| 光谱学与光谱分析 |
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| Inhibitory Kinetic-Synchronous Fluorimetric Determination of Trace Aniline |
| ZHANG Ai-mei, JIA Li-ping |
| Institute of Chemistry and Technology, Liaocheng University, Liaocheng 252059，China |
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Abstract A novel kinetic-synchronous fluorimetric method is reported for the determination of trace aniline. The method is based on the inhibitory effect of aniline on the oxidation of fluorescein by potassium bromate in the presence of surfactant -CTMAB in the acid medium. Fluorescein’s oxidized product produces strong fluorescence. But its excitation and emission spectra overlap seriously. So this article adopted synchronous fluorimetric spectra to diminish spectra overlap and obtained very good sensitivity and selectivity. The detection limit for aniline is 0.3 μg·L-1, and the linear range is 0-10 μg·L-1. The proposed method has been applied to the determination of trace aniline in waste water and laboratory water with satisfactory results.
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Received: 2003-01-26
Accepted: 2003-05-08
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Corresponding Authors:
ZHANG Ai-mei
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| Cite this article: |
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ZHANG Ai-mei,JIA Li-ping. Inhibitory Kinetic-Synchronous Fluorimetric Determination of Trace Aniline [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(06): 723-725.
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| URL: |
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http://www.gpxygpfx.com/EN/Y2004/V24/I06/723 |
[1] Norwize Geoge, Keliher Peter N. Anal. Lett., 1981, 53(8): 1238.
[2] CHENG Ding-xi, ZHANG Hong-wu(程定玺，张红武). Chinese J. Anal. Chem(分析化学), 2002, 30(6): 719.
[3] FENG Su-ling, ZHANG Gui-en(冯素玲，张桂恩). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1997, 17(4): 104.
[4] LU Yue-qing, LI Yi- min(鲁越青，李益民). Physical Testing and Chemical Analysis, Part B: Chemical Analysis(理化检验-化学分册)，1999, 35(6): 254.
[5] YUAN Cun-guang, LIU Guang-dong(袁存光，刘广东). Environmental Chemistry(环境化学), 1994, 13(4): 354.
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