| 光谱学与光谱分析 |
|
|
|
|
|
| Speciation Analysis of Arsenic in Traditional Chinese Medicines by Hydride Generation-Atomic Fluorescence Spectrometry with Ion Exchange Resin Separation |
| YANG Li-li1, GAO Li-rong2，ZHANG De-qiang3* |
1. College of Chemistry, Hebei Normal University, Shijiazhuang 050016，China
2. College of Chemistry & Environmental Science, Hebei University, Baoding 071002，China
3. Hebei Academy of Sciences, Shijiazhuang 050081, China |
|
|
|
|
Abstract A method for the determination of arsenic species (arsenide, arsenate) in traditional Chinese medicines using hydride generation atomic fluorescence spectrometry(HG-AFS) with ion exchange resin separation has been studied. The ion exchange resin was used to separate the arsenide and arsenate, and the separation conditions were investigated. The experimental conditions that influence the fluorescence intensity and the reduction of arsenic(Ⅴ) were investigated and optimized, and the influence of foreign ions and its elimination were studied. The proposed method was applied to the determination of arsenic species in water leachate of traditional Chinese medicines. A detection limit of 89.1 ng·mL-1 and a recovery range of 91.1％—109.3% were obtained.
|
|
Received: 2002-07-01
Accepted: 2002-11-08
|
|
|
|
Corresponding Authors:
ZHANG De-qiang
|
|
| Cite this article: |
|
YANG Li-li,GAO Li-rong,ZHANG De-qiang. Speciation Analysis of Arsenic in Traditional Chinese Medicines by Hydride Generation-Atomic Fluorescence Spectrometry with Ion Exchange Resin Separation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(04): 491-494.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I04/491 |
[1] Munoz O, Velez D，Montoro R. Analyst, 1999, 27: 798.
[2] Benramdane L, Accominotti M, Fanton L et al. Clin. Chem., 1999, 45: 301.
[3] Meser Z, Vitanyi G, Morabito R et al. J. Chromatogr. A, 1999, 832: 183.
[4] Holderbeke M V, Zhao Y, Vanhaecke F et al. J. Anal. At. Spectrum, 1999, 14: 229.
[5] LIU Zhi-hong, YANG Xiu-huan, ZHANG Zhan-xia(刘志红，杨秀环，张展霞). Chinese Journal of Analytical Chemistry(分析化学), 1994, 22(5): 468.
[6] LIU Zhi-hong, YANG Xiu-huan, ZHANG Zhan-xia(刘志红，杨秀环，张展霞). Journal of Instrumental Analysis(分析测试学报), 1994, 13(7): 56.
[7] ZHOU Tian-ze(周天泽). Chinese Traditional and Herbal Drugs(中草药)，1990, 21(10): 37.
[8] ZHANG Pei-yu(张佩瑜). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1989, 9(1): 61.
|
| [1] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 478-482. |
| [2] |
CHEN Hai-jie1, 2, MA Na1, 2, BO Wei1, 2, ZHANG Ling-huo1, 2, BAI Jin-feng1,2, SUN Bin-bin1, 2, ZHANG Qin1, 2, YU Zhao-shui1, 2*. Research on the Valence State Analysis Method of Selenium in Soil and Stream Sediment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 871-874. |
| [3] |
Lü Li, LI Yuan, JING Mei-jiao, MA Meng-dan, PENG Yue-han, QIN Shun-yi, LI Liu-an*. Determination of Selenium in Three Kinds of Eggs by Hydride Generation Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 607-611. |
| [4] |
YANG Fen1, 2, 3, XIE Shao-wen 1, 2, 3, WEI Chao-yang1, 2*, LIU Jin-xin1, 2, 3. Effects of Methanol Addition on Arsenic Speciation Analysis with HPLC-ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1884-1888. |
| [5] |
WANG Xiao-wei1, LIU Jing-fu2, GUAN Hong3, WANG Xiao-yan1, SHAO Bing1*, ZHANG Jing1, LIU Li-ping1, ZHANG Ni-na1. Determination of Total Sulfur Dioxide in Chinese Herbal Medicines via Triple Quadrupole Inductively Coupled Plasma Mass Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 527-531. |
| [6] |
WAN Xiao-ming, LIU Ying-ru, LEI Mei*, HUANG Ze-chun, CHEN Tong-bin . A Comparison of Arsenic Speciation in 13 Pteris Vittata L. Populations [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(08): 2329-2332. |
| [7] |
ZENG Chao1, LU Jian-ping2*, XUE Min-hua2, TAN Fang-wei2, WU Xiao-yan1 . Indirect Determination of Rare Earth Elements in Chinese Herbal Medicines by Hydride Generation-Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1959-1962. |
| [8] |
PENG Xiao-li1, XU Fang1*, BIAN Jing1, ZHANG Wen-zhong1, WU Yi2 . Fe(Ⅲ) Modified Sodium Alginate Beads Based Micro-Extraction in Combination with Hydride Generation-Atomic Fluorescence Spectrometry (HG-AFS) for Speciation Analysis of Inorganic As(Ⅲ) and As(Ⅴ) in Water Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(06): 1689-1692. |
| [9] |
LU Jian-ping1, GENG Guo-xing1, TANG Yan-kui2, LU Zhi-yong1 . Butanol Extraction Combined with Dilute Hydrochloric Acid Dissolution-Atomic Fluorescence Spectrometric Method for Indirect Determination of Molybdenum in Chinese Herbal Medicine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(12): 3295-3298. |
| [10] |
JIN Peng-fei，WU Xue-jun，ZOU Ding，KUANG Yong-mei，HU Xin，JIANG Wen-qing，SUN Chun-hua . Study on Arsenic Speciation Changes in Crude and Processed Traditional Chinese Medicines by HPLC-ICP-MS [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(03): 816-819. |
| [11] |
BIAN Jing1, XU Fang1*, LI Ling-hui2, WANG Wei2, HAN Jing-jing1, LI Li3 . Determination of As(Ⅲ) and As(Ⅴ) in Sea Water by Hydride Generation Atomic Fluorescence Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(10): 2834-2837. |
| [12] |
QIN Jiao-lan, CHEN Zhen-feng, LIU Yan-cheng, LIANG Hong. Determination of Trace Metal Elements in Zanthoxylum Nitidum by ICP-AES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(10): 2851-2854. |
| [13] |
YIN Xue-bin1, LU Xiao-qi1, YAO Chun-xia1, SONG Jing1, QIAN Wei1, LUO Yong-ming1*, LIANG You-qing2, SUN Li-guang2. A Study on Decreasing the Instrument Detection Limit of Atomic Fluorescence Spectrometry(AFS-930)for Hg[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(05): 1431-1433. |
| [14] |
YANG Qi-xia1,HAN Ji-qu2*,CHANG Xian-bo1,DU Xu-chang3. Application of Uniform Design in Optimizing the Condition of Arsenic Determination by Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(02): 526-529. |
| [15] |
YANG Qian1,TU Jian-bo2,WANG Si-wang1*,XIE Yan-hua1,WANG Jian-bo1. Determination of Arsenic Species in Bunge Pricklyash Seed by HG-AFS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(10): 2436-2440. |
|
|
|
|
