| 光谱学与光谱分析 |
|
|
|
|
|
| Near-Infrared Luminescence of Yb3+-Chrome Blue-Black R Complex |
| MENG Jian-xin, DENG Zhao-xia, CHEN Da-zhi, FENG De-xiong |
| Department of Chemistry, Ji'nan University, Guangzhou 510632, China |
|
|
|
|
Abstract In the present work, sensitized near-infrared fluorescence from Yb3+-chrome blue-black R (CBR) complex was studied. It was found that Yb3+ forms 1∶2 complex with CBR in natural ethanol solution. The visible fluorescence from CBR was quenched when the complex forms, while the near-infrared fluorescence from Yb3+ was greatly enhanced. A mechanism in which CBR absorbs excitation light and transfers its energy to Yb3+ ions was suggested. Near-infrared fluorescence intensity of Yb3+ is proportional to its concentration under the experimental condition, and was not disturbed by the addition of a small amount of other lanthanide ions, which indicate that near-infrared fluorometric analysis should be promising in the determination of single langthanide ions.
|
|
Received: 2002-05-06
Accepted: 2002-09-16
|
|
|
|
Corresponding Authors:
MENG Jian-xin
|
|
| Cite this article: |
|
MENG Jian-xin,DENG Zhao-xia,CHEN Da-zhi, et al. Near-Infrared Luminescence of Yb3+-Chrome Blue-Black R Complex [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(05): 582-584.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I05/582 |
[1] WANG Er-kang(汪尔康). Analytical Chemistry of 21th Century(21世纪的分析化学). Beijing: Science Press(北京： 科学出版社)，1999. 269.
[2] Meng J X, Li K F, Yuan J et al. Chem. Phys. Lett., 2000, 332: 313.
[3] Van Der Tol, Eric B, Van Ramesdonk et al. Chem. Eru. J., 1998, 4(11): 2315.
[4] Martinus W, Hofstraat H V et al. Chem. Phys. Lett., 1997, 276(3, 4): 196.
[5] MENG Jian-xin, CHEN Da-zhi et al(孟建新，陈大志等). Chinese J. of Luminescence(发光学报)，2002，23(1)： 49.
|
| [1] |
WU Qi-xiao1, 2, ZHAO Su-ling1, 2*, XU Zheng1, 2, SONG Dan-dan1, 2, QIAO Bo1, 2, ZHANG Jun-jie1, 2, ZUO Peng-fei1, 2. Synthesis and Upconversion Mechanism of NaYF4∶Yb3+,Er3+ Nanocrystal Doped with Different Concentration of Sensitizer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1406-1411. |
| [2] |
CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2. Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1949-1957. |
| [3] |
HE En-jie1, DONG Jun2, GAO Wei2, ZHANG Zheng-long3. Upconversion Fluorescence Regulation of Single NaGdF4∶Yb3+,Er3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3347-3353. |
| [4] |
CHEN Xiao-bo1, ZHOU Gu1, ZHOU Yong-fen2, WU Zheng-long1, GUO Yu-ying1, WANG Shui-feng1, ZOU Qiu-yan3, ZHUANG Jian4, 5, CHEN Xiao-duan1, LI Chun-mi1, YAO Wen-ting1, CHENG Huan-li1 . Near-Infrared Quantum Cutting Downconversion Luminescence of Yb3+ Ion Cooperative Energy Transferred from YVO4 Matrix Donor [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(02): 315-319. |
| [5] |
LI Rui-qin, QIU Jian-bei, YANG Zheng-wen*, LIAO Jia-yan, WU Hang-jun, LAI Shen-feng, SONG Zhi-guo, YANG Yong, ZHOU Da-cheng, WANG Rong-fei . Preparation and Up-Conversion Luminescence Properties of Yb3+/Tm3+ Co-Doped Sb2O4 Powder [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(03): 630-633. |
| [6] |
YANG Yan-min*, JIAO Fu-yun, LI Zi-qiang, SU Xian-yuan, ZHANG Shao-yang, SU Hong-xin, LI Zhi-qiang. Synthesis and Upconversion Luminescence Properties of BaIn6Y2O13∶Yb3+, Er3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(02): 325-329. |
| [7] |
YANG Yan-min1, JIAO Fu-yun1, SU Hong-xin1*, LI Zi-qiang1, LIU Yun-feng2, LI Zhi-qiang1, YANG Zhi-ping1 . Preparation and Up-Conversion Luminescence Dynamic Process of Yb3+/Er3+ Co-Doped BaGd2ZnO5 [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(10): 2637-2641. |
| [8] |
HU Yue-bo1, 2, 3, ZHANG Xin-na2, ZHOU Da-li3, JIAO Qing1, WANG Rong-fei1, HUANG Jin-feng2, LONG Xiao-bo2, QIU Jian-bei1* . Effect of Bivalent Alkaline Earth Fluorides Introduction on Thermal Stability and Spectroscopic Properties of Er3+/Tm3+/Yb3+ Co-Doped Oxyfluorogermanate Glasses[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 56-60. |
| [9] |
LIU Zhuo-qun1, ZHOU Gui-yao1,2*, XIA Chang-ming1, HOU Lan-tian1 . Research on Spectral Characteristics of Yb3+ Doped Double-Cladding Large-Mode-Area Micro-Structured Optical Fiber[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(09): 2525-2528. |
| [10] |
CHENG Xue-rui，WEI Xian-tao，CHEN Yong-hu*，YIN Min . Preparation and Luminescence of Eu3+/Yb3+ Codoped ZrO2 Powders [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(09): 2312-2316. |
| [11] |
ZHANG Xiang-hua1, YANG Si-yang1, DING Qing-lei2, LIU Zheng-wei2 . The Upconversion Luminescence Characteristics of Ho3+/Yb3+ Codoped ZrO2-ZnO [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(06): 1456-1459. |
| [12] |
CAO Chun-yan1，YU Xiao-guang1，QIN Wei-ping2，ZHANG Ji-sen3 . Study on Ultraviolet Upconversion Emissions of Gd3+ Induced by Tm3+ under 980 nm Excitation [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(03): 616-620. |
| [13] |
DONG Shi-rui1, HOU Lan-tian1,2, JIN Tao-tao1, HAN Ying1, XIA Chang-ming1, NIU Jing-xia1, ZHOU Gui-yao1,2, LIANG Dan-hua1, LI Rui1. Investigation on the Fabrication and Spectrum Properties of Yb3+-Doped Silicate Laser Glasses [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(09): 2485-2488. |
| [14] |
DU Hai-yan,YANG Zhi-ping,SUN Jia-yue*. Stokes and Anti-Stokes Luminescence Research of NaYF4∶Eu3+, Tm3+, Yb3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(09): 2317-2320. |
| [15] |
YANG Zhi-ping，DU Hai-yan, SUN Jia-yue*,WANG Wei . Upconversion Luminescence Properties of ZBLAN∶Nd3+, Tm3+, Yb3+ [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(06): 1489-1492. |
|
|
|
|
