm, when Ca(PO3)2 glass becomes β-Ca(PO3)2 crystal.
|
Received: 2009-11-10
Accepted: 2010-02-12
|
|
Corresponding Authors:
YIN Guang-fu
E-mail: Nic0700@scu.edu.cn
|
|
[1] Rezwan K, Chen Q Z, Blaker J J. Biomaterials,2006,27:3413. [2] Eui Kyun Park, Yoang Eud Lee, Je-Yong Choi, et al. Biomaterials, 2004,25:3403. [3] Yoshio Ota, Tetsushi Iwashia, Toshihiro Kasuga, et al. Journal of Materails Science: Materials in Medicine,2002,13:895. [4] Toshihiro Kasuga, Yoshio Ota, Kenji Tsuji, et al. J. Am. Ceram. Soc., 1996,79:1821. [5] Yoshihiro Abe, Toshihiro Kasuga, Hideo Hosono, et al. Journal of American Ceramic Society, 1984, 67(7)c: 142. [6] Lee Jinn-shing, Hsu Chung-king. Thermochimica Acta, 1999,339:103. [7] Wang Kai, Christian Russel, Liu Changsheng. Materials Chemistry and Physics, 2008,111:106. [8] Yuanzheng Yue, Ralf Keding, Christian Russel. Journal of Materials Research,1999,14:3983. [9] Boolchand P, Jin Mingji, Novita D I, et al. Journal of Raman Spectroscopy,2007,38:660. [10] ZHAO Si-jie, YOU Jing-lin, CHEN Hui, et al(赵思杰,尤静林,陈 辉,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2009,29(7):188. [11] Rothammel W,Burzlaff H,Specht R. Acta Cryst., 1989,C45:551, 4. [12] Bertoluzza A, Caccari S, Tinti A, et al. Journal of Materails Science: Materials in Medicine, 1995,6:76. [13] Prokupkova P, Mosner P, Koudelka L, et al. Journal of Materials Science, 1998,33:743. [14] Popovic L, de Waal D, Boeyens J C A. Journal of Raman Spectroscopy,2005,36:2.
|
[1] |
CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2. Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1949-1957. |
[2] |
DONG Jia-lin1, HONG Ming-jian1, 3*, ZHENG Xiang-quan2, 3, XU Yi2, 3. Discrimination of Human, Dog and Rabbit Blood Using Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 459-466. |
[3] |
ZHANG Bao-yong1,2,ZHOU Hong-ji1,2,WU Qiang1,2,GAO Xia3. Raman Spectra Characteristics of Gas Hydrate Growth with Different Driving Forces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2768-2773. |
[4] |
WU Cheng-ling1, GUO Jun-hong1, 2, YAO Heng-bin1, PAN Ling-nan1, WANG Fei1, WU Wen-qi1, JI Tong1, HU Fang-ren1, 2*. Study on the Photoluminescence Properties of ZnO Single Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1700-1702. |
[5] |
XU Dong-mei1, PAN Kun1, LIU Xu-wei1, WANG Xue-jin1*, WANG Wen-zhong2, LIANG Chun-jun3, WANG Zhi2 . Raman and Visible-Near Infrared Spectra of Cu(InGa)Se2 Films [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3197-3201. |
[6] |
WANG Guo-xiang1, WANG Hai-yan2, WANG Hu1, ZHANG Zheng-yong2, LIU Jun1 . Study on the Recognition of Liquor Age of Gujing Based on Raman Spectra and Support Vector Regression[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 729-735. |
[7] |
OUYANG Shun-li1, LI Bao-wei1*, ZHANG Xue-feng1, 2, JIA Xiao-lin2, ZHAO Ming1, DENG Lei-bo1 . Spectroscopic Research on Slag Nanocrystal Glass Ceramics Containing Rare Earth Elements [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(08): 2316-2319. |
[8] |
ZHANG Bao-yong1, 2, YU Yue1, 2*, WU Qiang1, 2, GAO Xia3 . Quantitative Analysis of the Hydration Process of Mine Gas Mixture Based on Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1912-1916. |
[9] |
ZHANG Xiao-guang1,2, REN Guo-zhong2,3, YANG Huai4 . Upconversion and Mid-Infrared Fluorescence Properties of Ho3+/Yb3+ Co-Doped 50SiO2-50PbF2 Glass Ceramic [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2060-2064. |
[10] |
LI Tao, TANG Yan-lin*, LING Zhi-gang, LONG Zheng-wen . Study on the Frontier Orbital and Raman Spectra of Aflatoxin B1 and Isomer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2122-2125. |
[11] |
LI Jing1, MAO Shi-de1*, ZHENG Hai-fei2,3 . Raman Spectroscopic Quantitative Study of NaCl-CaCl2-H2O System at High Temperatures and Pressures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1747-1753. |
[12] |
LI Bao-wei1, OUYANG Shun-li1*, ZHANG Xue-feng1, JIA Xiao-lin1,2, DENG Lei-bo1, LIU Fang1 . Effect of Temperature on the Structure of CaO-MgO-Al2O3-SiO2 Nanocrystalline Glass-Ceramics Studied by Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1869-1872. |
[13] |
WU Dun, SUN Ruo-yu, LIU Gui-jian*, YUAN Zi-jiao. The Spectrum Studies of Structure Characteristics in Magma Contact Metamorphic Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(10): 2861-2864. |
[14] |
YANG Xiao-dong1, CHEN Ying1, CHEN Xiao-bo1*, Sawarobori N2, WANG Shui-feng1, ZHOU Yong-fen3, LI Song1, XU Yi-zhuang3, CHENG Huan-li1, YANG Guo-jian1. Spectroscopy Parameters of Ho3+ in Ho3+:FOG and Ho3+:FOV[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(07): 1734-1738. |
[15] |
TAO Dong-yan, LIU Chao*, YIN Chun-hai, ZENG Yi-ping . Raman Spectra Analysis of GaN∶Er Films Prepared by Ion Implantation [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(03): 699-703. |
|
|
|
|