光谱学与光谱分析 |
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Study on the Transition of Green,Yellow Fluorescence of Ternary Complexes of Tb-Benzoic Acid-1,10-Phenanthroline |
WANG Xi-gui1,WU Hong-ying1,YAO Guang-qing2,WENG Shi-fu2,WU Jin-guang2 |
1. Department of Chemistry, Inner Mongolia Normal University, Huhhot 010022, China 2. College of Chemistry and Molecular Engineering, Peking University, State Key Laboratory of Rare Earth Materials Chemistry and Application, Beijing 100871, China |
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Abstract In this paper, ternary solid complexes of Tb-benzioc acid-1,10-phenanthroline have been synthesized. Compared with binary complexes of Tb-benzioc acid, their properties were investigated. The results showed that the second ligand-phenanthroline enhanced the fluorescence intensities of Tb3+, and shortened its fluorescence lifetime, and it was found that the aggregative state influenced the luminescence properties of ternary complexes. When particulates dispersed to a certain degree, the probability of 5D4→7F5 transition of Tb3+ was great, so, green fluorescence was observed for the complexes. With the aggregation of particles, the probability of 5D4→7F5 transition of Tb3+ decreased, while the probability of 5D4→7F3 transition increased. Therefore, ternary complexes of Tb-benzoic acid-1,10-phenanthroline exhibited yellow fluorescence. In addition, spectroscopic properties of the complexes were investigated.
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Received: 2002-08-20
Accepted: 2002-12-28
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Corresponding Authors:
WANG Xi-gui
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Cite this article: |
WANG Xi-gui,WU Hong-ying,YAO Guang-qing, et al. Study on the Transition of Green,Yellow Fluorescence of Ternary Complexes of Tb-Benzoic Acid-1,10-Phenanthroline [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(06): 708-712.
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URL: |
http://www.gpxygpfx.com/EN/Y2004/V24/I06/708 |
[1] SUN Bo,ZHAO Ying, XU Duan-fu et al(孙 波, 赵 莹,徐端夫等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1997, 17(2): 24. [2] LIAN Xi-shan, MA Su-qing(连锡山,马素清). Chinese Rare Earths(稀土), 1999, 20(5): 7. [3] Yan B, Zhang H J, Ni J Z et al. Science and Engineering, 1998, B 52: 123. [4] YAN Bing, ZHANG Hong-jie, WANG Shu-bin et al. Journal of Photochemistry and Photobiology, 1998, A 112: 231. [5] SHI Jin-chao, PENG Xiao-qi, JIA Ying-qi et al. Journal of Chinese Rare Earth Society, 2000, 18(1): 18. [6] ZENG Hai-yan, YANG Yan-sheng, HUANG Shi-hua(曾海燕,杨燕生,黄世华). Chinese Journal of Luminescence(发光学报), 1992, 16(4): 354. [7] ZHAO Ying, XIE Da-tao, WU Jin-guang et al.(赵 莹,谢大,吴瑾光等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1998, 18(2): 173. [8] WU Jin-guang(吴瑾光). Techniques and Applications of modern Fourier Transform Infrared Spectroscopy(近代傅里叶变换红外光谱技术及应用). Beijing(北京): Science and Technology Literature Press(科学技术文献出版社),1994. 642. [9] Dorenbos P. Journal of Luminescence, 2000, 91: 91. [10] HU Ji-ming, CHEN Guan-quan, ZENG Yun-e(胡继明,陈观铨,曾云鹗). Chem. J. Chinese Universities(高等学校化学学报), 1990, 11(8): 817.
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