光谱学与光谱分析 |
|
|
|
|
|
Synthesis and Spectrum of Some 5-Furanyl-1-Benzothiazoyl Pyrazoline Compounds with Fluorescence |
WANG Jin-min1,LI Dong-feng1*,WANG Fang1,LIU Ao1,LI Min2 |
1. College of Biotechnology,Changchun University of Technology,Changchun 130012,China 2. College of Material Science and Technology,Jilin University,Changchun 130025,China |
|
|
Abstract Pyrazoline derivatives have been investigated in many aspects due to their blue light emission with high quantum yield,ready accessibility,and easily being used as carrier transporting as well as emitting materials. According to Schellhammer theory of the relation between chemical structure and fluorescent quality,we designed some new fluorescent compounds with the benzothiazoyl group in the 1-pyrazoline,the derivatives of phenyl in the 3-pyrazoline and the furan in the 5-pyrazoline,and they possess fluorescent nature. In addition,the results of our research have shown that the benzothiazoyl derivatives can also be used for electroluminescence devices. Several benzothiazoyl pyrazoline compounds were synthesized,and their structures were confirmed by IR,1H NMR,fluorescence spectrum and elementary analysis. The fluorescence spectra showed that these compounds have good fluorescence. The fluorescence emission wavelengths are about 440-460 nm,and the fluorescence intensity is related to the substituent of the compounds.
|
Received: 2006-12-09
Accepted: 2007-03-09
|
|
Corresponding Authors:
LI Dong-feng
E-mail: dongfli626@sohu.com
|
|
[1] Tang C W,Vanslyke S A. Appl. Phys. Lett.,1987,51: 913. [2] Burroughe J H,Bradley D D C,Brown A R,et al. Nature,1990,347: 539. [3] Baldo M A,Thompson M E,Fprrest S R. Nature,2000,403: 750. [4] Hung L C S,Tang C W,Mason M G. Appl. Phye. Lett.,1997,70: 152. [5] Ogawa H,Ohnioshi K,Shirota Y. Synthetic Metals,1997,91: 243. [6] Wagner A,Schellhammer C W,Petersen S. Angew. Chem. Int. Ed Engl.,1966,5: 699. [7] Sarkar A K. Fluorescent Whitening Agents. Watford,England: Merrow,1971. [8] Sano T,Fujii T,Nishio Y,et al. Jpn. J. Appl. Phys.,1995,34: 3124. [9] Xie Zhiyuan,Huang jingsong,Chen Baijun,et al. Semiconductor Photonics and Technology,1998,2: 109. [10] LI Dong-feng,JIANG Gui-ji,LI Jing-shu(李东风,姜贵吉,李京淑). Chemical Journal of Chinese Universities(高等学校化学学报),1990,11(2):205. [11] XIAN Yuan-fang,LI Dong-feng,LI Hai-dong,et al(冼远芳,李东风,李海东,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1998,18(5):543. [12] XIAN Yuan-fang,LI Dong-feng,LI Hai-dong,et al(冼远芳,李东风,李海东,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(3): 391. |
[1] |
YAN Shuai1, LI Yong-yu1*, PENG Yan-kun1, LIU Ya-chao1, HAN Dong-hai2. A Method for Correcting Nitrofurantoin Raman Signal in Honey Based on Internal Standard of Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 546-551. |
[2] |
JIA Hui-jie, ZHU Ning, GAO Yuan-yuan, WANG Ya-qi, SUO Quan-ling*. Effect of Substituent Structure of Benzothiazole Probe on Recognition to Metal Ion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3594-3598. |
[3] |
ZHU Dan-dan1, 2, QU Peng2*, SUN Chuang2, YANG Yuan2, LIU Dao-sheng1*, SHEN Qi3, HAO Yuan-qiang2*. A Benzothiazole-Based Long-Wavelength Fluorescent Probe for Dual-Response to Viscosity and H2O2[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1775-1779. |
[4] |
LI Hui-xue, WANG Jia-peng. The Theoretical Study on the Infrared Spectra and Molecular Interaction of 3-Furoic Acid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 15-21. |
[5] |
LIAO Li-min, DENG Bing, LEI Guang-dong* . Preparation and Properties of Novel Polymer Blue Fluorescent Materials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 636-640. |
[6] |
HOU Shao-gang1, JIA Tai-xuan1*, ZHANG Huan-ping1, LI Hong-liang2, ZHAO Ling1, TIAN Da-yong1, WANG Ti1 . Preparation of TBSI with NS-Acetic Anhydride Method and Its Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(09): 2870-2873. |
[7] |
XIE Li-juan1, CHEN Zhuo2 . Pseudo-Furocoumarin: Synthesis, DNA-Binding Behavior and Cytotoxicity[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(11): 3051-3055. |
[8] |
KANG Xu-sheng1, 2, HOU Di-bo1*, ZHANG Guang-xin1, CHEN Xi-ai1, 3, YUE Fei-heng1, HUANG Ping-jie1, ZHOU Ze-kui1. Spectral Analysis of Nitrofurantoin in the Terahertz Frequency Range[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(07): 1744-1747. |
[9] |
XU Hui-xia1,2, CHEN Liu-qing1,2, WANG Hua1,2, HAO Yu-ying1, XU Bing-she1,2* . Molecular Structure and Luminescent Property of Bis(2-(4-Methyl-2-Hydroxyphenyl)benzothiazolate) Zinc [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(02): 504-507. |
[10] |
LIU Hua, XUE Sai-feng*, MOU Lan, TAO Zhu . Interaction between Cucurbit[n]Urils (n=7 and 8) and 2-Amino-Phenyl-Thiazole [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(12): 3351-3354. |
[11] |
YU Jian-ning1, HAO Yu-ying1*, GUO Xiao-xia1, LEI Li-ping1, XU Hui-xia2, XU Bing-she2 . A New Type of Iridium (Ⅲ) Phenylpyrazole Complexes: Synthesis, Photophysical Characterization [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(09): 2424-2427. |
[12] |
LIU Qiu-jun1,GAO Lei1,WANG Lei1,XIE Zhi-yuan2,LI Dong-feng1* . Synthesis and Spectrum of Novel Pyrazoline Fluorescent Compounds[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(10): 2810-2814. |
[13] |
XIAN Yuan-fang1,LI Dong-feng2,WANG Yu-ming1. Synthesis of New Blue Pyrazoline Fluorescent Compounds and Study of Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(07): 1617-1620. |
[14] |
ZHENG Jia-jin1,2,ZHANG Gui-lan1*,WU Feng1,MA Li-na1,CHEN Wen-ju1. The Spectra Properties of 2-(2’-hydroxyphenyl)benzothiazole in Different Solvents[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(05): 970-973. |
[15] |
WU Jun1,HONG Qing1, 2,CHEN Yi-nan1,LI Shun-peng1* . Analysis of the Degrading Products of Carbofuran by Sphingomonas sp. with GC/MS and GC/FTIR [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(09): 1716-1719. |
|
|
|
|